NC State
BioResources
  • Researchpp 434-447Wu, H., Xue, Y., Li, H., Gan, L., Liu, J., and Long, M. (2017). "Heterologous expression of a new acetyl xylan esterase from Aspergillus niger BE-2 and its synergistic action with xylan-degrading enzymes in the hydrolysis of bamboo biomass," BioRes. 12(1), 434-447.AbstractArticlePDF
    Efficient utilization of plant biomass by enzymatic hydrolysis is currently studied worldwide but still faces enormous challenges because of the inability to break down lignocellulosic materials with high sugar yields and low enzyme dosage. Therefore, the synergistic action between various enzymes plays an important role in reaching this goal. The synergistic cooperation between a novel acetyl xylan esterase (heterologous expressed at high levels in this study) and four other xylan-degrading enzymes (reported previously) were performed in this study. The acetyl xylan esterase (AnAxe) gene was cloned from Aspergillus niger BE-2 and expressed in Pichia pastoris GS115. The deduced amino acid (aa) sequence consisted of 304-aa and included a 23-aa signal peptide and 281-aa mature protein. The AnAxe was extracellularly expressed with a molecular weight of ca. 31 kDa. The purified AnAxe exhibited maximal specific activity of 480.2 IU/mg at pH 7.0 and 40 °C and was still thermostable below 50 °C. The metal ions used in this study and EDTA showed a slight effect on the AnAxe. A significant synergistic effect was determined between AnAxe and the other four xylan-degrading enzymes, including endo-Beta-1,4-xylanases, Beta-xylosidases, alpha-L-arabinofurano-sidases, and alpha-glucuronidases, on the degradation of bamboo biomass. The highest degree of synergism was obtained between AnAxe and endo-Beta-1,4-xylanases/Beta-xylosidases.
  • Researchpp 448-456Gáborík, J., Gaff, M., Ruman, D., Šomšák, M., Gaffová, Z., Svoboda, T., Vokaty, V., and Síkora, A. (2017). "The influence of thermomechanical smoothing on beech wood surface roughness," BioRes. 12(1), 448-456.AbstractArticlePDF

    This paper deals with the change of roughness of compressed beech wood. Effects of temperature, pressure, and time on the results of pressing were examined. The surface roughness of beech wood in longitudinal and transversal directions was evaluated. Roughness was described by Ra. A contact method was applied. The results show that by increasing pressure, time, or temperature, the surface roughness of beech wood decreases. The highest roughness reduction occurred at the temperature of 150 °C, pressure 4 MPa, and time 20 min.

