Abstract
Inorganic salt is a promising stabilizer in the hydrothermal synthesis of porous carbon materials. A three-dimensional palladium-loaded (Pd-loaded) lignin carbonaceous material with a porous structure was developed via hydrothermal carbonization, with lignin as not only a carbon source but also a reducing and stabilizing agent for palladium nanoparticles (Pd NPs) and then with LiCl as the hard template and porogen. The porogen-induced Pd-loaded carbonaceous material displayed an orderly pore structure with more porosity than the porogen-free Pd-loaded carbonaceous material. Subsequently, the porogen-induced Pd-loaded carbonaceous materials were transferred to an aqueous phase filter and mixed with reactants in a syringe as catalysts. The catalyst exhibited excellent catalytic performances in the reduction reaction of 4-nitrophenol to 4-aminophenol by NaBH4, with a rate constant of 0.11 min-1, which was higher than that of the porogen-free Pd-loaded carbonaceous material. In this study, LiCl was employed as the hard template and porogen to construct the porous carbonaceous structure and improve the porosity by stabilizing the pore structure and minimizing collapse, which provided a new way to synthesize lignin porous carbonaceous material.
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Salt-Template Hydrothermal Carbonization for Pd NP-loaded Porous Carbonaceous Material
Jiaming Li, Xiaoyun Li, Guocheng Han, Chuanfu Liu, and Xiaoying Wang *
Inorganic salt is a promising stabilizer in the hydrothermal synthesis of porous carbon materials. A three-dimensional palladium-loaded (Pd-loaded) lignin carbonaceous material with a porous structure was developed via hydrothermal carbonization, with lignin as not only a carbon source but also a reducing and stabilizing agent for palladium nanoparticles (Pd NPs) and then with LiCl as the hard template and porogen. The porogen-induced Pd-loaded carbonaceous material displayed an orderly pore structure with more porosity than the porogen-free Pd-loaded carbonaceous material. Subsequently, the porogen-induced Pd-loaded carbonaceous materials were transferred to an aqueous phase filter and mixed with reactants in a syringe as catalysts. The catalyst exhibited excellent catalytic performances in the reduction reaction of 4-nitrophenol to 4-aminophenol by NaBH4, with a rate constant of 0.11 min-1, which was higher than that of the porogen-free Pd-loaded carbonaceous material. In this study, LiCl was employed as the hard template and porogen to construct the porous carbonaceous structure and improve the porosity by stabilizing the pore structure and minimizing collapse, which provided a new way to synthesize lignin porous carbonaceous material.
Keywords: LiCl template; Hydrothermal carbonization; Lignin; Pd NP; Catalyst
Contact information: State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou, 510640, China; *Corresponding author: xyw@scut.edu.cn
INTRODUCTION
Nanocatalysts based on noble metallic nanoparticles (NPs), especially Pd NPs, have drawn research attention for decades because of their unique optical, photochemical, and phase transition properties, remarkably high catalytic activity, and excellent thermal stability. In particular, high catalytic activity results from the efficient hydrogen relay effect of Pd NPs (Bedia et al. 2010; Huang et al. 2010; Coccia et al. 2012), which facilitates the reaction rate of various essential catalysis processes by the surface migration of H atoms (Kobayashi et al. 2008). Nevertheless, for Pd NPs, the mobility is one of the most common and troublesome problems (Chen et al. 2010), and results in great loss and no recycling of Pd NPs, as well as a subsequent weakening of the catalytic performance (Chen et al. 2010; Fang and Wang 2013). Efforts have been made to immobilize Pd NPs onto various catalyst supports, including films, ceramics, carbons, etc. (Chu et al. 2007; Huang et al. 2008; Chan et al. 2009). Porous carbon materials are the most effective and convenient catalyst support (Bedia et al. 2010) because of their high chemical stability and controllable pore structure (Alatalo et al. 2016), which may confine metal nanoparticles and endow the surface with more catalytic active sites (Fang and Wang 2013; Duan et al. 2014). Therefore, porous carbon materials are considered as a promising catalytic support for Pd NPs to reinforce the composites.
