Abstract
Foam forming technology has attracted much attention during the past few years in the paper industry. Its advantages compared to conventional water forming are a new product portfolio and increased process efficiency. To support the paper industry in pushing foam forming technology forward, process simulation is needed to provide supporting data for strategic decision-making and as a basis for equipment dimensioning. This study examined the conversion of an existing wallpaper machine from water to foam forming technology using process simulation. To determine the required process configuration and parameter changes in the existing process, both published and unpublished data on the foam forming process were collected. This paper also describes modeling of the foam phase in the selected simulation software. The suitability of existing paper process equipment for foam was analyzed. Simulations revealed that undisturbed operation with foam requires some equipment modifications and re-arrangements in water circuits. With foam forming, the water balance in both short and long circulation changes remarkably compared to conventional water forming, leading to a large increase in the long circulation volume flows.
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Process Simulation-based Evaluation of Design and Operational Implications of Water-laid Paper Machine Conversion to Foam Technology
Lotta Sorsamäki,a,* Antti Koponen,a and Eemeli Hytönen b
Foam forming technology has attracted much attention during the past few years in the paper industry. Its advantages compared to conventional water forming are a new product portfolio and increased process efficiency. To support the paper industry in pushing foam forming technology forward, process simulation is needed to provide supporting data for strategic decision-making and as a basis for equipment dimensioning. This study examined the conversion of an existing wallpaper machine from water to foam forming technology using process simulation. To determine the required process configuration and parameter changes in the existing process, both published and unpublished data on the foam forming process were collected. This paper also describes modeling of the foam phase in the selected simulation software. The suitability of existing paper process equipment for foam was analyzed. Simulations revealed that undisturbed operation with foam requires some equipment modifications and re-arrangements in water circuits. With foam forming, the water balance in both short and long circulation changes remarkably compared to conventional water forming, leading to a large increase in the long circulation volume flows.
Keywords: Paper machine; Foam forming; Process simulation; Water balance; Process configuration
Contact information: a: VTT Technical Research Centre of Finland Ltd, P.O. Box 1603, 40101 Jyväskylä, Finland; b: VTT Technical Research Centre of Finland Ltd, P.O. Box 1000, 02044 VTT, Finland;
* Corresponding author: lotta.sorsamaki@vtt.fi
INTRODUCTION
Changes in the global paper industry during the past 10 years have increased the need for more cost-efficient processes and production technologies and even entirely new products. The demand for printing papers is decreasing along with a rapid growth in demand for packaging and tissue products. Papermakers must discover new solutions for their existing production lines. How valuable would it be if an existing production line could be used to produce higher value or even entirely new products? To respond to this challenge, foam forming technology has attracted much attention during the past few years (Lehmonen et al. 2013; Kinnunen-Raudaskoski 2017; Kiiskinen et al. 2019; Lehmonen et al. 2019). Foam forming utilizes small air bubbles (average bubble radius < 100 µm) containing aqueous foam instead of pure water as a process fluid and flowing medium. The fiber-foam mixture is generated by introducing a foaming agent, i.e., surfactant, to the pulp suspension, followed by intensive mixing with air. In the 1970s, foam forming was introduced as a way to replace water in papermaking (Radvan and Gatward 1972; Smith et al. 1974; Tringham 1974; Punton 1975a, 1975b; Smith and Punton 1975). The technique was called the “Radfoam process”. While some paper machines were modified to accommodate foam forming, the technique was not widely adopted by the paper industry at that time. However, foams have since been used by some manufacturers in the non-woven industry for handling long fibers (Hanson 1977). Generally, foams are widely used in many industrial applications, including the food, petroleum, and gas industries, as well as firefighting (Exerowa and Kruglyakov 1998; Weaire and Hutzler 1999).
The advantages of foam forming compared to water forming include 1) remarkable improvement in end product uniformity (i.e., good formation); 2) the possibility of producing highly porous and bulky products, saving raw material and lightening current products; 3) the production of uniform webs from longer and coarser fibers; 4) increased dryness after wet pressing, saving energy during drying (Torvinen et al. 2015; Koponen et al. 2016; Kiiskinen et al. 2019; Lehmonen et al. 2020); and 5) high layer purity in stratified forming e.g., in the production of board (Kiiskinen et al. 2019). The potential to introduce “difficult” raw materials such as long synthetic or manmade fibers to the papermaking process enables the manufacturing of novel products in an existing production line. Strength properties (both in- and out-of-plane) of water-formed samples are usually better than those made using foam forming. However, the mechanical properties of the foam-formed products may be affected by the different surfactants (i.e., anionic and non-ionic) used in the foam forming process. Lappalainen et al. (2014) presented that the effect of the strength additive (cationic starch) in increasing the strength of foam-formed samples was less in the presence of anionic surfactants than with non-ionic surfactants. Both Lappalainen et al. (2014) and Zeno et al. (2005) pointed out that ionic surfactants were more harmful to sizing than non-ionic surfactants. The conversion of existing production lines from conventional water forming technology to foam forming technology producing higher value products and/or even new products improves the competitiveness of the plant and lengthens the lifetime of the production line.
While the second wave of foam forming has now begun in Finland, foam forming has been explored on a laboratory scale already by many international research organizations. At the pilot scale, all the published studies have thus far been performed at the VTT Technical Research Centre of Finland Ltd. (VTT). Many aspects of foam forming have already been studied, including 1) the generation of foam and resulting foam properties, such as air content, bubble size, and half-life time (Al-Qararah et al. 2013, 2015b); 2) the nature and behavior of the foaming agent (Lappalainen et al. 2014; Mira et al. 2014; Gottberg et al. 2019); 3) methods for evaluating the bubble size distribution (Lappalainen and Lehmonen 2012; Koponen et al. 2019); 4) the macroscopic properties of foam-formed products (Lehmonen et al. 2013; Vähä-Nissi et al. 2018); 5) the pore structures of fiber networks of foam-formed fiber suspensions (Al-Qararah et al. 2015a, 2016; Koponen et al. 2017); 6) foam forming of long fibers (Koponen et al. 2016; Asikainen et al. 2020); and 7) the operational performances of individual process steps, such as foam generation (Koponen et al. 2018), forming (Koponen et al. 2016, 2018; Lehmonen et al. 2020), pressing (Torvinen et al. 2015; Järvinen et al. 2018; Lehmonen et al. 2020), and drying (Timofeev et al. 2016).
