Volume 19 Issue 2

Biomass is a renewable alternative to fossil fuels and a valuable source of chemicals. In this study, a facile and efficient method was established to improve the selectivity of methyl lactate (MLA) for the homogeneous Lewis acid catalyzed chemical conversion of glucose and methanol. The effects of catalyst dosage, reaction temperature, and reaction time were systematically investigated, with an emphasis on the variation trends of MLA and other by-products. Through process optimization, the best catalyst molar ratio was 0.075 to 0.1, the reaction temperature was 170 to 180 °C, and the reaction time was 3 h. Under these conditions, the conversion of glucose in methanol exceeded 98%, and the yield of MLA was greater than 40%.

Paper pulp is a lignocellulosic fibrous material used in the industrial production of paper and board products. In addition to cellulose and hemicellulose, paper pulp contains 1 to 20% lignin, depending on the raw materials and pulping process used. Lignin is a heterogenous aromatic polymer that is hydrophobic and more resistant to microbial degradation compared to the easily biodegradable cellulose and hemicellulose. In this study, the biodegradation of paper pulps containing varying amounts of lignin was examined in soil and marine environments using ISO testing methods. Lignin significantly reduced the mineralization of paper pulps to CO₂ in both environmental conditions, and a strong inverse correlation between lignin content and the mineralization to CO₂ was observed. A similar impact was observed with natural materials containing lignin, such as birch sawdust. Since the calculation of biodegradability in most ISO and EN standards is based solely on the concept of mineralization to CO₂, materials containing lignin can receive poor values in these tests. The implications of this for standardized requirements of biodegradability and possible options to overcome testing deficiencies are discussed.

Qualitative and quantitative anatomical characteristics and radial variations of the major cell components in Paulownia tomentosa wood were examined using optical microscopy and X-ray diffraction to aid in wood identification and as quality indices. The vessel arrangement on the transverse surface was either ring-porous or semi-ring-porous. Most vessels had solitary pores, while some vessels had multiple radial pores. The axial parenchyma was generally confluent and partially of aliform type. Tyloses with high frequency in the vessel lumen and multiseriate rays (2 to 5 cells) were typical. The vessel diameter of earlywood and latewood was approximately 240 and 107 μm, respectively, with a range of 165 to 289 μm in earlywood and 55 to 149 μm in latewood. Ray height and fiber length were approximately 178 and 740 μm, respectively. The vessel diameter in both earlywood and latewood and the fiber length increased gradually with an increasing number of growth rings. Ray height was constant from the pith to the middle section and decreased toward the bark. The anatomical characteristics and radial variation of major components of P. tomentosa can be used as wood identification keys and quality indices.

Anaerobic digestion (AD) has been widely used as a promising technology for the treatment of kitchen waste (KW). The effects of several acidification-resisting methods were compared, which included the supplementation of trace elements (TEs) and zero-valent iron (ZVI) / powdered activated carbon (PAC), and the application of the sludge domesticated by acetic acid (HAc) and KW as inoculum. The results showed that the supplementation of TEs and ZVI/PAC at total solid (TS) content of 6% and optimal addition doses resulted in an increase in methane yield to 346 and 366 mL/g VS, respectively. In addition, the methane yields of 327 and 241 mL/g VS were obtained by applying the sludge domesticated with KW and HAc as inoculum, while the methane yield of the control was only 89.2 mL/g VS, representing a relative increase of 288%, 311%, 267%, and 170%. The acidification could be alleviated by applying these methods, and also the methanogenic profile was improved. Furthermore, microbial community analysis revealed that the enrichment of Methanosarcina, which enhanced the substrate utilization capacity and subsequently increased methane production, was achieved through the addition of TEs and ZVI/PAC, along with the application of sludge domesticated by KW.

In agriculture-producing countries, pruning waste is obtained from fruit-bearing trees during the fruit-growing process. The present study aims to determine the potential of biochar of pruning wastes, obtained as a result of agricultural activities that have economic value. To the best of the author’s knowledge, no study has been conducted in Turkey to make a regional estimation of the biochar potential of pruning wastes. Biochar produced from waste provides the advantage of use in various fields, such as soil remediation and water and wastewater treatment. In this study, data on the number of trees bearing fruit (almond, apple, apricot, cherry, peach, pear, plum, and sour cherry) from the Turkish Statistical Institute were used based on the equations specified. First, the amount of pruning waste, then the usable pruning waste, and finally their biochar potential were calculated. It was estimated that the apple tree had the highest total biochar potential (41.5 thousand tons/year). Regarding the regions, the highest biochar potential was in the Central Anatolia Region for the apple tree (19.3 thousand tons), followed by the Eastern Anatolia Region for the apricot tree (13.6 thousand tons). The total biochar potential of pruning wastes from fruit-bearing trees in Turkey was estimated at 175 thousand tons for the year 2021.

