Volume 15 Issue 1

Removing xylan from the outer surface of cellulose could promote the accessibility of cellulase to cellulose. Under this premise, in order to develop an efficient pretreatment method to obtain fermentable reducing sugar from poplar fiber, a response surface methodology was created via the combination of the Plackett-Burman design and the Box-Behnken design and was utilized by the Design-Expert software. The optimum conditions were as follows: a liquid-solid ratio of 4.95 to 1 (mL/g), a pre-hydrolysis xylanase temperature of 70.3 °C, and a total hydrolysis time of cellulase of 52.9 h. Under these conditions, the maximum amount of reducing sugars converted from poplar fiber was 159.6 mg/g. The average amount from the validation results was 160.1 mg/g, which was in agreement with the predicted value. Meanwhile, the poplar fiber hydrolyzed via a xylanase-aided two-stage pretreatment was compared with the poplar fiber hydrolyzed via only a cellulase pretreatment, using scanning electron microscopy. The xylanase-aided treatment revealed a surface with a more damaged structure, indicating that the utilization of xylanase could further improve the effects of hydrolysis on poplar fibers.

The effects of extraction conditions on the yield of polysaccharides from the fruit of Chaenomeles sinensis (FCS) using a hot compressed water method were investigated. The results showed that an appropriately high temperature (150 °C) and a moderate extraction time (45 min) at a material to water ratio of 1 to 10 g/mL led to a high yield of alcohol precipitation polysaccharide (PA). The purified polysaccharides (CSP-1, CSP-2, and CSP-3) were successfully obtained using a DEAE-52 chromatographic column. Chemical analysis showed that CSP-2 and CSP-3 were homogenous and exhibited characteristics of esterified pectins, whereas CSP-2 mainly consisted of galacturonic acid (GalA), galactose (Gal), arabinose (Ara), rhamnose (Rha), and mannose (Man) with an average molecular weight of 59.1 kDa. Furthermore, CSP-1 possessed stronger antioxidant ability according to DPPH scavenging and reducing power compared with CSP-2 and CSP-3. However, it was weaker with respect to OH scavenging. The technical data presented in this study could help the industry make use of polysaccharides from FCS as a source of pectin for a range of pharmaceutical, culinary, and cosmetic products.

The contamination of agricultural soil with heavy metals is a complex phenomenon that causes negative consequences for various organisms. Poplars may have considerable phytoremediation potential, and this plant species can tolerate Cd, Cu, and Pb up to 15.6, 63.6, and 173.3 mg kg-1 soil, respectively, with 100% survival. The analyzed data revealed significant reduction in vegetative growth traits and leaf N, P, K, and carbohydrate (%) and leaf green color degree. However, a simultaneously significant increase in enzymatic activities and electrolyte leakage were recorded in comparison to control plants. A bioconcentration factor of plant organs was ˂ 1, and the translocation factors (TF) of Cd and Cu were ˂ 1 ( ˂100%) under various concentrations of each heavy metal, while TF of Pb was ˃ 1(>100%), except for the first level. More Cd, Cu, and Pb contents were localized in roots compared to leaves or stems. Thus, the risk of contamination through leaf can be minimized. Populus nigra has defense mechanisms against Cd, Cu, and Pb up to 7.8, 29.8, and 91.1 mg/kg soil, respectively because the tolerance index (TI) of either biomass or root was >0.8. Finally, it is a good candidate for research of phytoremediation and phytoextraction.

The residual peels of andiroba seeds were submitted to alkaline pretreatment that aimed to maximize the recovery of fermented sugar. Evaluation of the best operation performance via the reaction time variables (20, 60, and 100 min), NaOH concentration (2, 3, and 4% (m/v)), and temperature (60, 90, and 120 °C) at a fixed solids concentration of 5% (m/v) was performed. A Box-Behnken experimental design was used. Lignocellulosic material was characterized by cellulose (30.57 ± 1.00%), hemicellulose (15.08 ± 0.65%), lignin (36.02 ± 1.05%), extractives (7.49 ± 0.03%), and ash (1.53 ± 0.28%). The optimization was performed using the response surface methodology approach. The model provided a coefficient of determination (R2) of 0.95. The predicted optimal conditions for the process were a reaction time of 100 min, NaOH concentration of 4% (m/v), and temperature of 120 °C, which allowed the authors to obtain a saccharification of approximately 47.9%.

The selective removal of lignin can be a profitable value-added utilization for the pre-hydrolysis liquor (PHL) produced during kraft-based dissolving pulp production. In this work, the soluble lignin was removed from PHL using CaCl2, Al2(SO4)3, cationic polyacrylamide (CPAM), and a CPAM/Al2(SO4)3 dual-system treatment. The results of zeta potential recording revealed that 8.86% of soluble lignin was removed by CaCl2 treatment through charge neutralization and adsorption, and 13.1% soluble lignin was removed by CPAM through charge neutralization and flocculation bridging. The optimal dosages of CaCl2, CPAM, Al2(SO4)3, and CPAM/Al2(SO4)3 dual-system treatments were 2.0 wt%, 30 ppm, 300 ppm, and 60/300 ppm respectively, at which the soluble lignin removals were 8.09%, 9.24%, 18.3%, and 25.0%, respectively. Additionally, the total sugar loss by the CPAM/Al2(SO4)3 dual-system treatment was higher than that by other individual systems; however, the soluble lignin selective removal by the CaCl2 treatment was the highest, at over 80%.

