Research Articles
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- Researchpp 2618-2634Čabalová, I., Kačík, F., Gojný, J., Češek, B., Milichovský, M., Mikala, O., Tribulová, T., and Ďurkovič, J. (2017). "Changes in the chemical and physical properties of paper documents due to natural ageing," BioRes. 12(2), 2618-2634.AbstractArticlePDFThe aim of this study was to assess the changes in chemical and physical properties of selected paper documents, dating from the 18th century to the present date. Paper documents from the 18th, 19th, and 21st centuries had a pH ranging from slightly acidic to alkaline values, whereas paper documents from the 20th century were more acidic. The contents of mannose, glucose, holocellulose, and lignin were significantly correlated with the pH of the paper. High contents of both carboxylic acids (acetic and formic) and the most durable monosaccharide (glucose) were found in the oldest examined paper documents originating from the 18th and 19th centuries. The lowest percentage of brightness was found in paper documents originating from 1920 and 1923. The lowest breaking length was associated with papers originating from 1920.
- Researchpp 2635-2645Francezon, N., and Stevanovic, T. (2017). "Chemical composition of essential oil and hydrosol from Picea mariana bark residue," BioRes. 12(2), 2635-2645.AbstractArticlePDF
For the first time, the essential oil of Black spruce (Picea mariana) bark residue was obtained using two types of hydrodistillations: steam distillation (SD) and water distillation (WD). Both gave similar yields and compositions as analyzed using gas chromatography and mass spectrometry. The essential oil composition is turpentine-like with the predominance of α-pinene (40.6% SD; 40.5% WD) and β-pinene (33.9% SD; 25.9% WD), followed by hydrocarbon monoterpenes β-phellandrene (4.8% SD; 3.6% WD), 3-carene (4.1% SD; 3.1% WD), and limonene (4.0% SD; 3.7% WD). Hydrosol’s composition is rich in oxygenated compounds with α-terpineol (29.3% SD; 33.5% WD), trans-pinocarveol (5.2% SD; 3.7% WD), terpinen-4-ol (5.0% SD; 5.8% WD), verbenone (4.9% SD; 5.4% WD), borneol (4.9% SD; 3.9% WD), and pinocarvone (4.6% SD; 4.3% WD). These black spruce bark essential oils differ in composition from those from needles, which are commercially available and rich in bornyl acetate.
- Researchpp 2646-2659 Tian, Z., Chen, J., Ji, X., Lyo, G., Lucia, L. A., Yang, G. (2017). "Fractionation and characterization of three main components from Pennisetum sinese Roxb. (P. sinese) by microwave-assisted H2O2-NaOH extraction," BioRes. 12(2), 2646-2659.AbstractArticlePDFFractionation of lignocellulosic components is a prerequisite for maximizing valorization of plant biomass in an integrated biorefinery. In this study, microwave-assisted H2O2-NaOH extraction was developed for fractionation of Pennisetum sinese Roxb. (P. sinese), a highly productive energy crop. Different reaction conditions including solid-liquid ratio, NaOH concentration, H2O2 concentration, temperature, and time were tested for their effects on P. sinese fractionation. The cellulose, hemicellulose, and lignin obtained under optimal fractionation conditions were characterized by Fourier transform infrared spectrometry (FT-IR) and nuclear magnetic resonance (NMR). The optimal fractionation conditions were a solid-liquid ratio of 1:25 using 0.5% H2O2 and 4% NaOH at 75 °C for 4 h, which gave cellulose, hemicellulose, and lignin yields of 42.8%, 21.9%, and 15.2%, respectively. FT-IR and NMR analyses of the fractionated components clearly confirmed their structural integrity and representation. The work demonstrates the potential of the alternative approach for efficient fractionation of lignocellulosic biomass components for further valorization.