Switching from conventional water-laid papermaking to a foam-laid technology does not require replacing the major components of a production machine (Kiiskinen et al. 2019). However, the fundamental differences between water and foam that must be considered when designing a foam-forming machine are that 1) foam has a lower density and, by a few orders of magnitude, a higher viscosity than water, 2) foam is compressible, and 3) foam properties are dynamic (Kiiskinen et al. 2019). Dynamic here means that, due to drainage and bubble coalescence, the air and water phases easily become separated if the foam is not constantly mixed. All these properties affect the process.
To support the industry in pushing a new technology forward, process simulation is needed. It is a fundamental step in early-stage process design, one that is conducted alongside technology development and is a prerequisite for ensuring the economic sustainability of the process. With modeling and simulation, it is possible to evaluate different strategies for an existing process or a new one and to find the best strategies to decrease the production costs and increase the product’s added value. Process simulation and modeling are applied widely in various industries at different stages of the process design. The greatest advantage of simulation models would be obtained if they were built already in the design phase of a greenfield plant implementation project and utilized throughout the whole life cycle of the plant (Blanco et al. 2009). Although the pulp and paper industries have used balancing calculations and process control for a very long time, they have been more conservative in the use of computer-based modeling and simulation (Blanco et al. 2009). According to Blanco et al. (2009), this is largely because of the complex nature of the materials and the high degree of interaction between the various production processes. This statement is even more tenable for foam forming technology than for conventional water forming technology.
The historical perspective and future trends regarding the use of simulation in the pulp and paper industry have been reviewed by Dahlquist (2008) and Blanco et al. (2009). According to Blanco et al. (2009), steady state modeling of papermaking processes is challenging because papermaking is a process wherein the large amount of water and low efficiency of most of the separation steps make multiple recycling streams necessary. The level of detail in the simulation studies on conventional pulp and papermaking processes reported in the literature ranges from small-scale chemical reactions to mill-wide process calculations and from steady state to dynamic simulations. The steady state simulation studies have focused on 1) optimizing the raw material, fresh water, energy or utility consumption (Bortolin et al. 2004; Turon et al. 2005; Cardoso et al. 2009; Atkins et al. 2010; Ruohonen and Ahtila 2010; Jönsson et al. 2011; Mǎluţan and Mǎluţan 2013); 2) the build-up of dissolved substances (Sorsamäki et al. 2019); 3) studying the cost implications of different integrated modernization strategies (Hytönen and Stuart 2012); and 4) studying the chemical state of the plant (Clément et al. 2011; Huber et al. 2013). Although many studies have focused on dynamic simulation and paper machines, only a few approaches to the dynamics of a paper machine at an industrial scale are available (Blanco et al. 2009). These have focused on the transient behavior of wet-end (Orccotoma et al. 1997; Yeo et al. 2004), the improvement of fault detection (Cheng et al. 2008), and the identification of process bottlenecks (Savolainen and Lappalainen 2015). Several software packages exist for flowsheet-based mass balance calculations. When high-fidelity models of single pieces of equipment (e.g., paper machine dryers) are the focus, the models are typically programmed using FORTRAN, C++, or MATLAB and used without flowsheeting tools (Yeo et al. 2004; Blanco et al. 2009).
Although several studies on the modeling and simulation of conventional paper processes exist, no work to date has focused on the performance of the foam forming process using modeling and simulation. One reason for this may be that in the 1970s, when foam forming was introduced, process simulation was not as common as it is today as a process engineering tool. Currently, there is some industrial activity around foam forming. However, because the production volumes are so far small, and the technology is new and sensitive, the industry prefers not to publish any process data on foam forming. Another reason for the lack of simulation studies on foam forming may be the lack of proper handling of foam in existing simulation software. The nature of foam, like the modeling of it, is challenging. Foam itself is neither liquid nor gas, but it is a more-or-less uniform mixture of air bubbles in the water phase, which could even be called a separate “foam phase.” The air content in foam forming is typically 60 vol% to 70 vol%, but recent work has shown that foam forming also works well at as low as 30% to 40% air content (Torvinen et al. 2015). Most of the air exists in non-dissolved form as bubbles inside the liquid phase. The amount of dissolved air is marginal. Without proper modeling of the foam phase, the model does not give the true air amounts present in the streams nor the true volume flows of the streams. Without the volume flows, one cannot dimension the pipes or equipment. The volume flows are also needed to reveal any possible differences compared to the conventional water forming.
The main motivators prompting paper manufacturers to implement foam forming technology are the new product portfolio, energy efficiency, and savings in the raw material costs. In addition to the process benefits and product quality improvements verified in several foam forming laboratory trials and pilot-scale runs, process simulation is needed to provide preliminary mass, volume, and energy balances of the foam forming process to create a basis for equipment dimensioning. Together, they will support the process engineering and the strategic decision-making for investing in this new technology. Instead of implementing a greenfield foam forming process, one relevant implementation strategy would be to convert an existing water-laid process to a foam-laid process. In this case, process simulation is needed to reveal bottlenecks in the existing process due to the presence of foam.
Objectives
Because the use of simulation to support engineering has proven beneficial, it makes sense to focus on developing modeling techniques to overcome the shortcomings of commercial simulation tools. Such a focus will enable similar simulation capabilities for foam processes as currently exist for water-based systems. Therefore, this paper presents the required property calculations for describing foam in the used simulation platform. This paper also presents a systematic approach to examine, via steady state process simulation, the conversion of an existing paper machine from water-laid technology to foam-laid technology. The overall approach consists of three main steps that are very tightly bound together; 1) modeling of the existing water-laid paper machine; 2) modeling of the conversion of the water-laid paper machine into a foam-laid paper machine; and 3) the model-based, design-based and operation-based comparison of the above two concepts. In the model-based comparison, the authors present the challenges of modelling a foam-laid process in comparison with modelling of a water-laid process, wherein the proper handling of foam phase being the main modelling challenge. In the design-based comparison, the above two concepts are systematically compared to find out whether all parts of the system would be retained or some new parts would be implemented when switching from a water-laid process to a foam-laid one. In the operation-based comparison, the simulation results are utilized to compare these two processes based on their mass, volume, and energy balances with an emphasis on volume flows, foam density levels, and surfactant concentrations throughout the processes. Paper properties were not within the scope of this study. Thus, this three-step approach will reveal the necessary process configuration changes and possible bottlenecks in the existing process. Given these targets, steady state simulation is a sufficient tool, and dynamic simulation is not needed. To justify all the modifications implemented to the reference water-laid process to convert it to a foam-laid process, it was essential to collect all relevant information from the existing literature and experiences in VTT’s foam forming laboratory studies and pilot runs. Thus, this paper is both a simulation case study and a review of the foam forming process on a plant-wide level.
