Abstract
Due to the high viscosity of pure [Bmim]Cl, PEG was selected to be co-solvent to form the solvent system. The dissolution and plasticization ability of PEG-[Bmim]Cl to poplar veneer was completed with processes such as hot pressing and coagulation bath to achieve the in-situ modification of poplar veneers to develop an innovative wood composite, which are expected to be molded. At the same time, the effects of the solvent system on the properties of wood composites were studied. The results showed that both the [Bmim]Cl-treated group (B) and the PEG-treated group (C) had a certain degree of plasticity when compared with the untreated group (A). The PEG-[Bmim]Cl-treated group (D) had the greatest ductility. The main reason was that PEG and [Bmim]Cl synergistically in situ dissolve the components of the veneer, increasing the proportion of the matrix phase (dissolved part). The interface bonding between the matrix phase and the reinforced phase was enhanced and resulted in the best comprehensive mechanical properties. However, no other derivative reactions occurred in each group.
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Wood Composites Based on In Situ Modification of Poplar Veneers by PEG-[Bmim]Cl
Zuju Shu,* Mengya Xie, Jin Yu, Xinyue Zhang, Huanhuan Li, and Baoshan Gao
Due to the high viscosity of pure [Bmim]Cl, PEG was selected to be co-solvent to form the solvent system. The dissolution and plasticization ability of PEG-[Bmim]Cl to poplar veneer was completed with processes such as hot pressing and coagulation bath to achieve the in-situ modification of poplar veneers to develop an innovative wood composite, which are expected to be molded. At the same time, the effects of the solvent system on the properties of wood composites were studied. The results showed that both the [Bmim]Cl-treated group (B) and the PEG-treated group (C) had a certain degree of plasticity when compared with the untreated group (A). The PEG-[Bmim]Cl-treated group (D) had the greatest ductility. The main reason was that PEG and [Bmim]Cl synergistically in situ dissolve the components of the veneer, increasing the proportion of the matrix phase (dissolved part). The interface bonding between the matrix phase and the reinforced phase was enhanced and resulted in the best comprehensive mechanical properties. However, no other derivative reactions occurred in each group.
DOI: 10.15376/biores.18.4.6815-6826
Keywords: Poplar veneers; [Bmim]Cl; PEG; Modification; Wood composites
Contact information: School of Light and Textile In dustries Engineering & Art, Anhui Agricultural University, Hefei, Anhui 230036 China; *Corresponding author: shuzuju@ahau.edu.cn
INTRODUCTION
Environmental deterioration and shortage of resources caused by non-renewable and non-biodegradable resources are increasing. While more attention is being paid to renewable wood, wood can only be moulded into simple shapes due to its rigid nature (Dong et al. 2020). To improve the plasticity of wood veneers and broaden their applications, water, furfuryl alcohol, ammonia, and ionic liquids (ILs) have been used to modify them (Herold and Pfriem 2013; Ou et al. 2014; Šprdlík et al. 2016). These methods can be improved to be more environmentally friendly and efficient. In earlier research, ILs were used for wood pretreatment as a “green solvent” (Shu et al. 2017). Wood is a renewable resource composed of three macromolecular chemical components—cellulose, hemicelluloses, and lignin (Croitoru and Roata 2021; Bisht et al. 2022; Jiang et al. 2022). Generally, wood veneers are often obtained by rotary cutting or sliced cutting. However, the veneers obtained by rotary cutting have lower porosity and higher density compared with the sliced veneers (Kamperidou et al. 2020). ILs are potential solvents for most carbohydrate and lignocellulosic biomass that are insoluble in conventional solvents due to strong hydrogen bonding (Xu et al. 2019; Rajan et al. 2022; Wei et al. 2022). However, the high viscosity of ILs hinders the dissolution of lignocellulose (Goshadrou and Lefsrud 2017).
