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BioResources
Tang, C., Zhao, J., Li, X., and Song, J. (2020). "Formation mechanism of aromatics during co-pyrolysis of coal and cotton stalk," BioRes. 15(2), 4449-4463.

Abstract

Pyrolysis experiments were conducted in a tubular furnace from room temperature to 600 °C at 5 °C /min, and kept for 15 min. The light tar was then derived from the liquid products of pyrolysis by n-hexane supersonic extraction. Gas chromatography–mass spectrometry was employed to analyze the light tars from cotton stalk (CS) pyrolysis, Shenmu coal (SM) pyrolysis, and co-pyrolysis of CS/SM. Microcrystalline cellulose (MCC) was selected as a model compound, and the light tar from co-pyrolysis tar of MCC/SM was investigated for comparison. The results indicated that CS improved the yields and quality of phenols and benzenes in co-pyrolysis tar and that MCC had excellent performance in the formation of mononuclear aromatics during the co-pyrolysis of MCC/SM. Based on the pyrolytic behavior of CS and SM, the mechanisms of aromatic formation were further determined. It was shown that the free radicals that cracked from CS accelerated the formation of aromatics. The alkyl and mononuclear aromatic radicals of CS pyrolysis combined with the radicals from the SM aromatic structure, which then converted to benzenes and phenols. Finally, the most favorable reaction routes of mononuclear aromatics formation were proposed.


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Fiber Fines for Fabricating Lignocellulose Films and the Effect of Lignin

Mohammad Pourjafar, Amir Khosravani,* and Rabi Behrooz

Excess lignocellulose fines in some fiber processing mills cause issues and hurt product quality. To use this type of biomaterial as a resource, surplus fines can be separated and dissolved with solvents for further transformation. Therefore, 1-butyl 3-methyl imidazolium chloride ionic liquid (IL) was used as a powerful green solvent for a rapid dissolution process. However, a low degree of polymerization (DP) of the cellulose in fines and the effects of lignin content and its structure on the process and film properties are controversial subjects. This study demonstrated that the three dimensional structure of lignin did not permit the raw bagasse fines (prior to pulping) to dissolve in the IL even after several hours. However, following decomposition of the lignin structure by pulping, the fiber fines were readily dissolved. Further, all the fabricated films from the fiber fines exhibited satisfactory strength properties, despite the fact that the cellulose had a low DP. The films from bleached fiber fines showed higher tensile strength than those containing lignin, although the cellulose chain was longer and had a higher DP for the latter. Lignin resulted in reduced transparency, and higher absorption of ultraviolet radiations, but it did not affect the surface roughness of the films.

Keywords: Fiber fines; Lignocellulose film; Lignin; Ionic liquid

Contact information: Department of Wood and Paper Science and Technology, Faculty of Natural Resources, Tarbiat Modares University, 4641776489 Mazandaran, Noor, Iran;

* Corresponding author: khosravani@modares.ac.ir

INTRODUCTION

The wide application of synthetic polymers for industrial product fabrication has caused many environmental problems, as they are not biodegradable or eco-friendly, and they are increasingly accumulating in the biosphere. Moreover, dependence on fossil fuels is another challenge. Therefore, bio-based polymers and composites have attracted much attention. Bio-composite materials and films have potential use for a wide variety of applications such as environmental uses, scaffolds, food packaging, automotive industry, etc. (Pinkert et al. 2009; Abdollahi et al. 2012; Soheilmoghaddam et al. 2014).

One of the most important renewable, natural feedstocks is lignocellulose materials (Ibrahim 2002; Lateef et al. 2009; Pinkert et al. 2009). However, as most lignocellulose resources are consumed for wood products, wood-based composites, pulp and paper, and biorefining, introducing new applications can lead to more resource exploitation and further environmental damage (Lateef et al. 2009).

Therefore, developing sustainable approaches for lignocellulose material recovery and reuse is of great interest, and the effective application of lignocellulose residues is particularly important. For instance, in some fiber processing, paper manufacturing, or recycling mills, excess inactive or recycled fiber fines can reach 40% of the pulp oven-dry weight, causing problems with the process and damaging product quality (Doshi 1998; Jeffries and Schartman 1999; Hubbe 2002; Rahmaninia and Khosravani 2015; Steffen et al. 2016).

