Editorials

Cellulose serves as a skeleton for many of the useful products upon which we rely on each day. When we want to learn about a skeleton, it makes sense to think about X-ray methods. The same can be said when it comes to learning about the crystallinity of cellulose. Over the past six decades, the Segal X-ray diffraction (XRD) method has been popular for judging the percent crystallinity of powder samples. However, XRD patterns for ideal cellulose crystals can be easily simulated, and limitations of the Segal and other methods become obvious. Calculated patterns for model 100% crystalline powder particles are predicted to be less crystalline by the Segal method. Except for the Rietveld method, current approaches do not account for particle orientation or different shapes of crystallites. The Rietveld method has so many variables that it can easily overfit the data. The take-away message is that routine XRD examination is important for showing sample characteristics, but fractional crystallinity values are affected by constraints related to simplifications required for the analysis.

Higher-order systems found in nature continue to be a source of inspiration for designing highly functional artificial systems. However, compositing these systems requires a precise understanding of how the components required can affect final desired responses. This non-trivial task is daunting and therefore will require a multiplicity of approaches elaborated under the umbrella of compositomics, a proposed –omics cluster dedicated to fabricating green materials through modeling, systems thinking, and machine learning.

Sustaining life on the Earth with its ever-growing population is forcing changes in people’s way of life, industrial and agricultural production, exploitation of energy resources, and approaches to ecology. We face continual growth in the world’s population, and the demand for materials is growing even more rapidly. Every manufacturing and consumer sector is looking for ways to save energy and materials, attempting to minimize their negative impacts on the environment. In the pulp and paper industry, one of the segments in which progress can be made and help protect the planet is to reduce the brightness of paper. Such a reduction would lead to a lowering in the energy and material costs associated with paper production.

This editorial considers the use of images as a way to enhance the readability and possibly the impact of scientific writing. Readers are asked to envision effective scientific writing as a form of storytelling. Some stories can be enhanced by adding a diagram or a step-by-step procedure. Inherently dull results might be enlivened (in a cautious manner) with a non-typical graphical portrayal. A potentially tedious theoretical point might be lightened with a touch of humor, which might seem out of place if it were expressed in text. Keep these options in mind as you are creating your next story, i.e., your next research article.

The development of nanocellulose sustainable materials is considered as one of the most promising alternatives to address plastic pollution issues, as global plastic wastes may increase to 11 billion tonnes by 2025. However, how to achieve the homogeneous dispersion of nanocelluloses (CNCs) and strong interfacial interactions with matrix materials, while well maintaining its percolation networks, is a challenge in this field. As opposed to the conventional surface chemical modification strategy, the reducing end modification of CNCs as a novel approach provides an opportunity to achieve this objective, which also opens a new door for the design of stimuli-responsive CNC sustainable composites, such as vitrimer materials and stimuli-responsive Pickering emulsions.

An awareness of the problems associated with the use of plastics can provide new opportunities for the paper industry. We have to try to enhance the public awareness of the environmental value of papers by using diverse advertising approaches. We have to collaborate to make paper more viable to replace plastics in many uses. The collaboration not only between industry and academia but also between countries and associations is essential to advance the age of paper.

Lignin is considered by many as the ultimate barrier that impedes biomass conversion to fuels and chemicals. Several delignification strategies have been developed so far, but alkaline extraction remains the most widely used. However, this technology has a high chemical demand, consumes large amounts of water, and generates effluents that are hard to handle. Organosolv pulping is a good option for such application, but the impact of solvent losses and harmful emissions may be unsustainable. To this end, the use of greener alternatives such as water, biobased solvents, ionic liquids, and deep eutectic solvents, under sub- or supercritical conditions, may pave the road for the development of sustainable biorefineries.

Lignocellulosic biomass (LB) is widely used in the field of renewable energy production because of its low price and easy availability. Many kinds of fuels from LB have been developed and are being used in our daily lives. The LB energy has become an indispensable part in the energy mix on account of its steady and sustainable supply. However, there are some neglected issues and misconceptions regarding its development and utilization, although it has numerous advantages over other energy sources. Firstly, its development and utilization can change the living environment of organisms and decrease biodiversity to some extent, relative to using other sources of energy. Secondly, it is not a completely carbon-neutralized fuel as has been claimed in some literature. Finally, its excessive exploitation can seriously damage the environment and biosystems. This editorial will give a brief discussion on some neglected issues and misconceptions during its development and utilization for its suitable exploitation.

Insulating paper is the key material utilized in ultra-high voltage (UHV) projects, and it affects the safe and stable operation of the whole power system. Cellulose fiber-based insulating paper, having the advantages of low price and environmental friendliness, has been widely used as the preferred insulating material for certain transformers. Bamboo, as a fast-growing raw material, has a favorable fiber length and its carbon sequestration is better than that of wood. Bamboo can be potentially used as a new raw material for insulating paper, thus promoting the green development of the power and paper industry. This article mainly discusses the challenges and potentials of bamboo fiber-based insulating paper and the opportunities of bamboo fiber-based paper materials.

In many of its current and potential applications, technologists treat the surface of cellulose to render it more hydrophobic. By use of a variety of hydrophobic sizing treatment strategies, the bulk cellulose phase becomes covered up with a layer having lower polarity and less inclination to interact with water. Often, the goal is to use a relatively low amount of additive to cover up or change just the surface of the cellulosic material, while still benefiting from the strength, recyclability, relatively low cost, and other favorable features of the bio-based material. But what often gets forgotten is that the hydrophilic nature of pure cellulose is not very high, and there are ways to manipulate such characteristics without reacting the material or covering it up. Sometimes reacting the cellulose with hydrophobic substituent groups appears to make it more water-loving. So, when thinking broadly of processing options for new applications, there are several contrasting approaches to consider.