  • Researchpp 457-468Yang, Z., Zhang, J., Zhang, M., Wang, M., and Cao, J. (2017). "Characteristics of pollution from waste liquor of poplar pre-conditioning refiner chemical alkaline peroxide mechanical pulping," BioRes. 12(1), 457-468.AbstractArticlePDF
    The molecular weight distribution and composition of organic pollutants from chemi-mechanical pulping waste liquor was studied using ultra-filtration, Fourier transform infrared spectra, and gas chromatography-mass spectrometry. The concentration of dissolved chemical organic compounds was approximately 1.81 × 104 mg·L-1. In addition, the wastewater had poor biodegradability. The chemical oxygen demand (COD) was primarily composed of small molecular organic pollutants, and the larger pollutants in the waste liquor were its primary source of color. The data indicated that there were chromophoric and auxochrome groups in the waste liquor. The waste liquor contained 38 types of organic pollutants, which were aromatic compounds, including phenols, ketones, alcohols, and fatty acids.
  • Researchpp 469-477Yan, L. Y., Li, S. Y., and Song, X. L. (2017). "Preparation of paper strengthening agent by esterification of cellulosic fines," BioRes. 12(1), 469-477.AbstractArticlePDF
    Paper strengthening agents play an important role in the papermaking industry with the increase of secondary fiber applications. The objective of this study was to create a dry-strength agent by esterification. The fines from the pulp were collected and modified with trimesic acid and citric acid, respectively, to obtain the dry-strength agent. The influences of acid type and dosage on the enhancing effect were investigated. Compared with the control sample, the physical properties of paper sheet were improved after adding modified fines. The properties of recycled paper were also improved by the modified fines. When the dosage of citric acid agent was 7%, the effect on paper properties saw the greatest improvement. The tensile index, burst index, and folding endurance were increased by 60.3%, 18.3%, and 146.2%, respectively, compared with the control. The improvement of paper properties was due to the increase of carboxyl content in the modified fines. Based on the findings, it can be concluded that the esterification is an effective approach for producing paper dry-strengthening agent.
  • Researchpp 478-494Ouyang, H., Hou, K., Wang, L., and Peng, W. (2017). "Optimization protocol for the microwave-assisted extraction of antioxidant components from Pinus elliottii needles using response surface methodology," BioRes. 12(1), 478-494.AbstractArticlePDF
    Response surface methodology (RSM) based on a Box–Behnken rotatable design was used to determine the optimum conditions for the microwave-assisted extraction of antioxidant compounds from Pinus elliottii needles. Four process variables were evaluated at three levels (29 experimental conditions): ethanol (50, 70, and 90%), solvent:solute ratio (25:1, 20:1, and 15:1), extraction temperature (60, 70, and 80 °C), and ultrasonic power (100, 150, and 200 W). Using RSM, a quadratic polynomial equation was obtained by multiple regression analysis to predict the optimized extraction protocol. The radical scavenging capacity was determined by O2−, ·OH, and DPPH methods. For the microwave-assisted extraction of antioxidant compounds from Pinus elliottii needles, the optimum process used ethanol at 72%, a solvent:solute ratio of 21:1 mL/g, an extraction temperature of 67 °C, and an ultrasonic power of 200 W. The results indicated good correlation between total polyphenols content and O2−, ·OH, and DPPH radical scavenging activities.
  • Researchpp 495-513Gašparík, M., Gaff, M., Ruman, D., Záborský, V., Kašičková, V., Sikora, A., and Štícha, V. (2017). "Shear bond strength of two-layered hardwood strips bonded with polyvinyl acetate and polyurethane adhesives," BioRes. 12(1), 495-513.AbstractArticlePDF

    This article deals with the effects of various parameters on the shear bond strength (SBS) of glued wood. A four-factor analysis showed that the combination of only non-densified wood pieces achieves higher shear bond strength values than densified ones. In this case, only the piece combination was a significant factor. The other factors (glue type, wood species, and number of loading cycles) had no significant effect. Although the differences were not large, a higher SBS was achieved in beech wood glued with polyvinyl acetate (PVAc) glue. Glued wood consisting of the combination of densified and non-densified pieces had slightly lower SBS values. In this case, all the factors were statistically significant. Beech wood had a more significant impact on the SBS than aspen wood. The effect of the type of glue showed an opposite trend than that in the previous variant, i.e., a higher SBS was achieved with polyurethane (PUR) glue. Wood subjected to cyclic loading had slightly higher SBS values than non-cyclically loaded wood. The degree of densification had no significant effect. Glued wood composed entirely of densified pieces showed greater SBS variation between versions.

  • Researchpp 514-532Wang, B., Li, D. L., Chen, T. Y., Qin, Z. Y., Peng, W. X., and Wen, J. L. (2017). "Understanding the mechanism of self-bonding of bamboo binderless boards: Investigating the structural changes of lignin macromolecule during the molding pressing process," BioRes. 12(1), 514-532.AbstractArticlePDF

    Binderless boards were produced from bamboo particles through a molding pressing process. The boards were investigated for the chemical and structural changes of lignin and their mechanical strengths to evaluate the mechanism of self-bonding. The structural transformations of milled wood lignin (MWL) obtained from raw bamboo and molding pressed bamboo boards were investigated by Fourier transform infrared (FT-IR), gel permeation chromatography (GPC), quantitative 13C-NMR spectra, two-dimensional heteronuclear single quantum coherence (2D-HSQC) spectra, 31P-NMR, thermogravimetric analysis (TGA), and differential scanning calorimetry (DSC) techniques. Both molding press temperature and time affected the distribution and abundance of typical lignin linkages (β-O-4′, β-β′, and β-5′), as well as the S/G ratios of the lignin, demethoxylation, and the contents of attached molecules (PCE). In addition, a decrease in aliphatic OH and an increase in phenolic hydroxyl groups occurred in lignin as molding pressing proceeded. The optimal internal bonding strength (0.98 MPa) of the bamboo binderless board was obtained under the condition of 180 ºC for 20 min. Although the lignin obtained under this condition was structurally similar to the raw MWL, the decreased molecular weight, increased phenolic hydroxyl groups, and observable glass-transition temperature (thermal softening of lignin) provide some evidence to explain the acceptable internal bonding strength.