Lignin, the main byproduct in the pulp and paper industry, has been used as a precursor for the fabrication of porous carbons and carbonaceous materials in the past few years (García-Mateos et al. 2017). However, there has been no related research on the immobilization of Pd NPs onto lignin-based porous carbon materials. It has been found that lignin can act as a reducing and stabilizing agent to obtain Pd NPs, and it is notable that Pd NPs can be prepared on lignin-based porous carbon materials by adopting lignin waste as not only a green reducing and stabilizing agent (Shen et al. 2014), but also an accessible carbon precursor (Li et al. 2016; Zhang et al. 2016).
Various strategies have been developed for the synthesis of lignin porous carbon and carbonaceous materials, such as pyrolysis (Thangalazhygopakumar et al. 2015; Thines et al. 2017), activation (Xu et al. 2018), the template method (Wu et al. 2015), microwave-assisted method (Mubarak et al. 2014; Noraini et al. 2016; Nizamuddin et al. 2018), and hydrothermal carbonization (HTC) (Nizamuddin et al. 2016; Wang et al. 2017). Direct pyrolysis is generally considered to be a traditional method for fabricating lignin porous carbons (Li et al. 2016; Zhang et al. 2015), while two-step carbonization including the first pre-carbonization step and the subsequent pyrolysis/activation process has gradually become an efficient approach for improving the carbon porosity (Adebisi et al. 2017; Puziy et al. 2018). Numerous researchers have focused on the pyrolysis and activation process. Dozens of activating agents, such as potassium hydroxide (KOH) (Zhang et al. 2016; Guo et al. 2017), potassium bicarbonate (KHCO3) (Deng et al. 2016), and phosphoric acid (H3PO4) (Adebisi et al. 2016; García-Mateos et al. 2017), and hard templates, such as SiO2 (Li et al. 2016), have been introduced to produce large numbers of micropores by strong chemical etching and high temperature gasification and thus generate a high specific surface area (SSA) (Benzigar et al. 2018). Some studies have focused on the improvement during the hydrothermal process (Pileidis et al. 2014; Sevilla et al. 2014; Wu et al. 2016). HTC is a thermal treatment of an aqueous solution or dispersion of carbon source, which proceeds at moderate temperature (180 to 250 oC) under autogenously created pressure at approximately 20 to 30 bar (Adebisi et al. 2017; Chowdhury et al. 2018b). During the HTC process, linkages between the carbohydrate-rich fractions are broken through a series of hydrolysis, condensation, decarboxylation, and dehydration reactions (Adebisi et al. 2016; Chowdhury et al. 2016). As a mild and low-cost pre-carbonization approach, HTC mostly plays a role in the formation and the modification of carbonaceous materials, which is still limited in porosity increasement and requires further improvement (Sangchoom and Mokaya 2015). Carbonaceous materials synthesized in the hydrothermal pre-carbonization process with an improved pore structure and SSA are considered to be more efficient in subsequent pyrolysis and activation reactions because of their larger contact area with activating agents and templates (Liu et al. 2015; Puziy et al. 2018). However, converting lignin waste into hydrothermal carbonaceous materials with higher porosities remains a challenging task because of the intractable molecular structure of lignin (Chowdhury et al. 2018b; Lin and Dence 1992). Also, during HTC, the lignin precursor forms furanic and aromatic units with oxygen-substituted arene-type moieties (Hu et al. 2010; Wikberg et al. 2015) under pressurized water and inevitably becomes converted into irregular carbon spheres that aggregate easily and block the pore tunnel, which adversely affects the industrial scale-up (Zhang and Zhao 2009; Titirici and Antonietti 2010; De et al. 2015). To solve this problem, inorganic salts can be exploited as both hard templates and porogens to improve the porosity by stabilizing the pore structure, minimizing collapse, and subsequently endowing the materials with an orderly morphology and accessible tunnels (Fechler et al. 2013; Ming et al. 2013). Furthermore, the inorganic salts template can be eliminated by washing with deionized water without any chemical etching (Lynam et al. 2012).