To study the influence of process parameter changes on the properties of raw material obtained from corn rind, a central composite design (CCD) methodology with four factors and five levels was applied to statistically optimize the parameters. The stalk size, soaking time, working temperature, and processing speed were selected as influencing factors. The available fiber ratio, initial beating degree, and fiber aspect ratio were chosen as indicators. Response surface analysis methodology was employed for optimization. The results showed that the optimal range of parameters were as follows: 8 to 13 cm for the stalk size, 18 h for the soaking time, 60 °C for the working temperature, and 98 to 112 r·min-1 for the processing speed. In this optimal condition, the available fiber ratio was higher than 95%, initial beating degree was greater than 11 °SR, and fiber aspect ratio was greater than 50. The results could be applied to design and optimize the D200 type stalk fiber preparation machine and the process of making raw material.

Reducing particleboard thickness is one of the major approaches to decrease consumption volume of particleboard for furniture manufacture. This study employed an adhesive mixture of polymeric methane diphenyl diisocyanate (PMDI) and urea formaldehyde (UF) to produce single-layer medium density thin rice straw particleboard. The effects of various PMDI/UF formulations as well as board density on mechanical properties and water resistance of rice straw particleboard were studied. The results indicated that the mechanical properties and water resistance of the thin rice straw particleboard were appreciably affected by resin formulation. The panels bonded with PMDI/UF adhesive mixtures had mechanical properties and water resistance far superior to those bonded with UF. Higher PMDI content levels in resin mixtures led to improved mechanical properties and water resistance. Density influenced mechanical properties and water resistance of the thin rice straw particleboard. Increasing the density of the panel could upgrade the mechanical properties of the thin rice straw particleboard. The experimental outcomes showed that PMDI/UF resin systems had potential to substitute for pure PMDI resin in producing thin rice straw particleboard, which could effectively lower manufacturing cost and bring economic efficiencies due to reduced amount of pricey PMDI.

This experiment evaluated the taxonomic diversity of the fungal community in conventional (AP) and organic (OAP) apple pomace using high-throughput sequencing, applying fungal genetic barcodes to functional guilds. The most abundant taxonomic groups identified in both AP and OAP were the genera Aureobasidium, Cladosporium, and Alternaria, classified into the pathotroph-saprotroph-symbiotroph guild. The phenotype microarray provided insight into the role of the apple pomace fungal community in the ecosystem. It is theorized that adding apple pomace to the soil may improve the bioavailability of bioresource-based polyols. Evaluation of the antagonistic ability of the AP fungal community and Trichoderma atroviride G79/11 strain against pathogenic fungi was performed. Trichoderma G79/11 developed well on apple pomace and revealed the antagonistic mode against tested fungal plant pathogens. Therefore, it could be applied to soil as a formulation of AP with spores or AP with metaferm biopreparation.

Increasing demand for resonance spruce has led to gradual depletion of resources in traditional areas. Consequently, to meet the need for raw material to manufacture musical instruments, sorting has become the key operation of exploitation. This study was completed on the largest Romanian resonance wood resource, to maximize outputs of flitches for violin, cello, and double bass instruments by optimizing traditional requirements regarding quality of raw material with its current level. Ten resonance spruces were felled and gradually turned into semi-manufactured musical instruments. The material was analysed for defects in all stages of conversion. The frequency of zero defective samples was 60%. Evolution of defects along the trees indicated the tree section from 1 m to 12 m above the ground for musical instruments manufacturing. Output in terms of flitches ranged from one tree to another: between 19 and 32% if calculated from logs volume, and between 13 and 30% if calculated from volume of the standing trees. The results advocated for relaxing traditional requirements on resonance logs, at least regarding buttress and knottiness. Thus, recommendations are made, from the perspective of increasing efficiency, on the admissibility of defects and size diversification of musical instruments.

The objective of this study was to measure compressive strength properties perpendicular to the fiber of green Eucalyptus nitens specimens. The data was measured for clear 50 × 50 × 150 mm specimens obtained from 17-year-old trees that were harvested at the Ñuble region in Chile, and the data comprised modulus of elasticity (Ec), compressive strength (ƒc), basic density, initial moisture content, and some anatomical characteristics of the wood. The experimental design emphasized the influence of the radial position of the wood within the logs (defined as inner-wood, middle-wood, and outer-wood) on the measurements, and the results showed that the modulus of elasticity, compressive strength, and the basic density all increased from core to bark. The compressive strength of outer-wood showed a strong and positive relation with the basic density. Cell wall thickness and wall cell area showed a significant positive correlation with compressive strength.