  • Researchpp 533-545Liang, S., Zhang, L., Chen, Z., and Fu, F. (2017). "Flame retardant efficiency of melamine pyrophosphate with added Mg-Al-layered double hydroxide in medium density fiberboards," BioRes. 12(1), 533-545.AbstractArticlePDF
    The main objective of this study was to investigate the flame retardant (FR) efficiency of melamine pyrophosphate (MP) with added layered double hydroxide (LDH) in medium density fiberboards (MDFs) to be used as building decorative materials. The thermal degradation, FR efficiency, and combustion properties of MDF were analyzed by Fourier transform infrared spectra (FTIR), thermogravimetric analysis (TGA), limiting oxygen index (LOI) test, and cone calorimetric test. The TGA results showed that the combination of MP and LDH led to a lower decomposition temperature than the pure MP and pure LDH. The LOI results showed that the LOI values increased with the addition of the FRs. The cone calorimetric results showed that the addition of four proportions (1:1, 2:1, 1:2, and 1:3) of the compounds into MDF can clearly decrease the peak heat release rate (PHRR) and mean heat release rate (MHRR). The results indicated that the MP and LDH compounds have a synergistic effect to improve the flame retardancy and smoke suppression in the MDFs. The combination of MP and LDH in a 1:1 ratio under 10 wt% FR addition has the best flame retardant efficiency in the MDFs.
  • Researchpp 546-570Gosselin, A., Blanchet, P., Lehoux, N., and Cimon, Y. (2017). "Main motivations and barriers for using wood in multi-story and non-residential construction projects," BioRes. 12(1), 546-570. AbstractArticlePDF

    Steel and concrete are traditionally used as structural materials for non-residential and multi-housing buildings. However, wood can meet the same structural property requirements, and a variety of multi-story buildings have recently been built all over the world using this key material. In this study, the main motivations and barriers to wood adoption for structural uses in non-residential buildings are highlighted, based on an analysis of grey literature concerning some well-known buildings and on scientific literature. The motivations found were linked to sustainability, lack of expertise, costs, rapidity of erection, and aesthetic of wooden structures. In contrast, the barriers preventing its use encompass building code implementation, technology transfer, costs, material durability and other technical aspects, culture of the industry, and material availability. Furthermore, an analysis of non-residential timber building meeting minutes for nine projects is also presented to support the identification of problems and concerns related to site assembly issues, the conception of the building, the scheduling, and stakeholders’ relationships. With a better understanding of the expectations and challenges concerning wood usage in non-residential construction projects, companies will be able to adapt their business models and use the resource even more in the future to develop innovative structures.

  • Researchpp 571-585Chang, L., Guo, W., and Tang, Q. (2017). "Assessing the tensile shear strength and interfacial bonding mechanism of poplar plywood with high-density polyethylene films as adhesive," BioRes. 12(1), 571-585.AbstractArticlePDF
    A series of high-density polyethylene (HDPE) films were tested as adhesives for plywood and were fabricated using hot pressing followed by cold pressing. The effects of the moisture content, HDPE dosage, and the hot-press temperature and pressure on the mechanical properties were evaluated by analyzing the tensile shear strength. The results indicated that the HDPE films that were used as adhesives in plywood had good bonding strength, meeting the requirements for type II-grade plywood according to the GB/T 9846.3 standard (2004, Beijing, China). The bonding mechanism was also investigated using the width of the bond line, the average penetration (AP), and the effective penetration (EP) through the use of optical microscopy and scanning electron microscopy (SEM). The results showed that the HDPE is able to penetrate into the vessels, xylem, and so on. On the whole, both the AP and EP increased with an increase in the HDPE dosage and hot-press temperature and pressure, but not with an increase in the moisture content. In addition, the effects of the factors mentioned above on the width of the bond line, AP, and EP were also investigated by an ANOVA analysis.

@BioResJournal

54 years ago

Read More