EXPERIMENTAL
Overall Approach
The overall approach taken in this study was steady state simulation-based process concept design and evaluation. After defining the scope of the case study, including design- and operation-related questions, ideas for possible concepts to study the questions were defined, and available design and operation data and information were gathered for both the reference water-laid concept and the foam technology. The reference concept simulation model was developed and validated with real process data. The foam technology concept model was developed and used to study the process design and operations to identify any unknown parameters. Pilot plant data was used to validate corresponding parts of the model. Further experimental work was performed to fill in some of the gaps in the datasets. Clarifying experimentally some of the key design parameters would have required major modifications to the experimental setup. The implications of these parameters for the overall design and operation of the foam-based process were studied using separate designs of the concept and possible parameter values were defined based on simulating these designs. After fixing all model parameters, the simulation model results for the final concepts were compared to the reference model results to answer the original questions.
The simulation study was conducted with Balas (v3.3, VTT Technical Research Centre of Finland Ltd., Espoo, Finland), which is a steady state simulation software for assessing chemical processes with an emphasis on pulp and paper, food processing, and biochemical processes. The software uses Microsoft Visio (2013) as a flowsheeting tool and is equipped with a Microsoft Excel (2016) spreadsheet software link. This link allows the user to access all of the simulation software model parameters, manipulate input data, and process the simulation results further within the spreadsheet software.
Case Study Scope
This process simulation study was set up to systematically provide information on the engineering questions related to the technology switch. The specific design-related (#1 to #6) and operation-related (#7 to #9) questions were as follows:
- How does the existing equipment operate with foam?
- Is there a need to re-arrange the process streams and/or water circuits?
- Is there a need for new equipment?
- Is there a need for changes in the forming section?
- Do the increased stream volumes necessitate increasing the capacity of the existing equipment?
- Does the presence of surfactant cause a remarkable increase in the wastewater treatment plant (WWTP) capacity?
- What are the surfactant concentrations in process waters?
- What are the foam densities in process waters?
- Are any savings achieved in drying steam consumption?
Reference Paper Machine
The reference paper machine was a real-life wallpaper machine producing wallpaper from a mixture of softwood and hardwood bleached kraft pulp (SW-BKP and HW-BKP), chemi-thermomechanical pulp (CTMP), and polyethylene terephthalate (PET) fiber. When producing wallpaper, the machine experienced some handling problems with the long PET fiber as well as some quality issues. The most direct advantage of foam forming is the potential to produce quite uniform webs with good formation from longer or coarser fibers. This aspect is one of the main motivators for the reference company to consider converting its existing wallpaper machine to a foam-forming machine.
Figure 1 shows a block diagram of the reference wallpaper machine. It includes the following areas: the stock preparation area; the forming, pressing, and drying zones; the machine white water network; and the wet-broke re-pulping system. The wood-based furnishes (SW-BKP, HW-BKP, and CTMP) are first pulped, cleaned in a high consistency cleaner (HCC), homogenized in a deflaker, and then refined in conical refiners (i.e., “conflos”). Next, the pulped PET fiber is introduced to the process. When long PET fiber is used, the double disc refiners (DDRs) are not used. Before cleaning it in the low consistency cleaners (LCCs) and screening it, the mixed pulp is diluted in several stages with white water (W/W) from the settling tank. Wire water from the white water tank is used for the dilutions in low consistency cleaning and screening. The pulp stream is at 0.75 wt% consistency when it is delivered to the headbox (HB). The Fourdrinier type of former consists of hydrofoil and vacuum boxes. In the press section, there are two single-felted press nips and a smoothing roll. Surface sizing is applied at the size press located between the pre- and after-dryers. Only wet broke (“trim”) is recycled. Fiber is recovered from the press water and any surplus wire water with a valveless filter. Chemicals are added to the mixing box and to the size press. Freshwater (here “reuse water”) intake to the paper machine occurs through wire and felt showers and cleaning. Rejects from cleaning and screening are treated as the paper machine (PM) effluent in the WWTP.
Modeling Strategy
The modeling strategy of this study was divided into the following five steps:
- Development and validation of the water-laid concept model
- Development of the foam-laid process design and concept model
- Case definition
- Simulation of the selected cases
- Comparison of the selected cases
- Development and validation of the water-laid concept model
Assumptions for the water-laid concept model
The main assumptions for steady state balances for the water-laid process were:
- The chemical components in the model were Water, Pulp (describing the mixture of SW-BKP, HW-BKP, and CTMP), PETfibre, and Chemical (describing all types of basic-papermaking chemicals).
- Dissolved and colloidal substances were not modeled.
- No fiber length classification was considered in this study.
- The model was developed at atmospheric pressure.
- The density of the fiber-water suspension was assumed to be constant, 992 kg/m3.
- The energy balance calculation was less emphasized.
Fig. 1. Block diagram of the reference wallpaper machine. Yellow circles mark the points in the process where the water-laid process is compared with the foam-laid process.
When modeling the system at atmospheric pressure, the mass flows are correct. However, the volume flows are unknown because there is overpressure in the pipes, which decreases the volume flow of a compressible fluid. Pilot runs by VTT suggest that the overpressure is at most a few tens of kilopascals, i.e., much lower than in conventional paper machines. This is due to the machine speed being rather low and because the viscous losses of foam do not increase the pressure levels remarkably. With, for example, 40 kPa of overpressure, the volume of the used foam decreases by only 9%. The fiber-water suspension is thus almost incompressible, and it is justified to assume that no changes in volume flows occur. The volume flows of streams were calculated separately in Excel from the simulated mass flows using the constant density (992 kg/m3).