To lower the viscosity of the solution, green co-solvents should be employed for pretreatment, dissolution, or extraction. A co-solvent can prove helpful in reducing the cost of solvent (Rodriguez et al. 2009; Nasirpour and Mousavi 2021). N, N-dimethylformamide (DMF) and dimethyl sulfoxide (DMSO) are effective co-solvents, but they have toxic effects (Clarke et al. 2018; Yang et al. 2014). Polyethylene glycol (PEG, molecular weight greater than 4000) can be used as solvent or additive in solvent extraction systems due to its biodegradability, low toxicity, and low cost, with relatively low melting points and very low volatility. PEG dissolves lignin, and it has been used to develop cleaner, more efficient pulp delignification. ILs are often used in many practical applications such as efficient catalysts, clean energy storage, and pollutant gas treatment (Wang et al. 2022). As an environmentally friendly reaction medium, PEG is often used to dissolve chemicals, catalysts, complex metal cations, and participate in redox chemistry (Hoffmann 2022). Both ILs and PEG are considered to be in the framework of green chemistry. Given the remarkable thermal stability and the very low volatility of both ILs and PEG, PEG-ILs may be promising solvents for pretreatment of lignocellulose, dissolution of lignocellulose, and fractionation of its biopolymers (Willauer et al. 2000; Nasirpour and Mousavi 2018).
Wood obtained from fast growing poplar is an important bio-renewable lignocellulose resource. Poplar veneers are rotary cut or planed wood slices with high yield. The effective use of the veneer resources will increase the added value of the poplar wood (Shu et al. 2017). [Bmim]Cl, 1-butyl-3-methylimidazolium chloride was used as a low-cost IL to dissolve wood, cellulose, and lignin. The addition of cosolvent PEG further reduced the viscosity of PEG-[Bmim]Cl solvent system and the cost of this new technology (Goshadrou and Lefsrud 2017). In this work, mild impregnation of poplar veneers in PEG-[Bmim]Cl solution was expected to induce softening and plasticization of wood components. Subsequent hot-pressing and coagulation technology promoted an even in-situ dissolution and regeneration. The final drying resulted in a new environmentally friendly wood composite to meet the sustainable requirements.
EXPERIMENTAL
Materials
As raw material, the hybrid poplar clones (Populus×euramericana (Dode) Guiner CL. ‘Zhonglin 46’) aged from 5 to 6 years were randomly collected from the agricultural garden at Anhui Agricultural University. The lumber pieces were air-dried after being peeled. Selected lumber pieces, free from flaws such as knots, holes, cracks, fungi, and insect damage, were rotary cut (YD-335, Jinhua Yidi Medical Equipment Co., Ltd., China) into veneers with 1.8 ± 0.1 mm thickness. 1-Butyl-3-Methyl Imidazolium Chloride ([Bmim]Cl) with a purity of 99.0% was purchased from Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, and used without further purification. PEG (6000) was purchased from Shanghai Macklin Biochemical Co., Ltd. Deionized water (DW) was manufactured in the laboratory at Anhui Agricultural University.
Fabrication of Novel Wood Composites
The experimental procedure was performed as described by Shu et al. (2017). Figure 1 illustrates the procedure used to develop the novel wood composites. The prepared veneers were selected randomly, cut into 30 mm × 25 mm samples, and dried to a constant weight at 60 °C. The [Bmim]Cl solvent system has a higher viscosity, and full impregnation requires higher energy and longer time. PEG was introduced to form the solvent system PEG-[Bmim]Cl with reduced viscosity. Three groups of prepared veneers (30 mm × 25 mm) were impregnated with [Bmim]Cl (B), PEG (C), and 20 wt.% PEG-80 wt.% [Bmim]Cl (D), which were melted already in the electric vacuum drying oven (DZF-6050, Nanjing Tianhuang Machinery Co., Ltd, China) at 90 °C. The untreated control group was defined as A. During this infiltration process, the impregnation temperature was 90 °C, while the immersion time was 24 h to ensure uniform soaking.
Subsequent hot-pressing (R-3212 Hot Press, Wuhan Qien Science and Technology Development Co., Ltd, China) promoted the dissolution of cellulose or cellulose/lignin with the synergistic effect of heat, pressure, and solvent. The hot-pressed veneer exhibited plastic deformation without fracture.
Afterward, in-situ partially dissolved veneers were placed into DW at room temperature to replace IL during the coagulation bath. Finally, the in situ modified veneers were dried by hot-pressing at 6 MPa and 160 °C for 30 min, and the resulting wood composites had a densified structure and excellent mechanical robustness. This hot pressing process can not only dry the modified veneer, but also fix the shape of the veneer to prevent it from deforming.
Fig. 1. Fabrication of novel wood composites
Scanning Electron Microscopy (SEM)
Scanning electron microscopy (S-48, Hitachi, Tokyo, Japan) was used to visualize the microstructure and evaluate the surface morphology of the novel wood composites. The samples were dried and sputter-coated with gold using an ion sputter coater (E1010, Hitachi) for 30 s with a current of 10 mA prior to observation. The surface topography of the samples was observed with a SEM using an accelerating voltage of 5 kV.
