NC State
BioResources
P. Noé and F. Henry. Hydration of refined chemical pulps studied by microwave spectrometry. In Fundamentals of Papermaking, Trans. of the IXth Fund. Res. Symp. Cambridge, 1989, (C.F. Baker & V. Punton, eds), pp 105–120, FRC, Manchester, 2018.

Abstract

A bleached sulfate pulp has been refined in a disk refiner to different degrees : from 15 to 75° SR (720 to 70 CSF) . Different water contents ranging from 40 to 90 % by volume (70-90 % by weight) , have been obtained by centrifugation of small samples of ca.30 mg o.d. weight. The samples have been analyzed by microwave spectrometry performed in a cavity at 5 GHz. The theory of small perturbations of a resonant cavity allows the determination of the dielectric losses Es of the hydrated material. The slope of the lines : Es vs. moisture content is an index of the hydration of pulps. At the same water content (in the range 70 to 90 % by weight) , we have shown that refining increases the hydration, which can be defined as the transformation from free water to bound water.


Download PDF