Research Articles

This study shows that it is possible to manufacture moulded products from fibrous pulp at the laboratory scale using the Rapid-Köthen apparatus (found in almost every paper laboratory) and a special sieve form set. This process includes the design of elements of the mould forming sets by special software, production of these elements using a numerically controlled tool machine, the assembly of the sieve form, its installation in the Rapid-Köthen apparatus, and the forming and drying of the pulp product.

Finite element simulations of coupled thermal and moisture fields in wood during kiln drying were observed with a focus on non-isothermal moisture transfer in three dimensional orthotropic models of wood with an initial moisture content below the fiber saturation point. Four different unsteady-state numerical models of the drying process were compared with the assumptions given by standards commonly used in wood kiln-drying processes. The first model describes linear simulation, and the other three models present nonlinear simulation using variable material coefficients dependent on temperature and moisture content, differing in settings of the Soret effect (thermodiffusion). A linear model was useful for predicting only the average moisture content during drying. Moreover, the nonlinear simulations were useful for computing the moisture content distribution. High differences (2.31% of moisture content) were found between the flow of moisture predicted by numerical models and standard requirements.

In the Mexican state of Jalisco, a significant amount of fibrous agave waste is generated from the tequila industry every year. The objective of this study was to establish the potential of obtaining cellulose nanofibers (CNF) from the bagasse waste of Agave tequilana, and then incorporate them into a linear medium density polyethylene matrix to obtain nanocomposites through the thermocompression process. These nanoparticles were used to prepare nanocomposites of the selected matrix, incorporating 1 to 5 wt% of CNF. All of the prepared composites had a low water absorption. Increases in tensile strength and in modulus and flexural properties occurred when the concentration of the CNF was augmented. However, in the case of nanocomposites with 5 wt%, a decrease in elongation was observed.

The wood chemical composition was determined for five tree species that cohabitate in the forest of Ixtlán de Juárez (Oaxaca, Mexico). These species were Alnus acuminata, Arbutus xalapensis, Myrsine juergensenii, Persea longipes, and Prunus serotina. The chemical composition was then correlated with the higher heating value of the wood. The chemical components determined were total extractives, ash, lignin, and holocellulose (alpha cellulose and hemicelluloses). The extractives were separated using Soxhlet equipment, and the ash obtained was analyzed via atomic absorption spectrometry. On average, the species presented 8.26 to 19.64% of total extractives, 0.56 to 1.50% of ash, 23.1 to 37.2% of lignin, 74.0 to 79.5% of holocellulose, 56.3 to 66.3% of α-cellulose, and 12.3 to 21.0% of hemicelluloses. In the ash, higher percentages of calcium, potassium, and magnesium were detected. The amount of chemical components was different between species (p ≤ 0.05). The higher heating value showed a positive correlation with the extractives content (r = 0.582), while with the ash content it was negative (-0.575). The high proportions of polysaccharides predict good performance of these species in pulp production, and the calorific value indicates that they have the potential for use as fuel.

The objective of this study was to evaluate the extent to which the practicing architects in Malaysia were familiar with timber products as a construction material. The materials consumption data was extracted from the Construction Industry Development Board (CIDB) database and was used to conduct a survey among 189 respondent architects. The results indicated that the architects were familiar with common timber products such as plywood, fiberboard, particleboard, and laminated veneer lumber. Correlation analysis of awareness and knowledge against the rate of utilization of these timber products was significant. Furthermore, the most important deterrent factors for the use of timber products in building construction in Malaysia were the high cost, poor durability, restrictive building codes and by-laws, as well as the low fire resistance. More aggressive promotion of timber products as a potential construction material is advisable to be undertaken when the goal is to boost the material’s use in the construction industry. Policy makers may also consider providing financial incentives to increase timber products utilization in building construction in Malaysia.

Autonomous self-repairing properties can prolong the service life of materials. In this paper, galactomannan hydrogel with high mechanical strength was prepared by graft copolymerization of galactomannan with acrylamide and octadecyl methacrylate in aqueous solution. The microstructure, water absorption property, self-healing behavior, and mechanical properties of the hydrogels were investigated using Fourier transform infrared spectroscopy (FTIR) and scanning electron microscope (SEM), etc. The galactomannan hydrogel had the highest tensile strength of 49 KPa and strain of 3000%. The water absorption reached 2340%, and the removal rate of methylene blue was more than 80%. Galactomannan hydrogels demonstrated significant self-healing properties. The cut hydrogel was quite effective in self-repairing in a few minutes, and the self-repairing strength increased with increasing contact time of hydrogel cut surfaces. The healing efficiency of fracture strain could reach 92.7% of the original sample in 10 h. The maximum water absorption of hydrogel reached 2340%. The maximum removal rate of methylene blue by hydrogel reached 80.5%, and the maximum adsorption capacity was 19.3 mg/g. The novelty of the work lies in octadecyl methacrylate being used for galactomannan cross-linking with the ability to self-repair after fracture. The galactomannan self-healing hydrogel has potential in water treatment and sealing technology.