Tensile Test
The samples were cut into longitudinal samples with dimensions of 30 mm × 3 mm. 5 samples of each group were selected randomly. The mechanical properties were determined by the standard test method of ASTM D638 (2022), using the electronic universal material testing machine (AG-X plus, Shimadzu, Kyoto, Japan) at 25 °C and 50% relative humidity. The crosshead velocity was 10 mm/min (Khakalo et al. 2020).
Fourier Transform Infrared (FTIR) Spectrometry
The samples were also cut into longitudinal samples with dimensions of 30 mm × 3 mm. The attenuated total reflectance (ATR) mode of an FTIR Spectrometer (Tensor Ⅱ, Bruker, Karlsruhe, Germany) was used to investigate the chemical components and their changes on the surface of samples without damage. The scanning resolution was 4 cm-1. Both the background and sample scanning time were 32 s. The scanning wavelength ranged from 4000 to 400 cm-1 (Khakalo et al. 2019).
X-ray Diffraction (XRD)
The samples were ball-milled after being frozen in liquid nitrogen, and the dried powder was used for XRD analysis. The powder XRD patterns for all samples were measured in reflection mode (CuKα radiation) on an X-ray diffractometer (XD-3, Beijing Purkinje General Instrument Co., Ltd, China) with a voltage of 36 kV and a current of 20 mA. Diffractograms were recorded in an angular range of 10° to 40° (2θ) with a scanning speed 0.5°/min. According to the scanning pattern, the (002) diffraction peak was near 2θ = 22°, whereas there was a minimum valley near 2θ = 18°. The relative crystallinity index (CrI) was calculated according to the empirical formula of Segal et al. (1959),
(1)
where I002 is the intensity of the (002) diffraction angle (near 2θ = 22°), Iam is for non-crystalline diffraction background scattering intensity (near 2θ = 18°), and CrI is the relative crystallinity index.
RESULTS AND DISCUSSION
Morphology Analysis
Figure 2 shows that there were obvious macroscopic changes in 3 treated groups compared with group A. The increase of group D in width direction was the most evident, which indicated PEG could reduce the viscosity of the solvent system. The carrier [Bmim]Cl improved the swelling of lignocellulose during impregnation. During hot-pressing, [Bmim]Cl and PEG enhanced the plasticity of lignocellulose and promoted the dissolution of the veneer components under the synergistic effect of temperature, pressure, and time. For group C, PEG swelled the veneers during impregnation and only partially dissolved lignin during hot pressing. For group B, high viscosity led to limited penetration during impregnation and uneven dissolution during hot-pressing. The plasticity of group B treated by [Bmim]Cl was higher than the one treated by PEG, whereas the combination of PEG and [Bmim]Cl for group D resulted in the best ductility.
Fig. 2. Photos of samples
SEM images of each group (Fig. 3) showed that both [Bmim]Cl and PEG enhanced the plasticity of the veneers. For PEG treatment group (C), PEG swelled the veneers during impregnation and partially dissolved lignin during hot pressing to improve its anisotropy. The porous structure was densified by molding and shaping of the liquefied part. During impregnation and hot pressing, the ILs in Group B and D partially dissolved lignin and cellulose in wood. At the same time, hot pressing, with the synergy of temperature, pressure, and time, made the veneer easy to deform, which greatly improved its ductility. Among them, the veneers were not plasticized enough by [Bmim]Cl. When PEG was added to [Bmim]Cl to promote the dissolution of the wood components, the ductility of the sample was more obvious under the hot-press. Through molding, the reorganized veneer structure during the coagulation bath was fixed to make it denser, which improved the morphology and mechanical properties (Abushammala and Mao 2020).