- Researchpp 2660-2672Pesenti, H., Torres, M., Oliveira, P., Gacitua, W., and Leoni, M. (2017). "Exploring Ulex europaeus to produce nontoxic binderless fiberboard," BioRes. 12(2), 2660-2672.AbstractArticlePDFUlex europaeus is one of the most abundant and aggressively invasive plants on the world. Its fibres, which can be isolated using an alkaline pulping process, have been successfully thermo-pressed into high-density fibreboards without any type of binder. The influence of the bioorganic and crystalline components on the product was investigated using crystallographic, thermo-analytical, and mechanical techniques. Cellulose was predominantly an Iβ polymorph, more common in hardwood, but the composition of the material was typical of softwood. Both the crystallinity in the fibres and the average domain size of cellulose increased during thermo-pressing. Notwithstanding that the residual lignin was present in a small amount, this promoted the cohesion of fibres by improving hydrolysis and adhesion properties. The best overall properties were observed in the pressed products of 1030 ± 38 kg/m3, showing an elastic modulus of 4.31 ± 0.26 GPa, with a modulus of rupture of 26.5 ± 1.3 MPa. These results serve as the basis to transform the invasive species into a fully non-toxic added-value resource.
- Researchpp 2673-2689Zaharia, S. M., Morariu, C. O., Nedelcu, A., and Pop, M. A. (2017). "Experimental study of static and fatigue behavior of CFRP-balsa sandwiches under three-point flexural loading," BioRes. 12(2), 2673-2689.AbstractArticlePDFBalsa wood is a natural cellular material with an excellent resistance-to-weight ratio that is ideal for manufacturing the core of sandwich structures. In this study, sandwich specimens with a carbon-fiber-reinforced polymer (CFRP) skin and a balsa wood core were tested with static and dynamic loading. Three-point flexural tests in static regime determined the mechanical characteristics of the CFRP-balsa specimens that were needed for subsequent fatigue strength tests. Also, experimental research was performed on the Charpy impact response of the CFRP-balsa sandwich specimens. This study implemented an accelerated fatigue testing method to identify and predict the mean fatigue life of the CFRP-balsa sandwich specimens subjected to cyclic fatigue via three-point flexural tests. Using the accelerated fatigue and the three-point flexural testing methodology on the CFRP-balsa sandwich specimens, the testing period was reduced by 11.9 times, and thus the material costs necessary for the tests were also reduced. Also, the breaking surfaces were analysed to reveal the failure modes of CFRP-balsa specimens subjected to static and fatigue tests at three-point flexural and at impact tests.
- Researchpp 2690-2698Mertoglu-Elmas , G. (2017). "The effect of colorants on the content of heavy metals in recycled corrugated board papers," BioRes. 12(2), 2690-2698.AbstractArticlePDF
Recycled paper is an important raw material to provide sustainability of natural resources and reduce the environmental impact of the use of paper from recycled pulp in the packaging industry. Hence, recycled paper production is higher in terms of volume and utilization. Recycled paper products are used in the packaging industry partially or fully. Such usage leads to the presence of heavy metals due to recycled and chemical additive sources. The present study aims at determining the amounts and also identifying the sources of heavy metals such as Pb, Cd, Zn, Ni, and Cu contained in recycled testliner (TL) and fluting (FLT), which are main products used in production of corrugated cardboard. The metals in the structure of the paper used in packages directly or indirectly in contact with foods are heavy metals. Mean values of 2.6 mg kg-1 Pb (lead), 2.8 mg kg-1 Zn (zinc), 0.094 mg kg-1 Cd (cadmium), 1.8 mg kg-1 Ni (nickel), and 25.4 mg kg-1 Cu (copper) were detected in test liner and fluting papers using inductively coupled plasma optical emission spectrometry (ICP-OES). The main sources of heavy metals are colorants, mainly consisting of conventional paint and pigments as well as spot and Pantone Matching System (PMS) colorants.