The modeling of the energy balance was less emphasized. Only the consumption of steam in the dryers was calculated. The energy consumption of process pumps, drying air compressors, and other process equipment were not considered, nor were heat exchanges between any equipment and its surroundings considered.
Definitions for the water-laid concept model
Figure 2 presents the overall flowsheet of the water-laid simulation model containing four sub-models. In addition to the detailed modeling of the paper machine, freshwater production, the wastewater treatment plant, and chemical preparation were modeled in less detail. This overall flowsheet is identical for both the water-laid and foam-laid concept models.
Fig. 2. Overall flowsheet of the simulation model describing the reference wallpaper machine. In addition to the paper machine, freshwater production, wastewater treatment, and chemical preparation were modeled. The overall flowsheet is identical for both forming technologies. The differences in the two technologies are shown in the Paper machine sub-model (presented in the supplementary material, Figs. S1 to S3).
The differences in the process configurations (i.e., equipment and stream connections) of these two concept models can only be seen in the Paper machine sub-model (Figs. S1 to S3, supplementary material). The rest of the sub-models, Chemical preparation, Wastewater treatment, and Freshwater (Figs. S4 to S6, supplementary material), were identical in both concept models regarding the process configuration. However, there were differences in the process stream data.
The Paper machine sub-model included all the unit operations presented in the block diagram for the reference machine. The main parameters defining the water-laid paper machine are presented in Table 1. The targeted basis weight was 95 g/m2, the annual production capacity was 13 800 tons (1.73 t/h), and the forming consistency was 0.75%. (In paper making, including foam forming, consistency is a key parameter defined as the mass of the pulp fibers to the total mass of the suspension. As the density of air is negligible compared to that of water and cellulose, its mass can be neglected when calculating the consistency of fiber foams used in foam forming.) The Freshwater sub-model described the production of freshwater. Freshwater was produced at the mill from several water fractions and used as sealing water, liquid ring vacuum pump water, cooling water, maintenance washing water, and chemical dilution water. Wastewater flows to the Wastewater treatment sub-model consisted of sealing waters, liquid ring vacuum pump water, and paper machine (PM) effluent. One third of the treated effluent was discharged from the site as “clean water.” Two thirds of the treated effluent was recycled back to the mill to be used either in freshwater production or as reuse water in showers, wire cleaning, and felt cleaning in the paper machine. The modeling of the WWTP was less emphasized because the authors were only interested in the increase in the chemical oxygen demand (COD) in the WWTP feed due to the foaming agent present in the foam forming process. The detailed modeling of different basic papermaking chemicals was not relevant at this point, as it was uncertain how the conversion from a water-laid paper machine to a foam-laid paper machine affects the dosages and activities of the basic papermaking chemicals. In the model, all individual chemical dosages were summed together. Half of this chemical amount was dosed to the mixing box, and half was dosed to the size press. Thus, only the effect of the chemicals on the mass balance, not on paper chemistry, was considered.
The water-laid process model was validated using real-plant process data provided by the reference mill. The selected parameters were temperature, capacity, consistency, flow rate, and dryness level. At points where measured data was lacking, the data were estimated based on general process expertise. Because the provided data were exceptionally good, validation of the model was simple, and the results of the water-laid model were robust. The model predicted the state of the water-laid wallpaper machine quite accurately.
- Development of the foam-laid process design and concept model
Assumptions for the foam-laid concept model
The main assumptions, in addition to those presented above for the water-laid process, when establishing steady state balances for the foam-laid process were as follows:
- Additional chemical components were FoamChem (describing the surfactant) and Nitrogen&Oxygen (describing the air).
- The bubble size distribution of the foam was not considered.
- The density of the fiber-water-air suspension was calculated by considering the air density in prevailing conditions and the air content.
- An ideal mixing was assumed everywhere in the model.
- Re-foaming due to geometry (present in pipe angles and pumps), shear forces (cyclones, wire section), or mixing was not considered.
- The fiber retentions in the forming and press sections and the efficiencies of the fiber recovery systems were assumed to be the same for both the water-laid and foam-laid concept models.
- The steady state model did not consider equipment dimensions and material hold-ups.
- Surfactant affects the foam properties and foam generation, but linking surfactant properties to foam density was beyond the scope of this study.
For a compressible fluid like air, as the pressure doubles, the volume is halved. For the fiber-water-air suspension, the assumption of modeling the system at atmospheric pressure is a reasonable simplification because only the air is compressed, and the overpressure in the pipes is relatively low. At this point of the engineering work, the authors were not interested in designing the pipes. Instead, the primary interest was what occurs when the system is at atmospheric pressure. Thus, the calculated volume flows were correct for most of the points. Only those points with minor overpressure were slightly overestimated.
The assumption of ideal mixing is debatable. In reality, a density profile inside the tanks exists, and it depends on gravity, mixing, tank geometry, foam stability (half-life time), and surfactant concentration. It is possible to find several foam fractions with different foam densities inside the same tank. Low-density froth typically piles at the top of the tank, while it is possible to obtain high-density foam, almost to the point of being water, from the bottom of the tank. Re-foaming occurs if a foamable liquid, i.e., a water phase containing enough surfactant, is exposed to mixing or shear forces.
Modeling of foam and density calculation
To achieve the main objective of this study, i.e., creating the basis for equipment dimensioning of the foam-laid process, it is necessary that the used simulation platform contains the needed foam property calculations. In the used simulation software, foam was described as two separate phases, water and air. The presence of air in the foam forming process challenges the material balance calculation in traditional simulation software. All process simulators base their material balance calculation on mass units (e.g., kg/s). This causes no problems with conventional water forming. Because the density of dilute fiber suspensions is approximately 1000 kg/m3, the mass flows equal the volume flows (1000 kg/s ≈ 1000 L/s). However, in a foam forming process with a foam density of, for example, 500 kg/m3, the mass flow is the same as in the water-laid process (1000 kg/s), as the mass of air is negligible. At constant stock consistency, however, the volumetric flow is double (2000 L/s), due to the presence of air. (Notice that in water forming, the volume fraction of the fibers depends on the consistency, while in foam forming it depends both on the consistency and the air content of the fiber foam. This has to be taken into account e.g. in the calculation of the crowding number of fiber foams (Koponen et al. 2016)). For sizing the pumps and tanks involved in the foam forming process, volume flow rates need to be identified. Unfortunately, most simulators do not provide liquid density calculation for the conversion of mass flows into volume flows. Because density was not among the calculated parameters in the used simulation software, a separate calculation procedure was created in the spreadsheet software to calculate the density of air present in the stream in prevailing conditions using the ideal gas law. The density of the fiber-water suspension was assumed to be constant (992 kg/m3) irrespective of the process conditions, as the temperature changes occurring in the process are moderate. The volume flows for the air phase and the fiber-water phase were calculated based on the mass flows using the density calculated for air and the constant density for the fiber-water suspension. Finally, the foam density was calculated by dividing the total mass of the foamy fiber suspension (weight of air was ignored) by the total volume of the foam, i.e., the combined volume of the fiber-water suspension and air. When modeling foam forming processes, this additional density calculation must be done with all process simulation software that does not already contain it.