Fines are small fiber segments that can pass through a 200-mesh screen with nominally round hole diameters of 76 µm as per TAPPI T261 cm-00 (2007). Flake-like or chunk-shaped fines have low potential to bond to improve paper strength (Motamedian et al. 2019). Therefore, surplus fiber fines can be separated for further processing as a renewable feedstock (Jeffries and Schartman 1999; Steffen et al. 2016).

However, cellulose materials are not easily dissolved in common solvents due to their numerous inter- and intra-molecular hydrogen bonds, crystalline structure, and high degrees of polymerization (Abdolkhani et al. 2013; Niroomand et al. 2016; Zhang et al. 2017). Therefore, various solvents, such as lithium chloride/1,3-dimethyl-2-imidazolidinone (LiCl/DMI), N-methyl morpholine N-oxide (NMMO), lithium chloride/N,N-dimethylacetamide (LiCl/DMAc), phosphoric acid, and urea/NaOH, were developed to prepare regenerated cellulose materials.

Unfortunately, most of the solvents cannot be widely applied due to recovery obstacles, high environmental toxicity, or detrimental side reactions (Zhang et al. 2005; Meenatchi et al. 2017). However, ionic liquids (ILs) have been proposed as suitable, environmentally friendly solvents for many chemical operations. These solvents possess very low vapor pressure, facilitating their recovery and reuse. In addition, they are non-flammable, and also chemically / thermally stable (Swatloski et al. 2002; Kilpeläinen et al. 2007; Pinkert et al. 2009; Mäki-Arvela et al. 2010; Meenatchi et al. 2017).

However, complete dissolution of wood chips from various species in the most powerful ILs has not always been achieved, even after long periods at very high temperatures (Kilpeläinen et al. 2007; Pinkert et al. 2009). Other lignocellulose materials, such as sawdust, wood fibers from thermo-mechanical pulping, bagasse fibers, and microcrystalline cellulose (MCC), have been partially or totally dissolved in ILs under mild process conditions (Fort et al. 2007; Kilpeläinen et al. 2007; Pinkert et al. 2009; Mäki-Arvela et al. 2010; Khosravani et al. 2018).

Moreover, it is important to clarify the effect of lignin and its structure in the dissolution of lignocellulose material in the IL. Prior to pulping, the lignin possess a compact three-dimensional structure. After pulping and bleaching, lignin breaks down and it is partially or totally removed.

The dissolution and transformation of fiber fines as a bio-polymer resource for different purposes is a controversial matter. Due to various chemical processes, such as pulping and bleaching, the degree of polymerization and crystallinity of cellulose in typical fiber fines is low. Consequently, poor mechanical properties can be expected for the resulting product. However, these qualities can be positive factors that facilitate dissolution with less viscosity and improved cellulose solution workability. In addition, the composition of fiber fines is different from that of pure cellulose raw materials, as it often contains lignin and other non-cellulose impurities that can affect cellulose recovery and reuse.

EXPERIMENTAL

Materials

De-pithed bagasse (lignocellulose residue from sugarcane processing factory), a locally available lignocellulose material, was provided by Pars Paper mill (Ahwaz, Iran). The raw fibrous material was pulped and bleached to prepare unbleached bagasse fiber and the bleached material. The ionic liquid, 1-butyl-3-methyl imidazolium chloride (BMIMCl) with a purity of more than 95% was purchased from Sigma-Aldrich Chemical Company (Steinheim, Germany). Other chemicals were of analytical grade, provided by local vendors, and used without further purification.

Methods

Preparation of bagasse soda pulp

For the pulping process, a 3-L cylindrical rotating digester was used. The digester was equipped with the necessary instruments for measurement and control of pressure and temperature, and it was linked through a rotary axle to ensure proper agitation. The bagasse/liquor ratio was 1:8 with an alkali charge of 22.5 gL-1 NaOH (18% based on the oven-dry weight of bagasse) for soda pulping at 170 °C for 45 min.

Then, the resulting bagasse pulp was discharged into a 200-mesh sieve and washed with tap water thoroughly. The Kappa number was determined according to TAPPI T236 om-99 (2007), and the evaluation of lignin content was according to TAPPI T222 om-02 (2007) with three replications. The degree of polymerization (DP) for cellulose in fiber fines was determined using the method described in the TAPPI T230 om-04 (2007) standard with a capillary viscometer at 25 °C and using cupriethylenediamine (CED) for cellulose dissolution. Finally, the DP was calculated with Eq. 1 (Keshk 2008),

DP 0.905 = 0.75[954 log (v)325] (1)

where v is TAPPI viscosity (cP).