In this study, a strategy was proposed that incorporates lithium chloride (LiCl) into hydrothermal carbonization for the fabrication of an efficient catalyst, namely Pd NP-loaded lignin porous carbonaceous material. The procedure consists of three stages and is illustrated in Fig. 1. First, lignin was utilized as a reducing and stabilizing agent to prepare Pd NP and was also employed as a carbon source to fabricate porous carbonaceous material. Second, lignin/Pd NP composites were carbonized hydrothermally to form Pd NP-loaded porous carbonaceous material with LiCl as the hard template and porogen. LiCl was employed to construct the porous carbonaceous structure and improve the porosity by stabilizing the pore structure and minimizing collapse, which provided a new way to synthesize lignin porous carbonaceous material. Third, a typical catalytic reaction involving the reduction of 4-nitrophenol (4-NP) to 4-aminophenol (4-AP) by sodium borohydride (NaBH4) was selected as a model reaction to investigate the catalytic performances of the Pd NP-loaded porous carbonaceous materials. The effect of the LiCl salt template was then determined by comparison of the morphologies, textural properties, and catalytic performances of the obtained carbonaceous materials.
Fig. 1. Preparation of Pd NP-loaded lignin porous carbonaceous material, resulting in application as a catalyst in the reduction of 4-NP to 4-AP by NaBH4
EXPERIMENTAL
Materials and Apparatus
The alkali lignin was recovered from soda pulping effluent from the State Key Laboratory of Pulp and Paper Engineering (Guangdong, China) through the alkali extraction and acid precipitation method. It was highly soluble in sodium hydroxide. Diammine dichloropalladium (II) (Pd(NH3)2Cl2), 4-NP, and lithium chloride (LiCl) were purchased from Shanghai Macklin Biochemical Co., Ltd (Shanghai, China). Sodium borohydride was acquired from Finechem Group (Zhejiang, China).
Microwave irradiation equipment (XH-100B) was purchased from Beijing Xianghu Sci-Tech Co., Ltd. (Beijing, China). A THC-000 hydrothermal reactor was purchased from Shandong Tianhe Science Center (Shandong, China).
Purification of the Alkali Lignin
First, the crude alkali lignin was uniformly dispersed in water and an alkali lignin suspension (30 wt%) was obtained. Then, 10 wt% NaOH was poured into the alkali lignin suspension until the pH was approximately 13 to 14 to completely dissolve the crude alkali lignin. The mixture was centrifugated and the solution was collected. Then, 12% (v/v) HCl was slowly poured into the solution at 60 °C, such that the refined lignin was precipitated. The residue was collected and dried at 45 °C for 36 h.
Synthesis of the Lignin/Pd NP Composites
The synthesis of the lignin/Pd NP composites was conducted in the lignin solution with the Pd precursor under microwave irradiation. Briefly, the 2% lignin solution was prepared by dissolving lignin in a 1% NaOH solution, and the Pd precursor solution was prepared by dissolving Pd(NH3)2Cl2 in a 2% NaOH solution. Then, the lignin solution was added into the Pd precursor solution under microwave irradiation. Finally, the lignin/Pd NP composites were obtained after the resultant solution was dialyzed and freeze-dried at a sublimating temperature of -40 °C and a pressure of 0.035 bar for 24 h. The lignin/Pd NP composites were prepared with different ratios of lignin to Pd2+, reaction temperatures, and reaction times (Table S1). The lignin raw material sample was labeled as Lignin, and the lignin/Pd NP composite samples were labeled LigPd1 to LigPd9.
Synthesis of the Pd NP-loaded Lignin Porous Carbonaceous Material
For the synthesis of the Pd NP-loaded porous carbonaceous material, lignin/Pd NP composites (3.0 g), LiCl (3.0 g), and deionized water (15.0 g) were mixed and then autoclaved at 240 °C for 24 h. The resultant mixture was washed with deionized water to remove residual porogen and then dried under vacuum at 80 °C. This LiCl-induced sample was labeled LigC-Pd-LiCl, while the LiCl-free sample was labeled LigC-Pd.