Modification strategy
After developing, validating, and simulating the process model for the water-laid wallpaper machine, the model was modified to correspond to the foam-laid process. For modeling and parameterizing the foam-laid process, the authors defined the needed changes in the process configuration and parameters based on theories derived from the laboratory trials, pilot runs, and studies conducted at VTT, as well as knowledge of the steady state operation. The implemented changes in the parameters and process configuration of the water-laid process model when converting it to a foam-laid process model are discussed in detail below.
Modifications to the main parameters
The modifications to the main parameters are presented in Table 1. With foam forming, it is possible to consistently obtain a noticeable improvement in the end product’s uniformity and formation. With foam, improved water removal (see below) in the press section permits the use of lower loads in wet pressing, resulting in lower density (higher bulk) of the end product compared to those produced by water forming (Punton 1975a; Kinnunen et al. 2013; Torvinen et al. 2015; Kiiskinen et al. 2019; Lehmonen et al. 2020). A clear increase in bulk, however, is not always noticeable (Koponen et al. 2016, 2018). Bulk improvement is greatest with stiff fibers; bulk diminishes with an increased level of refining. For this study, it was assumed that foam forming would yield a 10% bulkier end product with equal quality properties to those achieved with water forming. Thus, the wallpaper basis weight was decreased by 10% from 95 g/m2 to 86 g/m2. By keeping the running time (8000 h/a), machine width (1340 mm), and machine speed (225 m/min) unchanged, the same number of square meters of wallpaper was produced with both technologies. Due to the 10% lower basis weight, the mass-based production capacity decreased by 10%, from 1.73 t/h for the water-laid process to 1.56 t/h for the foam-laid process.
In conventional paper and board production, with increased forming consistency, fiber flocculation tends to occur, which weakens the web formation (Lehmonen et al. 2019). Foam forming technology, in contrast, permits higher forming consistency and improved formation simultaneously. Various studies (Punton 1975b; Smith and Punton 1975; Lehmonen et al. 2013; Torvinen et al. 2015; Koponen et al. 2016, 2018) have shown that the headbox consistency may even be doubled for foam without any major loss in the formation uniformity. For this study, the headbox consistency in the foam-laid model was assumed to double from 0.75% to 1.5%.
At the beginning of the forming section, the dewatering of foam with hydrofoil boxes is most likely not as effective as the dewatering of water. This was taken into account in the foam-laid model by decreasing the end dryness level after the hydrofoil boxes from 1.9% for the water-laid process to 1.7% for the foam-laid process. Foam forming often increases the effects on the dryness level after the forming section (Koponen et al. 2016, 2018; Lehmonen et al. 2019), and the difference increases with increasing surfactant dosage mainly due to the reduced surface tension and subsequent decrease of capillary forces (Lehmonen et al. 2020). The increase in dryness is typically greater with mechanical pulp than chemical pulp. However, VTT’s pilot trials have occasionally shown no improvement in the dryness level after the forming section. For example, Lehmonen et al. (2019) observed no improvement in the dryness level with a foam density of 600 kg/m3. To be on the safe side in this study, the dryness level after the forming section remained unchanged in the foam-laid model compared to the water-laid process.
The dryness levels are often higher after the press section with foam forming compared to water forming (Torvinen et al. 2015; Koponen et al. 2016, 2018; Lehmonen et al. 2020). The increase in dryness may be due to foam forming increasing the number of large pores in the sheet, which leads to increased sheet permeability (Koponen et al. 2017). Pilot trials at VTT with a single extended nip press have shown that with foam forming, 2-percentage-point to 8-percentage-point higher dryness levels after the wet press are usually achieved, depending on the furnish type. Notably, the press type used in the pilot trials differs from the press type used on the industrial scale. The increases in dryness levels after the press section are noticeable with mechanical pulp, while for chemical pulp, the effect of foam forming on the dryness is smaller (Lehmonen et al. 2019). With VTT’s pilot machine, the dryness levels after the press section have even exceeded 50% for stiff natural fibers. When long synthetic fibers have been included, dryness levels as high as 60% have been obtained. The increased dryness leads to remarkable energy savings during thermal drying. For this study, the dryness level after the press section in the foam-laid model was assumed to increase by 5 percentage points compared to the water-laid process. The dryness levels after the pre-dryer and after-dryer were assumed to be the same for both forming technologies. The surface sizing applied at the size press between the pre- and after-dryers decreases the dryness level temporarily.
The recipe in both processes was the same: a mixture of SW-BKP, HW-BKP, CTMP, and PET fiber. The nominal freshwater consumption (m3 / t paper) and dosage rates for basic papermaking chemicals (t / t paper) remained unchanged compared to the water-laid case. These are, however, debatable assumptions, as it is uncertain how the presence of foam and surfactant affects the process purity and the activities of the basic papermaking chemicals compared to conventional water forming. Lengthier pilot trials are required to determine whether the accumulation of impurities will increase or decrease, causing a corresponding increase or decrease in the fresh washing water consumption rate. It is also unclear if, for example, the dosage of wet strength chemicals would need to be increased.