Precipitation of lignin from black liquor

To prepare the lignin required for further study, the black liquor resulting from the soda pulping of bagasse in the previous stage was heated to 90 °C. Then, under intensive stirring, 20% (w/w) sulfuric acid solution was added to the liquor, and the pH and temperature were reduced to 11 and 40 °C, respectively. The filtered material was washed with distilled water. It was then diluted to 2% (w/w) and acidified with the sulfuric acid solution to a pH of 2. The precipitated lignin was washed with an acidic solution (pH: 2), air-dried, and then oven-dried in a vacuum oven at 40 °C (Lin and Dence 1992).

Bleaching (delignification) of the pulp

The bleaching process was performed to remove residual lignin according to the procedure developed by Zobel and McElwee (1966) and used for various studies (Janardhnan and Sain 2007). First, preheated distilled water (160 mL) was added to the air-dried brown pulp (2 g) in an Erlenmeyer flask. Then, 20 mL of sodium chlorite (34 gL-1) and 20 mL of a prepared buffer solution (10.5 g sodium hydroxide, 29 mL acetic acid, and 170 mL distilled water) were added to the flask. The flask was heated in a hot-water bath at 70 °C for 2 h. Finally, following neutralization of the pulp by sodium sulfite, the resulting white, fully bleached fibers were thoroughly washed with distilled water.

Fines and fiber fractions

To prepare fiber fines from specified fibers of known sources for laboratory-scale evaluation, bleached (near zero-lignin content) and unbleached (2% lignin content) fibers resulting from previous stages were ground in a small laboratory mill and then passed through a 150-mesh size (approximately 100-micron) vibratory sieve in laboratory conditions to obtain bleached fiber fines (BFF) and unbleached fiber fines (UFF). The same procedure was followed to prepare raw bagasse fines (RBF). To study the effect of residual lignin incorporated in the cell wall structure of UFF, the same amount of lignin (2%) was added to BFF and the mixture was referred to as BFL.

Dissolution of lignocellulose fines and preparation of the film

The oven-dried (103 °C ± 2 °C for 24 h) lignocellulose fiber fines were mixed into hot (85 °C to 95 °C) BMIMCL liquid, at a 2% (w/w) fines: IL ratio and a 300 rpm stirring rate under a nitrogen atmosphere for 1 h. The resulting solution was casted on a glass plate and kept at the ambient temperature for 24 h. Afterwards, the resulting gel was washed with distilled water once every 6 h for a total of 4 times to ensure complete IL removal. Eventually, the wet-produced films were mildly blotted between filter papers and dried at 60 °C for 12 h.

Optical microscope

To visualize the development of the process, some images were taken during the initial fines dissolution stages by a MICROS N-200 optical microscope (Vienna, Austria) at 250x magnification.

Characterization

Morphological studies on the structure of the produced film specimens were performed using a Tescan MIRA3 XMU field emission scanning electron microscope (FE-SEM) (Tescan, Brno, Czech Republic). For preparation, the samples were frozen in liquid nitrogen, immediately snapped, and the fractured surfaces of the samples were studied.

To analyze possible chemical transformations, the infrared (IR) spectra of raw lignocellulose fines and the produced films were recorded on a SHIMADZU-8400S Fourier transform infrared (FT-IR) spectrometer (Kyoto, Japan) equipped with an attenuated total reflectance (ATR) apparatus. Thirty two scans were performed within the range of 4000 cm-1 and 400 cm-1 with a resolution of 4 cm-1.

To study the crystalline structures of cellulose material during the dissolution and preparation processes, the fines and the resulting film specimens were analyzed using a X’Pert MPD diffractometer (Philips, Eindhoven, Netherlands) with Cu Kα radiation (40 kV and 40 mA) in the range of 2θ = 10° to 50° with a speed of 1.5°/min. Then, the crystallinity indices (CrIs) were estimated with Eq. 2, according to the method of Segal et al. (1959),

 (2)

where IMax is the maximum intensity of the principal peak (2θ = 22.2°) (200) lattice diffraction, and Iam is the intensity of diffraction attributed to the amorphous cellulose, lignin, and hemicellulose (2θ ≈ 18°).