Characterization
The X-ray diffraction (XRD) analyses were performed on a D8 Advance Diffractometer system (CuKα radiation, 40 kV, and 40 mA) from Bruker (Billerica, United States). The diffraction data was recorded using continuous scanning at 3.125°/min with a step size of 0.02°. Fourier transform infrared (FT-IR) spectra were obtained on an FT-IR spectrophotometer (TENSOR 27, Bruker). Ultimate analysis (C, H, N, O and S) of the samples was carried out on an Elemental Analyzer (Vario EL cube, Berlin, Germany). Thermogravimetric analysis (TGA) was conducted on a TA Instruments 5500 TGA system to determine the thermal stability of the samples under a 20 mL·min-1 nitrogen flow. In the TGA analysis, 7 mg of each sample was heated under a N2 flow at 1000 °C with a heating rate of 10 °C min-1. The surface morphology was surveyed with a Zeiss Ultra 55 (Carl Zeiss, Oberkochen, Germany) scanning electron microscope (SEM) operating at 5 kV and JEOL JEM-2010 transmission electron microscope (TEM) (Tokyo, Japan) operating at 200 kV. The SEM samples were prepared by embedding the carbon powder onto carbon epoxy followed by oven-drying at 60 °C. Before subjected to TEM analysis, the samples were dispersed in ultrapure water, sonicated for 2 h, and then taken up and carefully dropped on an ultra-thin copper mesh grid, followed by drying with an infrared lamp. Nitrogen sorption analysis was conducted with an ASAP 2020 Micromeritics (New York, USA). The samples were degassed at 150 °C under vacuum for 8 h before measurements. The specific surface area (SSA) was determined by Brunauer-Emmett-Teller method (BET), and pore size distribution (PSD) was calculated by non-local density functional theory (NLDFT) model. The ultraviolet-visible measurements were performed on a TU-1810 spectrophotometer (Puxi General Equipment Co., Ltd., Beijing, China) with the spectral window ranging from 200 nm to 600 nm.
Catalytic Activity
The synthesized Pd-loaded lignin porous carbonaceous materials were tested as catalysts for the reduction of 4-nitrophenol (4-NP) to 4-aminophenol (4-AP) by sodium borohydride (NaBH4), which has become a model reaction for evaluation of the catalytic activity of metal NPs (Blosi et al. 2014). The catalytic reduction of 4-NP by NaBH4 was studied in a standard quartz cuvette with a 1-cm path length and approximately 3-mL volume. The obtained Pd NP-loaded porous carbonaceous material was used as a catalyst. The catalysts (0.01 g) were transferred to an aqueous phase filter. Next, the NaBH4 solution (1 mL and 0.12 M) and 4-NP solution (0.5 mL and 0.005 M) were freshly prepared. Then, the above solution was mixed with 60 mL of distilled water as a reactant. A syringe was used to inject 5 mL of reactant through the prepared filter with a residence time of 1 min and the solution was filtered through the catalysts 10 times. An aliquot of the solution was poured into the quartz cuvette, and the absorption spectra were collected using the TU-1810 spectrophotometer over the range of 200 nm to 600 nm.
In the ultraviolet-visible analysis, the 4-NP solution was absorbed at 400 nm, and a second peak appeared at 294 nm after the addition of the NaBH4 solution. By measuring the change in absorbance at 400 nm and 294 nm, the catalytic performance of the Pd NP-loaded porous carbonaceous material was revealed.