New main parameters
The fiber-foam mixture is generated by introducing a foaming agent, i.e., a surfactant, to the pulp suspension followed by intensive mixing or injection of air. An ideal surfactant should produce foam rapidly, provide the desired air content and sufficiently small bubble size (bubble diameter less than 100 μm), be cost-efficient, not have any harmful interactions with other process chemicals, and give additional functionality (wet/dry strength, porosity) to the foam-formed product (Gottberg et al. 2019). Mira et al. (2014) used seven surfactants in lab-scale foam forming tests and Lappalainen et al. (2014) used three surfactants belonging to different surfactant classes. Surfactants used in pilot-scale foam forming trials include sodium dodecyl sulfate (SDS) and polyvinyl alcohol (PVA) (Gottberg et al. 2019). The surfactant concentration in the process depends on the end application. As surfactant concentration increases, the produced foam’s stability also increases, and, consequently, bulkier products may be achieved. Typical SDS concentrations in VTT’s pilot trials have been 10 ppm to 290 ppm (Koponen et al. 2018), 40 ppm to 200 ppm (Koponen et al. 2016), or even up to 400 ppm, depending on the foam density level. The lowest concentrations (< 50 ppm) can only be used with inline foam generation when the foam’s half-life time is quite short. For this study, SDS was selected as the surfactant, and the SDS concentration at the headbox was set to 100 ppm (100 mg/L).
Typical foam densities in VTT’s pilot trials have been 400 kg/m3 to 600 kg/m3 (Koponen et al. 2016), 250 kg/m3 to 700 kg/m3 (Koponen et al. 2018), or 400 kg/m3 to 800 kg/m3 (Lehmonen et al. 2019). As foam density increases, the efficiency of water removal in the forming section also increases, and the required amount of surfactant decreases. For this study, the foam air content at the headbox was set to 40%, which means that the foam density was 600 kg/m3. With this foam density, a sufficient improvement in the formation was assumed to be achieved.
New equipment
The properties of the foam are a key issue affecting not only the performance of the forming process but also some important properties of the end product, such as the formation. Foams can be generated via either tank generation (Lappalainen and Lehmonen 2012; Al-Qararah et al. 2013; Jäsberg et al. 2015; Kouko et al. 2020) or inline generation (Koponen et al. 2018; Jabarkhyl et al. 2020a, 2020b). A tank generator consists of a stirring tank with a turbulent mixer without air injection. With inline generation, compressed air is injected into a pipe and mixed with water. The foam generation method affects the foam density, foam stability, and bubble size distribution (Al-Qararah et al. 2012; Kouko et al. 2020). Bubble size distribution is also affected by the amount of foaming agent and by the mixing energy (Jabarkhyl et al. 2020b; Kouko et al. 2020). An increase in the specific energy consumption decreases the bubble diameter (Al-Qararah et al. 2013; Kouko et al. 2020). An increase in the foaming agent dosage decreases the foam density and bubble diameter (Kouko et al. 2020). Inline generators generate a wider bubble size distribution with a greater share of large bubbles than tank generation. So far, foam generated with inline generators has not been as stable as foam generated in tanks (Koponen et al. 2018). The main advantages of producing the foam with inline generators located as close to the headbox as possible are smaller surfactant dosages than in tank generation and a restriction on the spreading of foam to all circulations. Tank generation with an adequate surfactant dosage generates a stable and uniform foam that has a narrow bubble size distribution with a large share of small bubbles (Al-Qararah et al. 2012, 2013; Koponen et al. 2018; Kouko et al. 2020). It is suitable for applications where high bulk is desired. For this study, it was assumed that with the foam-laid process, the foam would be generated with an inline generator. The inline generator is located on the approach pipe before the headbox. Air and surfactant are fed to the generator.
Surfactant recovery and recycling are essential for three reasons: 1) to increase the cost-effectiveness of the process by reducing the chemical costs, 2) to guarantee undisturbed operation of the WWTP, and 3) to avoid problems when using surfactant-rich water or a mixture of water and foam in the process. The recovered surfactant can be recycled back to the process to substitute for the makeup surfactant. With surfactant recovery, it is possible to obtain a surfactant-lean stream that can be used in positions where foam is not tolerated. Without surfactant recovery, the surfactant concentration in all water circuits would be virtually the same as at the headbox. In addition, a notable amount of surfactant would be lost along with the effluent to the WWTP. The most suitable methods for treating large amounts of surfactant-rich water are foam fractionation (Lee and Maa 1986; Boonyasuwat et al. 2003; Burghoff 2012) and membrane separation (Kowalska et al. 2004; Fernández et al. 2005). Fiber removal before the surfactant recovery step is crucial. Otherwise, there will be a frequent need to clean the surfactant recovery units. To guarantee a low total suspended solids (TSS) concentration in the feed to the recovery units, cartridge filters or bag filters may be used before introducing them. For this study, foam fractionation was selected as the surfactant recovery method. In foam fractionation, a surfactant-rich filtrate from the fiber recovery system (here “valveless filter”) is fed to a foam fractionation vessel where air is blown into the surfactant solution from the bottom of the vessel. Surfactant molecules attach themselves to the surface of the air bubbles and rise to the top of the vessel, where the surfactant-rich concentrate overflows into a foam resolution unit where foam is collapsed mechanically. Mechanical methods for collapsing foam include; 1) slowly rotating perforated centrifuges; 2) a rotating basket made of stainless steel; 3) discharging the foam on to a rotating disk; and 4) a suction device (Leonard and Blacyki 1978; Lee and Maa 1986; Burghoff 2012). The surfactant-rich fraction is recycled just before reaching the headbox to substitute for a major part of the makeup surfactant. The surfactant-lean fraction is removed from the bottom of the vessel. The acceptable surfactant concentration for the recovered lean fraction depends on the surfactant type. For SDS, the target concentration is less than 20 ppm of SDS. Based on laboratory trials performed at VTT, water containing less than 20 ppm of SDS should not re-foam even if exposed to mixing or shear forces. With 100 ppm of SDS in the feed to the surfactant recovery system, the target concentration for the surfactant-lean fraction is achieved by positioning two foam fractionation vessels in series. The surfactant-lean fraction is led to the white water tower (here “settling tank”) and further used as dilution water. The volume reduction ratio (VRR) and the recovery degree in each foam fractionation vessel were adjusted based on laboratory trials performed at VTT. A VRR of 10 was used. This means that 10 vol% of the feed was taken as a concentrate from the top of the fractionation vessel. The surfactant recovery degree depends on the surfactant concentration of the feed. As the surfactant concentration in the feed increases, the recovery degree over one unit decreases.