Fig. 3. SEM images of untreated wood (A) and in situ modified wood composites (B: the [Bmim]Cl-treated group; C: the PEG-treated group; D: The PEG-[Bmim]Cl-treated group)
Mechanical Properties
The mechanical properties of wood are determined by the properties of cell walls. Wood is a natural porous material that is formed by a large number of capillary systems of different scales in series or parallel. High porosity provides natural channels for the modification treatment of poplar wood. During impregnation, PEG or [Bmim]Cl was absorbed by veneer surfaces and gradually diffused. Under hot-pressing, PEG and [Bmim]Cl penetrated the cell wall to dissolve its components, which are then regenerated and reorganized into more compact structures (Croitoru and Roata 2020). Previous research has shown that [Bmim]Cl improves the material properties and plastic deformation, and the modified poplar veneers tend to be isotropic (Shu et al. 2017; Neyses et al. 2021). PEG produced the same result. The thickness, density, and longitudinal mechanical properties are shown in Table 1.
The tensile strength (TS) of Group D with the PEG-[Bmim]Cl solvent was the highest. There was almost no difference of elongation at break (EAB) and initial elastic modulus (E0) among B, C, and D. By partially dissolving the components, each treatment promoted the regeneration and reorganization of the components. The control group (A) had the lowest TS, EAB, and E0. While the mechanical properties of three treated groups were improved, Group D had the best comprehensive mechanical properties. This result showed that PEG and [Bmim]Cl synergistically dissolved the components in the veneer, increasing the percentage of matrix phase, and the interfacial bonding between matrix phase and reinforcement phase was also enhanced (Acosta et al. 2020).
Table 1. Mechanical Properties of Untreated Wood (A) and in situ Modified Wood Composites (B: the [Bmim]Cl-treated group; C: the PEG-treated group; D: The PEG-[Bmim]Cl-treated group)
FTIR Analysis
The FTIR spectrum of each group is shown in Fig. 4. All FTIR spectra were similar, exhibiting the main peaks of lignocellulosic materials. It can be concluded that there were no other derivatization reactions during the treatment, and the components of poplar veneer were changed only in the proportions of cellulose, hemicellulose, and lignin. Therefore, the intensity of some corresponding absorbance peaks was different (Xiong et al. 2015)
Fig. 4. ATR-FTIR spectra of untreated wood (A) and in situ modified wood composites (B: the [Bmim]Cl-treated group; C: the PEG-treated group; D: The PEG-[Bmim]Cl-treated group)
For Group B, the dissolved components were regenerated and reorganized in the coagulation bath. Although the intermolecular hydrogen bonds were not completely restored after recombination, they were rarely lost overall. Compared with the control group (A), the position and intensity of the absorbance band were not significantly different. At the same time, there was no characteristic peak of IL in group B, indicating that the ionic liquid was replaced in the coagulation bath.
For Group C, there were no characteristic peaks of PEG at 2900 cm-1, 1330 cm-1, and 1460 cm-1, which may be due to substitution during the coagulation bath (Hu et al. 2013). For Group D, even if a small amount of PEG remained, high temperature may cause decomposition. Because lignin can be quickly degraded in alcohol, PEG cooperates with IL to destroy the lignin that wraps cellulose faster. The characteristic peaks of lignin at 1590 and 1507 cm-1 were weakened. However, the cellulose dissolved in the process of impregnation and hot pressing can be regenerated. Thus, there was an obvious characteristic absorbance peak of cellulose (Xie et al. 2012).
XRD Analysis
In Fig. 5, the (002) crystal planes of groups A, B, C, and D were located at 21.97°, 21.73°, 21.77°, and 21.70°, and their (001) crystal planes were located at 15.82°, 15.23°, 15.01°, and 15.16°, respectively. The (002) and (001) plane of each group had a very slight offset to the left, which remained in the vicinity of 2θ=22° and 2θ=15°, and the interlayer spacing of crystal planes among each group had almost no change, which indicated each treatment had no effect on its crystalline region. Each group had a trough near 2θ=18°, which was the maximum value of the scattering intensity of the amorphous region. So the crystal structure of the modified group was still the same as the control group.
Through calculation, CrI of each group was 67.0%, 73.4%, 73.0%, and 72.8%, respectively. The CrI of the wood composites of Group B, C, and D increased, and there was almost no difference. To a certain extent, CrI can reflect the physical and chemical properties of plant biomass materials, and it was an important basis for evaluating the mechanical properties. Generally, the tensile strength and other mechanical properties of lignocellulosic materials increase with higher CrI (Oosthuizen et al. 2023). The CrI corresponded to the tensile strength in Table 1.