Mechanical measurements

To evaluate the mechanical performance of the films, tensile modulus (TM), tensile strength (TS), and elongation at break (EAB) were measured using a Perten TVT-300Xp universal testing machine (Perten Instruments, Hägersten, Sweden) according to the ASTM D882-02 (2002) standard procedure. Five rectangular samples of the films (10 mm × 50 mm) were prepared and their thicknesses were measured at five points. The grip separation distance and the constant elongation rate for the test were 30 mm and 10 mm/min, respectively (Niroomand et al. 2016).

Contact angle (CA)

The water droplet contact angles of the specimens were measured by applying a PG-X Goniometer dynamic contact angle analyzer (FIBRO System ab, Stockholm, Sweden), at 50% RH, 23 °C, and a droplet volume of 30 µL (Khosravani et al. 2016).

Water absorption (WA)

To measure the water absorption capacity of the films, a previously published method was used that determined absorption capacity by the weight increase of the samples due to water uptake in specified periods (Lavorgna et al. 2010; Abdollahi et al. 2012; Niroomand et al. 2016). The initial weights of the 20 mm × 20 mm film samples were determined by placing them in a desiccator containing fresh silica gel for approximately 3 days. Then, the samples were put in 30 mL of distilled water at 25 °C with a pH of 7 in sealed beakers. At predetermined time intervals, the WA was measured. For each measurement, the unabsorbed water on the sample surfaces was removed by blotting with a new filter paper. Finally, the WA values of the films were calculated using Eq. 3,

WA (%) = (Ws – Wi/ W× 100 (3)

where Ws is the secondary weight (g) of the samples following water absorption, and Wi is the initial dry weight (g) under the above described conditions.

Optical properties

The transmittance (Tr) and opacity (Op) of the film samples were evaluated by a Lambda 25 UV–visible spectroscope (PerkinElmer Inc., Waltham, MA, USA) in the range of 200 nm to 800 nm. The samples were 9 mm × 30 mm, and they were placed in the specified cell of the spectrophotometer directly. As a reference blank, a vacant quartz compartment was employed. Evaluation of opacity was performed at 600 nm and calculated according to Eq. 4 (Abdollahi et al. 2013; Atef et al. 2014),

Op = A600 (4)

where A600 is the absorbance at 600 nm, and T refers to the thickness of the film (mm).

Color evaluation

The color parameters of the samples were analyzed by a BYK-Gardner color meter (BYK-Gardner Gmbh, Geretsried, Germany). The samples were placed on a standard white plate (L* = 94.63, a* = −0.88, and b* = 0.65) and the color parameters were measured. Among these parameters, L* indicates the lightness (0 to 100), a* shows (+red/-green), and b* is (+yellow/-blue). Therefore, the total color difference (∆E) index was calculated with Eq. 5 (Niroomand et al. 2016):

 (5)

Atomic force microscopy

The surface roughness of the fabricated films was analyzed using an atomic force microscope (AFM) (NanoWizard; JPK Instruments AG, Berlin, Germany). The samples were placed on a glass lamella, and the measurement was taken in a 10 µm × 10 µm area using the tapping mode. Then, the obtained root mean square (RMS) roughness data were analyzed.

Statistical analysis

To identify the statistically significant differences, an analysis of variance (ANOVA) was performed (SPSS software, SPSS Inc., Version 16.0, Chicago, USA). The obtained data were presented as mean ± standard error, and probability values less than 0.05 were considered significant.

RESULTS AND DISCUSSION

Following the pulping process, the average pulping yield and lignin content were approximately 52% and 2%, respectively. The Kappa number of the unbleached pulp samples was 16.5.

In addition, the DP of cellulose for BFF and UFF were tested (Table 1).

Table 1. The DP of Cellulose for Unbleached and Bleached Fiber Fines

Dissolution of various fines in the IL

The dissolution of cellulose materials in common solvents is difficult due to their highly-ordered crystalline domains, powerful intermolecular and intramolecular hydrogen bonding, and high degrees of polymerization (Song et al. 2013; Soheilmoghaddam et al. 2014).

Figure 1 shows microscopic images of lignocellulose fines in the early stages of the dissolution process. Figure 1 demonstrates that there was no observable visual development in the dissolution process of the RBF in the IL even after more than 12 h (Fig. 1c). In contrast, the papermaking UFF disappeared visually in less than 1 h in the IL. For the BFF, the process took approximately 15 min (Fig. 1a). This indicated that the delignification process (especially pulping) facilitated dissolution, as during pulping and bleaching, lignin, which acts as a binder between carbohydrates (hemicelluloses and cellulose) to form the complex and compact structure of lignocellulose materials (Wang et al. 2011), breaks down and is partially removed. The complex and dense structure of the original lignocellulose material between lignin, cellulose, and hemicellulose inhibits the diffusion of ionic liquid into the interior, but following pulping and bleaching, it becomes more accessible (Kilpeläinen et al. 2007).