Froth build-up in tanks is an unavoidable and unwanted phenomenon, especially in the short circulation. Froth piles up at the surfaces of the tanks, accounting for notable tank volume and eventually leading to an undesired overflow of foam/froth on the floor. The wire pit, which may contain air more than 50% of its volume, is the most problematic regarding the froth. The residence time in the wire pit is not sufficient to collapse the foam. Thus, the foamed liquid ends up in fiber recovery. Depending on the device used for fiber recovery, small amounts of foam/froth may even end up in the white water tower, which provides the dilutions for thick stock preparation and refiners at the beginning of the process. Froth may be collapsed with, for example, mechanical foam breakers, which are used in brown stock washing and black liquor oxidation systems. In this study, mechanical collapsing of froth was implemented in the foam-laid model to remove part (20%) of the air present in the white water tank.
Modifications to the existing equipment and water circuits
The conversion of existing paper machines to foam technology requires some changes in the existing equipment. For several years now, VTT has studied the running and operation of the unit operations in the short circulation with foam. Because VTT’s pilot environment does not include refiners, hydrocyclones, or fiber recovery systems, how they will function with foam remains uncertain. Only limited public information is available on how existing paper process equipment tolerates foam. The equipment suppliers would be a reliable source of information, but they were not contacted for this study. Based on the best existing knowledge and not using data based on systematic tests or physical laws, Table 2 was compiled to present the suitability of existing paper process equipment for foam when producing paper-like products (25 g/m2 to 150 g/m2). The re-arrangement of the process streams in the foam-laid process was conducted based on the assumptions presented in Table 2.
Refiners, hydrocyclones, headbox, and forming section were identified as the most critical paper process equipment when considering converting a water-laid process to a foam-laid process. Foam presents challenges in adjusting the refiner pressure. Hydrocyclones, meanwhile, may or may not work with foam, depending on the furnish type. The headbox may require some modifications, and the vacuum capacity of the forming section must be increased. Preliminary simulations of the foam-laid concept model revealed that, from the standpoint of mass and volume balance, the questionable operability of hydrocyclones with foam is the most crucial issue. Option for overcoming this challenge would be to skip the hydrocyclones entirely. However, this is possible only when the quality of pulp is not an issue. In greenfield foam-laid processes, it might even be possible to pass the pulp through a hydrocyclone system in the pulp mill before it is introduced to foam in the paper mill. In this study, it was assumed that the hydrocyclones retain in their place, and their possible malfunction when exposed to foam is solved by changing the source of their dilution water. In the water-laid process, dilution waters for hydrocyclones are taken from the short circulation, i.e., from the white water tank. In the foam-laid process, the white water tank most definitely contains foam (foamed liquid) or foamable liquid (water phase with high surfactant concentration), which causes more foaming and results in malfunction if used as dilution water in the hydrocyclones.
To avoid this refoaming problem in the foam-laid concept model, the dilution waters for the first and second LCCs must be taken from the long circulation, i.e., from the settling tank, because the settling tank contains non-foamable, surfactant-lean (SDS < 20 ppm) water from the surfactant recovery that should not foam even if exposed to shear forces or mixing. This re-arrangement of the dilution water mixes the water balance between the short and long circulations and results in increased volume flows from the short to the long circulation, leading to increased capacity for the existing equipment in the long circulation. The fiber recovery system (i.e., valveless filter) as such was assumed to mechanically collapse the foam due to the suction and rotation. Thus, the filtrate exiting the valveless filter was assumed to be in the water phase, whereas the recovered fiber fraction was assumed to contain some foam. To prevent the foamy fiber fraction from entering the LCCs, it is recycled after the first LCC to the feed of the first pressure screen, not to the mixing chest, as is done in the water-laid process.
Modifications to the modeling of the forming section
Dewatering in conventional papermaking is widely studied and quite well understood (Baldwin 1997; Hubbe and Heitmann 2007; Åslund and Vomhoff 2008). However, the dewatering of foam differs considerably from the dewatering of water. The viscosity of foam is typically a few orders of magnitude greater than that of pure water (Jäsberg et al. 2015). Due to the greater viscosity, the dewatering of foam in the forming section is poorer/slower. To reach the same dewatering rate in both cases, greater vacuums or lower machine speeds need to be used in foam forming.
For modeling the forming section of the foam-laid wallpaper machine, the authors studied foam removal in the forming section of VTT’s pilot machine as a function of the vacuum level, foam density, and web consistency. Altogether, six trial points were run, either by varying the foam density at the headbox (400 kg/m3, 500 kg/m3, or 650 kg/m3) and using constant vacuum profiles through the forming section or by keeping the foam density at the headbox constant (650 kg/m3) and varying the vacuum profiles through the forming section. Because only one type of furnish and surfactant was used, their effects on the dewatering were excluded.
The VTT pilot machine (Fig. 3) consists of an approach system with different kinds of containers; a forming section that can be run in gap, hybrid, or Fourdrinier mode; and a press section, which consists of a single extended nip press. In these trials, the pilot machine was run in the hybrid-forming mode (Fig. 4). The machine speed in the trials was 500 m/min. The pilot machine’s forming section is divided into four foam removal sections, each having two to four foam removal units and its own degassing pump feeding the wire water tank. This division into four sections was also applied in the model describing the forming section. By modeling the forming section in stages, it is possible to estimate the volume flows and the foam densities of the exiting wire water fractions from each section separately and further use this data for dimensioning the degassing pumps. To estimate the water and air removal efficiency in each section, the authors created mass balances for water and air over each section based on the pilot trial data.
The other, more simplified method to model the forming section is to describe it as a black box with a fixed end dryness level (i.e., fix the water removal) and assume that water and air are removed at the same ratio. By using this approach, however, one only obtains estimates of the volume flow and density level of the combined wire water flow. Thus, it is not possible to obtain data for the wire water fractions from different parts of the forming section. Both approaches have the same outcome regarding the water balance: The web exits the forming section with a fixed end dryness level and with a corresponding amount of water. The rest of the water originally present in the web ends up in the wire water tank. However, the air balance differs. By using the stagewise modeling and experimental data describing both water and air removal, the air balance through the forming section can be modeled in more detail.
