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Song, X., Bie, R., Ji, X., Chen, P., Zhang, Y., and Fan, J. (2015). "Kinetics of reed black liquor (RBL) pyrolysis from thermogravimetric data," BioRes. 10(1), 137-144.

Abstract

The pyrolysis of reed black liquor (RBL) was studied in nitrogen atmosphere by thermogravimetric analysis at six different heating rates of 5, 10, 20, 30, 40, and 50 ˚C·min-1 from ambient temperature (25 ˚C) to 800 ˚C. Thermogravimetric (TG) and differential thermogravimetric (DTG) curves were obtained. The results show that there are three main weight-loss stages in the temperature ranges of 180 to 350, 350 to 560, and 560 to 800 ˚C, for which the error is about ± 10 ˚C. The kinetic parameters were determined by the Coats-Redfern method. A kinetic compensation effect (KCE) between activation energy (E) and pre-exponential (A) factor also was found.
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