The results in Table 1 indicate that the dissolution stage was aided by the lower lignin content and DP of cellulose in BFF than UFF due to the chemical processes in bleaching.

Fig. 1. Microscopic images (magnification: 250x) comparing the lignocellulose fines in the IL: a) bleached fiber fines, b) unbleached fiber fines, and c) raw bagasse fines, at the first min (top row) and 15 min after stirring in the IL (bottom row)

Morphological studies

The micrographs from the cross-section of the fabricated film specimens are presented in Fig. 2. The images show a uniform dense matrix, in which an even context with no gap is observed (Fig. 2). Therefore, the ionic liquid was able to penetrate the amorphous structures between micro/nanofibrils to dissolve the lignocellulose material. Eventually, by adding water to form a gel film, the dissolved, dispersed sections coagulated and formed an even contiguous layer. Yousefi et al. (2011) reported that the intact parts of the original nanofibrils in this structure are embedded among the regenerated sections.

Figure 2 indicates that no obvious difference was observed between the films produced from UFF, BFF, and the BFL. Especially in the case of lignin containing films, either separation of lignin or agglomeration of lignin particles in the film structure was not observed.

Fig. 2. The FE-SEM images (at 5 kX and 75 kX magnifications) from the cross-section of the fabricated film specimens (a. UFF, b. BFF, and c. BFL)

FT-IR spectroscopy

Figure 3 compares the recorded FT-IR spectra of BFF, UFF, lignin, and those of their produced films. In all spectra, the broad band in the 3000 cm-1 to 3600 cm-1 region, and the peaks at 2850 cm-1 to 2950 cm-1 and 850 cm-1 to 1160 cm-1, were assigned to the hydroxyl (–OH), C–H ,and C–O stretching vibrations, respectively. The peaks located at 1427 cm-1 and 1365 cm-1 were assigned to C–H / CH2 bending vibrations (Abdolkhani et al. 2013; Sohehilmoghaddam et al. 2014; Niroomand et al. 2016). For the soda lignin of bagasse, the assignments at 1596 cm-1, 1512 cm-1, and 1458 cm-1 were attributed to the symmetric stretching, the asymmetric stretching of the aromatic ring, and the asymmetric C-H bending in lignin, respectively (Sammons et al. 2013; Stark et al. 2016).

Fig. 3. The FT-IR spectra of the BFF, unbleached fiber fines, soda lignin of bagasse, and the films fabricated from these lignocellulose materials

The similarity of the spectra (with negligible shift or intensity difference) of the regenerated film samples and their original raw cellulose materials (fiber fines) indicates that, during the fabrication of the cellulose films, hydrogen bond breaking and cellulose regeneration primarily occurs rather than cellulose derivatization and side reactions. Notably, the assignments typically indicating the presence of the ionic liquid were not observed, demonstrating that IL was successfully removed following the washing process (Niroomand et al. 2016).

XRD analysis

The X-ray diffraction patterns can present useful information about transformations in the crystalline structure of cellulose (Zugenmaier 2008; French and Santiago Cintrón 2013; French 2014). Figure 4 shows the XRD patterns for the initial lignocellulose materials compared with the fabricated film specimens. The BFF and UFF diffraction graphs exhibited peaks at 2θ = 15.9°, 22.5°, and 34.7°, with the most intensity observed at 2θ = 22.5°. This pattern resembles the typical spectra of native cellulose (cellulose type-I) (Fort et al. 2007; Jiang et al. 2012; Niroomand et al. 2016), indicating the structure of cellulose material before treatment with the IL.

Fig. 4. The XRD diagrams of a) BFF, b) UFF, c) regenerated BFF film, d) regenerated UFF film, e) regenerated BFL film, and f) lignin

However, the XRD diagrams of the regenerated films showed only one broad peak around 2θ = 20°. The broad full width at half maximum (FWHM) of the peak for the regenerated samples could be attributed to the formation of smaller regenerated cellulose crystallites and the less ordered domains in the regenerated cellulose material due to the treatment with the IL (Cheng et al. 2011; Samayam et al. 2011; Jiang et al. 2012). Further, as the height of the peak with the maximum intensity decreased following processing with the IL, Segal’s formula (Eq. 1) demonstrated that the crystallinity index diminished from approximately 80% before dissolution to 22% following treatment with the IL and the regeneration process. These results indicated the regenerated films predominantly consisted of amorphous regions (Abdulkhani et al. 2013; Soheilmoghaddam et al. 2014). This reveals that the fiber fines were readily affected by the IL within the short treatment period, which confirms the simplicity and workability of papermaking fiber fines relative to other reports for cotton fiber, linter, or dissolving pulp (Kilpeläinen et al. 2007; Pinkert et al. 2009).