Natural lignocellulosic biomass is a valuable feedstock for soluble-grade cellulose (α-cellulose > 90%) with advantageous features such as abundance, high strength, rigid structure, low weight, and it is biodegradable. The bagasse from Agave tequilana Weber var. azul is the main agroindustrial waste from the tequila industry and poses an environmental threat. However, due to its high cellulose content, Agave tequilana bagasse is an excellent candidate for the extraction and utilization of its components. In this study, alkaline cooking, followed by five stages of bleaching, was employed to obtain soluble-grade cellulose pulp. The obtained soda pulp material had a Kappa number (KN) of 23 ± 3, viscosity (μ) of 11.53 to 10.18 cp, degree of polymerization (DP) of 830 to 750, brightness of 87.5%, and percentage of alpha-cellulose (α) of 81 ± 3 at 94 ± 3%. The obtained material was characterized using X-ray diffraction, Fourier-transform infrared spectroscopy, and scanning electron microscopy to compare its properties with published information. The waste of A. tequilana Weber var. azul produced pulp with a high percentage of alpha cellulose and a high crystallinity degree. This methodology is novel and simple for the production of soluble-grade cellulose pulp, a raw material for the production of cellulose nanocrystals.

Flexural properties were evaluated of blockboard with spruce (Picea abies Mill) core and faces made of 2.5-mm fromager (Ceiba pentandra) veneer and 3-mm high-density fiberboard (HDF). For these two types of structures, fiber glass, jute, gauze, and cotton fabrics, were separately bonded under the face layers to improve the strength performance. Flexural properties, modulus of rupture (MOR), and modulus of elasticity (MOE) were determined under laboratory conditions. Improved values were found for MOR and MOE tested in the parallel to core grain direction compared to those perpendicular-to-grain. They were 32% to 49% (MOR) and 39% to 95% (MOE) improvements in case of veneer faces and 142% to 161% (MOR) and 134% to 245% (MOE) improvements in case of HDF faces. The best results of MOR and MOE were obtained for glass fiber used as insertion material, the higher ones being reached for specimens tested in the parallel direction to grain, which were 56.1 N/mm2 (MOR) and 6704 N/mm2 (MOE) for HDF faces. Generally, the improvements were more evident on the blockboard structures with veneer faces oriented perpendicular-to-core grain (30% for MOR and 18% MOE) and for HDF faces with parallel core grain orientation (16% for MOR and 6% MOE).

Foam forming is an innovative process for papermaking that yields various paper products with excellent formability and porosity. The stability of the foam is a critical factor in foam forming technology. The effects of different surfactants and gases (N2 and CO2) on the ability of the foams to coalesce and the stability of the foams were studied. The properties of the liquid film were investigated via high-speed camera observation and infrared spectrum. The CO2 foam was less stable than the N2 foam under the same conditions, especially for the polyvinyl alcohol surfactant. The infrared spectra and high-speed camera observation showed that the main factor that resulted in CO2 foam instability was the bubble coalescence caused via the gas diffusion in the foam column, although the process of liquid film thinning was performed simultaneously. The greater the liquid film permeability coefficient of the foam, the easier the gas was able to spread throughout the liquid film. Foam forming technology will likely be employed in many potential pulp and papermaking mill processes.

The use of particleboards (PB) has increased quickly as an alternative engineered wood product mainly due to its having a better ratio of resistance to weight and more elimination of wood defects, such as the presence of knots. Although the panel industry has been constantly growing, innovations are still necessary to improve the final product. The use of metallic oxide nanoparticles on the wood-based panels has the potential to increase the heat transfer process and improve the physico-mechanical properties. The aim of this work was to evaluate the influence of the addition of zinc oxide (ZnO) nanoparticles in PB, correlating the physical and mechanical properties of the panel with the heat transfer process at 180 °C. The results were compared with the Brazilian standard ABNT NBR 14810-2 (2013) and the European standard EN 312 (2010), as well with works found in literature. The results showed a homogenous heat distribution during the pressing, which improved physical properties, decreasing the 24h swelling from 22.2% to 14.9% and the 24 h absorption from 30.29% to 21.0%. Besides that, MOR values was increased from 11.3 MPa to 14.5 MPa and the MOE from 1880 MPa to 2510 MPa.