Fig. 3. Foam forming pilot machine at VTT (Jyväskylä, Finland)
Fig. 4. Hybrid former section of the pilot plant (schematic diagram, not to scale). HB = headbox, VB = vacuum box, HVB = high vacuum box. The forming board consists of five vacuum boxes. The top unit consists of three vacuum boxes and loadable blades under one vacuum box. Typical wire tension values are shown. The vacuum levels (in kPa) presented are for the trial point at which a moderate vacuum profile was used and the foam density at the headbox was 650 kg/m3. The vacuum and web consistency increase along with the forming section.
Achieving an understanding of foam removal and the modeling of foam removal were difficult with the limited number of available trial points. When moving along the forming section, the foam removal was different and also affected differently by the vacuum and foam density. With web consistencies less than approximately 15%, air and water were removed at roughly the same volumes. In the high vacuum box with higher web consistencies, the volume of removed air was only approximately 40% of the volume of removed water. Subject to possible measurement errors, foam forming behaves quite differently than water forming: After the water line (or dry line), there is noticeable flow of external air through the web (Hubbe et al. 2020). The reason for this difference is likely that the foam effectively seals the sheet with higher consistencies due to capillary forces acting between the bubbles and the fibers. If this is the case, compression dewatering, where water is expelled from the web due to applied pressure decreasing its volume, should be more important in foam forming than displacement dewatering, in which the water held within a web is displaced by air. Generally, as the vacuum increased, the efficiency of the foam dewatering also increased. With identical vacuum profiles, as foam dryness increased, foam removal occurred further along the forming section. Dry foam (400 kg/m3 to 500 kg/m3) removal occurred mainly at the end, whereas wet foam (600 kg/m3 to 700 kg/m3) removal mainly occurred at the beginning of the forming section. The effective foam removal of wet foams at the beginning of the forming section might be explained by their clearly lower viscosity compared to dry foams.
Figure 5 presents the modeling of the forming section in the foam-laid case. By imitating the structure of the VTT pilot machine’s forming section, the forming section of the reference wallpaper machine was divided into four dewatering sections (DW0, DW1, DW2, and DW3), each having one to two vacuum boxes. The length of each of the four dewatering sections in the reference wallpaper machine was half that of the VTT pilot machine’s corresponding dewatering section. In addition, the speed of the reference wallpaper machine was half that of the pilot machine’s speed. If the machine speed is halved, and the vacuum level is kept constant in the dewatering section, the length of the dewatering section may be halved to maintain the same impulse due to the pressure difference throughout the foam removal unit. Thus, it is justified to apply to the wallpaper machine the same vacuum level profile that was tested in the pilot machine and shown to provide sufficient foam removal. It seemed that the amount/length of the existing vacuum boxes in the reference wallpaper machine would be enough for sufficient foam removal if the machine speed does not exceed 250 m/min. However, if the dewatering remains insufficient, it is possible to substitute some of the hydrofoil boxes with vacuum boxes.
In addition to the vacuum-aided dewatering sections, the forming section of the reference machine contained one dewatering section with hydrofoils (Hydrofoil boxes) just after the headbox. The dryness levels after the first (Hydrofoil boxes) and last (DW3) dewatering sections were fixed to 1.7% and 19.4%, respectively. The simulation model calculated backwards the required water removal efficiency (wt% of water removed from the incoming) to achieve the fixed dryness levels. These efficiencies were 15.5% for Hydrofoil boxes and 50.7% for DW3. The water removal efficiencies in the second (DW0), third (DW1), and fourth (DW2) foam removal sections were fixed based on the pilot trial data points, the vacuum profile of which is presented in Fig. 4. Thus, the same kind of water removal trend along the forming section was assumed as was observed in the pilot trial. The water removal efficiencies in the second, third, and fourth foam removal sections were set to 45%, 50%, and 55%, respectively. The simulation model calculated the corresponding dryness levels of the web. To estimate air removal in each dewatering section, a correlation derived from the pilot trials was used. It revealed that until a certain web consistency (approximately 15% to 20%), air removal is 97% that of water removal. However, at high web consistencies (>15%), air removal is only approximately 40% that of water removal. The air removal efficiencies in the five foam removal sections were set to 15.0%, 43.7%, 48.5%, 53.4%, and 20.3%.
The attempt to create a general and consistent model to describe the consistency profile (i.e., foam removal) in the forming section of a foam-forming machine failed because of the limited trial data. Still, it is notable that successfully predicting the consistency profile in the forming section of a conventional water-laid paper machine is extremely challenging. An exact modeling of the forming section is crucial only when estimates of the required vacuum levels or dimensioning data for the vacuum pumps are needed. For preliminary mass and volume flow balances, the approach used in this study is sufficient.
Fig. 5. Modeling of the forming section of the foam-laid wallpaper machine. The forming section is divided into one vacuum-less (Hydrofoil boxes) and four vacuum-aided (DW0, DW1, DW2, and DW3) foam removal sections to estimate the volume flows and densities of the different wire water fractions.
Modifications to the modeling of the press section
The modeling of the press section was kept simple because the density development of the web during the wet pressing was not of interest. The press section was modeled with three pressing rolls (DW4, DW5, and DW6 in Fig. 6). The solids content profile in the rolls mimicked the solids content profile observed by Järvinen et al. (2018) in laboratory tests, in which three parallel long-pulse tests for both water- and foam-formed wet sheets were used. The solids contents after the three rolls were 33.0%, 42.7%, and 45.6% in the water-laid case and 37.7%, 47.0%, and 50.6% in the foam-laid cases. Exact modeling of the air balance during wet pressing is challenging due to the lack of experimental data. When pressing the web, some of the air present in the web remains in the web, while some is removed along with the press water, and some escapes into the surroundings. In the foam-laid model, it was assumed that the density of the press waters removed from each of the rolls was 800 kg/m3, i.e., the press waters contained 20% air. The authors assumed that the rest of the air remains in the web until the last roll (DW6). After the last roll, the rest of the air present in the web was modeled as if leaving the system. This assumption did not prove correct, but it was accurate enough at this point, as the density of the web entering the drying section was not of interest. From the standpoint of total air balance, only the amount of air present in the press waters is crucial.