Mechanical strength

The tensile strengths (TS) and tensile moduli (TM) of the fabricated film samples were studied (Fig. 5). Figure 5 shows that BFF films had the highest TS and the lowest TM compared to the lignin-containing film specimens. This may have been due to final consequent of the opposite effect of lignin, which negatively affects bonding, versus higher DP of cellulose chain, which helps the film strength properties (Wu et al. 2009; Abdulkhani et al. 2013).

Fig. 5. Strengths properties of the films: a) tensile strength and tensile modulus, b) elongation at break

The UFF film samples showed less TS (123.69 MPa ± 9.9 MPa), but the cellulose possessed higher DP among these fiber fines. The BFL films exhibited the least TS (107.35 MPa ± 10.8 MPa) due to having lower DP of cellulose and added lignin. Figure 5 indicates that the lignin caused reduced elongation at break (EAB).

Surface roughness of the films

Surface roughness data can help to quantify the smoothness of the films, which can affect other parameters (Niroomand et al. 2016). Figure 6 shows AFM illustrations of the surfaces of the films. The RMS values and the vertical scale indicating the spatial variance between the highest and lowest points are presented in Fig. 6.

The images in Fig. 6 do not indicate a clear difference between the specimens. This confirms the expectation that differences in the surface roughness of the films would not have a significant effect on other related results, such as transparency and contact angle.

Fig. 6. The AFM images illustrating the surface roughness of a) BFF films b) UFF films, and c) BFL films

Wettability and hydrophobicity

Because the hydrophilic nature of the films could affect their application, the water absorption (WA) of the samples were studied (Fig. 7). Figure 7 demonstrates that during the first 2 h following immersion in water, the weight of all the film specimens increased by over 45%. However, after 72 h, all the WA diagrams reached their respective maximum values (BFL: 73%; BFF and UFF: approximately 90%).

Fig. 7. The WA of the samples

Analogous results were previously observed for regenerated cellulose film specimens (Mahmoudian et al. 2012; Soheilmoghaddam et al. 2014). Unexpectedly, the diagrams also revealed that the WA results of the UFF films more closely resembled the BFF films than the BFL samples (Fig. 7). This may be due to initial extraction of lignin and then its addition to the cellulose material, which has intensified its effects.

Table 2 presents the CA of water droplets at the collision moment and after 10 s. The BFF films had relatively wettable hydrophilic surfaces with low CA reductions during the specified time (Mahmoudian et al. 2012). The higher CA of the UFF and BFL films was due to the presence of lignin. Simmons et al. (2011) reported that lignin diminishes the availability of hydroxyl groups and interferes with their hydrophilic effect on the film surface. Therefore, for the BFL film (with 2% lignin added), the CA increased to more than 99° (relatively hydrophobic).

Table 2. The CA Data

Optical properties

Because the color parameters and transparency (Tr) of a film are essential for certain applications, the relevant data is presented in Fig. 8 and Fig. 9.

Figure 8 comparatively presents the transmittance data of the films made from bleached/unbleached fiber fines between 200 nm and 800 nm. Although the figure indicates similarly high Tr for all samples in the visible wavelength range, the lignin-containing specimens (UFF and BFL films) had lower Tr. In addition, the-lignin containing films showed more UV radiation absorption, especially for wavelengths less than 300 nm.

Fig. 8. Transparency of the fabricated films

In addition, the Op test, a well-known method for the comparison of films at a specific wavelength (600 nm), considers film thickness (Eq. 4) (Abdollahi et al. 2012). Therefore, the thickness variations of the films could not distort the test results.

Figure 9 compares the Op of the fabricated film specimens. The Op results confirmed the results of Tr testing.

The appearances of the produced film specimens are compared in Fig. 10. In addition, quantitative evaluation data on the color values of the samples are presented in Table 3.

Fig. 9. Comparison of the opacity of the specimens (at 600 nm wavelength)