Fig. 5. XRD spectra of untreated wood (A) and in situ modified wood composites (B: the [Bmim]Cl-treated group; C: the PEG-treated group; D: The PEG-[Bmim]Cl-treated group)
For Group B, [Bmim]Cl fully wetted the veneer under the temperature of 90 °C, and very few components were dissolved during impregnation. When hot-pressed under the temperature of 160 °C, more lignin and carbohydrates were dissolved by [Bmim]Cl. At the same time, the increased fluidity of the cellulose chain promoted the reorganization of the amorphous region of cellulose. In the coagulation bath, the dissolved part was regenerated and reorganized. However, the dissolved hemicellulose was lost in the coagulation bath, which led to an increase in CrI, reaching 73.4%.
PEG can penetrate the wood cell wall and act as a swelling agent, leaving the cell wall in a permanent swelling state and no longer shrinking. The cellulose also swelled, which mainly included two types: swelling in the intra crystallization region and swelling in the inter crystallization region. When the swelling agent only penetrated the amorphous region, swelling of the intercrystalline region occurred, and the XRD pattern remained unchanged with the peak intensity changed. When the swelling agent can penetrate the amorphous and crystalline regions, swelling in the intra crystallization region occurred (Xu 2012). From Figure 4, only the swelling of the intercrystalline region occurred in each treatment group. For Group C, PEG can enter the amorphous region of cellulose, causing the amorphous region to swell. PEG itself was partly crystalline with a certain degree of crystallinity. Without protection of IL, even a small amount of retained PEG was to be thermally decomposed into smaller molecules under the high temperature. Therefore, the amorphous area was degraded without affecting the compact crystalline area, resulting in an increase in crystallinity and no characteristic peaks of PEG (2θ=19° and 23 °).
For the PEG-[Bmim]Cl-treated group, the veneers were easily dissolved because of the different solubility between PEG and [Bmim]Cl (Rodriguez et al. 2009). During the coagulation bath, PEG or [Bmim]Cl were replaced. Thus, the peak intensity of C and D spectra in Fig. 5 changed, but there was no characteristic diffraction peak of PEG (Meints et al. 2018).
CONCLUSIONS
- Using poplar veneers as the raw material and [Bmim]Cl, PEG, or PEG-[Bmim]Cl as the solvent system, novel wood composites were developed through a series of impregnation, hot pressing, coagulation bath, and drying. The solvent can be effectively replaced in the coagulation bath to obtain all-wood composite materials with plasticity, which provides a basis for the molding of wood.
- The macroscopic and microstructures of each treatment group showed that: [Bmim]Cl, PEG or PEG-[Bmim]Cl all made the veneers swell and enhance their plasticity and ductility. The synergistic effect of immersing in the solvent system and hot pressing facilitated the wood components to dissolve and flow. After the coagulation bath, the dissolved part reorganized. Thus, the modified veneers tended to be uniform in all directions. Group D had the best ductility with the biggest macroscopic dimensional change. PEG as a co-solvent can help dissolve the veneers, and the veneers’ plasticity and ductility can be improved by the synergistic effect of PEG and [Bmim]Cl.
- The tensile strength (TS), elongation at break (EAB), and initial elastic modulus (E0) of each treatment group were higher than that of untreated one. These results indicated that the partial dissolution of the components by the solvent system can promote the recombination of the components during the coagulation bath process, thereby improving the mechanical properties and plasticity of the veneers. Group D had the best overall mechanical properties, which was attributed to synergistic solubility of PEG and [Bmim] Cl, increasing the percentage of matrix phase. The interface bonding between the matrix phase and the reinforcement phase was enhanced, thereby improving its comprehensive mechanical properties.
- The relative crystallinity of group B (73.4%) was the highest. Group A (67.0%) was the lowest. The relative crystallinity was consistent with the mechanical properties. No characteristic Fourier transform infrared (FTIR) peaks of PEG were found in Groups C and D, indicating that no other derivatization reactions occurred in each treatment. Only some of the absorbance peaks were different in intensity. Both from X-ray diffraction (XRD) and FTIR, the composition of poplar veneer was not changed, only the ratio of cellulose, hemicellulose, and lignin changed.
ACKNOWLEDGMENTS
The authors are grateful for the support of Anhui Natural Science Foundation (2018085MC84), the College Students Innovation and Entrepreneurship Training Program (X202210364429, X202210364678, X202210364485).
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Article submitted: May 17, 2023; Peer review completed: June 3, 2023; Revised version received and accepted: June 28, 2023; Published: August 7, 2023.
DOI: 10.15376/biores.18.4.6815-6826