- Researchpp 2699-2710Liu, H., Luo, B., Shen, S., and Li, L. (2017). "Design and mechanical tests of FRP pipe with bamboo and veneer layer," BioRes. 12(2), 2699-2710.AbstractArticlePDF
Pipes that are light in weight are necessary for convenience and to reduce the cost of transportation and installation. A new design of glass fiber reinforced plastic (FRP) pipe with a bamboo and veneer layer is presented in this paper. The core layer of the sandwich structure of the pipe wall is made of bamboo and veneer, and the inner and outer layers are FRP. Range analysis and variance analysis of orthogonal experiments were conducted to investigate the effect of fiber stress, winding angle, and core material on the mechanical performance of the pipes subjected to shearing and parallel-plate loading tests. The results indicated that the new design of FRP pipe with a bamboo and veneer layer was feasible, and the pipe had better mechanical performance with a fiber stress of 300 N, a winding angle of 30°, and a core material of bamboo. Core material was the most influential factor in mechanical performance. The average density of pipes was 0.94 g/cm3, approximately half that of the glass fiber reinforced plastic mortar (GRPM) pipes. The FRP pipe offered advantages in terms of weight savings and improved mechanical performance, and it showed a great application potential for the future.
- Researchpp 2711-2720Liao, C., Zhang, H., Song, X., Chen, T., and Huang, S. (2017). "The screening method of the internal defects in wood members of the ancient architectures by hammering sound," BioRes. 12(2), 2711-2720.AbstractArticlePDF
Defects have a serious impact on the load carrying capacity and the safety of ancient architectural wood members. Common screening methods to identify defects cause damage to this wood. To protect ancient architecture, it is necessary to develop a method that can screen for internal defects and estimate their size quickly and efficiently without destruction. This paper studied the detection mechanism of the sound hammering method for screening internal defects in wood. Wood members generated different kinds of vibration through hammering experiments, and the vibration produced by hammering wood with internal-hole defects was divided into three kinds: local surface vibration, the whole structure vibration, and defective-part vibration. The parameters and their variation of these three kinds of vibration were investigated by a mechanical vibration simplified model, and the method for screening the internal defects based on sound hammering was proposed. The feasibility of the method was verified by experiments.
- Researchpp 2721-2730Büyüksarı, U. (2017). "Effect of loading rate on mechanical properties of micro-size Scots pine wood," BioRes. 12(2), 2721-2730.AbstractArticlePDF
The use of micro-size samples is becoming more important to determine the mechanical properties of wood. The aim of this study was to investigate the effect of the loading rate on the micro-mechanical properties of Scots pine (Pinus sylvestris L.) wood. The bending strength, modulus of elasticity in bending, compression strength parallel to the grain, and tensile strength parallel to the grain were determined using micro-size test samples. Three different loading rates were used for each test. The first loading rates were determined according to related ISO standards, and the second and third loading rates were determined as half- and quarter- of the standard loading rates. The results showed that the loading rate had significantly affected the modulus of elasticity and compression strength of Scots pine wood. However, the loading rate had no significant effect on the bending and tensile strength of the Scots pine wood. When the loading rate decreased, the mechanical properties of micro-size Scots pine wood were decreased.
- Researchpp 2731-2747Zhang, B., Leng, E., Wang, Y., Gong, X., Zhang, Y., and Xu, M. (2017). "Characterization of water-soluble intermediates and solid residues from fast pyrolysis of cellulose in a wire-mesh reactor," BioRes. 12(2), 2731-2747.AbstractArticlePDFThe fast pyrolysis characteristics of cellulose were investigated in a wire-mesh reactor, which minimized the secondary reactions between the solid residues and the evolved volatiles during pyrolysis and facilitated the collection of the primary intermediates and volatiles. The main component of the water-soluble intermediates was anhydro-oligosaccharides with various degrees of polymerization (DP). The yields of cellotriosan and cellotetraosan in the intermediates were much higher than those of levoglucosan and cellobiosan in the early pyrolysis stage, indicating that the depolymerization of the cellulose chain occurred during a random cleavage process. Anhydro-oligosaccharides with DP up to 3, and partially decomposed sugar-ring-containing oligomers, were identified in the primary volatiles. Among the sugar-ring-containing oligomers, the compound with a relative molecular weight of 222 was considered to be the product of a reverse aldolization reaction. An analysis of the solid residues confirmed the occurrence of intramolecular dehydration during the cellulose pyrolysis.