RESULTS AND DISCUSSION
Characterization of the Pd-loaded Porous Carbon
The XRD patterns of the lignin/Pd NP composites prepared with different ratios of lignin to Pd2+, reaction times, and reaction temperatures are shown in Fig. S1 (see Appendix). Almost all of the patterns had four peaks at 2θ values of 39.13°, 45.31°, 66.53°, and 80.25°, corresponding to the (111), (200), (220), and (311) planes, respectively (Nasrollahzadeh et al. 2016; Kandathil et al. 2018). The diffraction peak at 39.13° was prominent, while the other peaks were weak, but they still existed. This indicated that Pd NPs were obtained. After a careful comparison, it was found that with an increase in the Pd precursor, reaction time, and reaction temperature, the characteristic peaks increased gradually, which indicated the formation of more Pd NPs. Moreover, the FT-IR analysis was performed to evaluate the structural changes of the lignin after the formation of the Pd NPs. The spectra of the lignin/Pd NP composites prepared with different ratios of lignin to Pd2+, reaction temperatures, and reaction times are exhibited in Fig. S2. The peak at 1708 cm-1, belonging to the absorption of conjugated carbonyl stretching in lignin, disappeared after the reaction, which indicated that the carbonyl groups in the lignin were transformed into carboxyl groups by the Pd salts (Ruthiraan et al. 2017; Xiao et al. 2013). The absorption of benzene ring stretching at 1593 cm-1, 1510 cm-1, 1462 cm-1, and 1420 cm-1, as well as phenolic hydroxyl stretching at 1221 cm-1 became smaller and even disappeared after the reaction (Xiao et al. 2013; Shen et al. 2014). This indicated that phenolic hydroxyl played an important part in the formation of Pd NPs, and formed coordination compounds with the Pd NPs or were removed from the lignin during the reaction (Hu et al. 2014). Furthermore, there was also a slight decrease in the relative band intensities at 1028 cm-1 after the reaction because of aromatic C-H deformation of the syringyl and guaiacyl units and aromatic ether ring breathing (Figueiredo et al. 2018). This implied that methylene and methoxy groups were liberated and ether linkages in the lignin structure were cleaved. The decreasing intensities of the bands from the conjugated carbonyl stretching, benzene ring stretching, and phenolic hydroxyl stretching indicated the oxygenation of the lignin by the Pd salts. From the above explanation, it was concluded that the lignin was decomposed into relatively small molecules with cleavage of the ether linkages and was successfully oxidized by the Pd salts, which acted as a reducing agent in the synthesis of the lignin/Pd composites.
To investigate the influence of carbonization and the LiCl porogen on the formation of Pd NPs, the obtained carbonaceous materials were characterized by XRD analysis (Fig. 2). The pattern in Fig. 2a had four diffraction peaks, which corresponded to the optimum reaction conditions (60 min, 80 °C, and 0.5 mg:0.5 mmol) for the lignin/Pd composites. Figures 2b and 2c show the sample patterns after carbonization with the LiCl porogen, which had five peaks at 2θ values of 39.98°, 46.52°, 68.24°, 81.76°, and 86.54°, which corresponded to the (111), (200), (220), (311), and (222) planes of JCPDS (NO. 46-1043), respectively. The diffraction peaks were sharp and intense, which indicated that the Pd NPs were successfully embedded on the prepared carbonaceous materials. Compared with the weak diffraction peak of the lignin/Pd NP composites (Fig. 2a), the strong diffraction peak characteristic of the Pd species in the Pd-loaded porous carbonaceous materials (Figs. 2b and 2c) could be interpreted in terms of the incomplete reduction of Pd2+ during microwave irradiation and further reduction of Pd2+ to Pd NPs during the subsequent HTC (Kang et al. 2011). Also, the diffraction peaks of the Pd-loaded porous carbonaceous material (Figs. 2b and 2c) shifted right compared with the diffraction peaks of the lignin/Pd NP composites (Fig. 2a).
Fig. 2. XRD patterns of the (a) LigPd8, (b) LigC-Pd, and (c) LigC-Pd-LiCl
This rightward shift of the diffraction peaks might have been related to the cell contraction of the Pd NPs after HTC and resulting decrease in the interlayer spacing of the Pd NPs (Pecharsky and Zavalij 2005). The characteristic peaks of the LigC-Pd-LiCl (Fig. 2c) decreased compared with that of the LigC-Pd (Fig. 2b), which implied that the addition of porogen LiCl had some influence on the Pd loading of the lignin porous carbonaceous material. One interpretation was that some of the obtained ultrafine Pd NPs were encapsulated in the constructed micropores during the HTC process and concealed within the carbonaceous structure (Calderon et al. 2018), but not all homogeneously dispersed on the carbon surface (Tran et al. 2015), which made them undetectable in the XRD analysis and resulted in a slight decrease in the characteristic peaks.
The morphology and porosity of the prepared Pd NP-loaded porous carbonaceous materials were analyzed by means of a TEM and SEM. Figure 3a shows that the sizes of the Pd NPs were uniform and no larger particle aggregates were observed.