The limited market share and growth of Bumiputera entrepreneurs in domestic furniture and wood product industry in Malaysia remains a long-standing challenge. Therefore, a study to examine the market factors that contribute to the failure to thrive among Bumiputera entrepreneurs, registered with the Malaysian Timber Industry Board, was conducted. The results revealed that most of the respondents were micro- and small-sized enterprises, with sales focused on the domestic and contract markets. They were mostly producing sofa and kitchen cabinets, made to order, and sold in domestic markets within the vicinity. The respondents also indicated that the major challenges that impeded their ability to penetrate and capture market share include the limited production volume, lack of product diversity, limited government contract, and inter-ethnicity business collaboration. The Chi-square and Pearson Product Moment Correlation tests found that the significant challenges were only the limited production volume due to small company size, lack of product diversity, and the limited inter-ethnicity business collaboration among Bumiputera entrepreneurs. Therefore, policymakers should take heed that despite the many years of targeted and affirmative assistance to expand the domestic market share of Bumiputera entrepreneurs, the results remain poor, and inevitably, a new approach to Bumiputera entrepreneurs’ development must be adopted.

This study investigated the effect of various layer arrangements and their impact on the properties of laminated veneer lumber (LVL). Seven different layer arrangements (CCCCCCC, DDDDDDD, PPPPPPP, CDDDDDC, CPPPPPC, CDDCDDC, CPPCPPC, CDCDCDC, CPCPCPC, CCDDDCC, CCPPPCC, CCDCDCC, and CCPCPCC) were used in the manufacturing of the LVL, with each arrangement represented by a combination of the three wood species: hornbeam (C), paulownia (P), and poplar (D). The veneers were bonded with a polyurethane adhesive and pressed under 1 MPa pressure. The physical and mechanical properties of the laminated veneer lumber, including modulus of rupture, modulus of elasticity, block shear, delamination, and swelling, were measured under both dry and cyclic conditions (boil and dry). The modulus of rupture and modulus of elasticity of the LVLs increased when the proportion of hornbeam in the lamination increased. In the cyclic boil-dry condition, the laminated veneer lumbers with the configurations CPCPCPC and CDCDCDC showed the best structural performance. Furthermore, the study found that when one or two upper layers of poplar and paulownia were replaced with hornbeam layers, cracks were observed in the laminated veneer lumber samples. However, when the layers of poplar and paulownia were replaced with hornbeam alternately, no cracks were observed after saturating the laminated veneer lumber with water. The utilization of an alternating arrangement of poplar and paulownia layers with hornbeam in LVL can be used as an effective and cost-efficient approach for enhancing and reinforcing the LVL performance.

Malaysian bamboo residues were subjected to a liquefaction process. Bleaching of the liquefied product was carried out to reduce its coloration. Polyurethane (PU) films were then manufactured as a coating material by reacting the -OH groups in the bamboo material with isocyanate (-NCO). The study’s objective was to investigate the effects of bleaching on the properties of resulting polyurethane films and to elucidate its behavior as affected by the NCO/OH ratios. Bamboo residues, in powder form, were liquefied with polyethylene glycol (PEG 400) and glycerol (Gly) as reactive co-solvent, and sulphuric acid as catalyst. The obtained liquefied bamboo was then bleached with hydrogen peroxide. Bleached and unbleached liquefied bamboo were used to produce PU film by reacting isocyanate at NCO/OH ratios of 1.6, 1.8, 2.0, and 2.2. The results revealed that the NCO/OH ratios improved the mechanical performance of the PU films. Bleaching treatment slightly reduced the thermal stability and mechanical strength of the PU films. However, bleached PU films displayed lower water absorption and lower biodegradation than unbleached PU films. Nevertheless, the performance of the bleached PU films was still acceptable, indicating that the bleaching treatment using hydrogen peroxide is feasible to obtain semi-transparent film.

The anatomical characteristics are highlighted for Entandrophragma cylindricum, Entandrophragma utile, and Entandrophragma angolense. Wood samples, which were previously obtained from commercial timber industries in the Marmara region of Türkiye and used as course materials, were used. Qualitative and quantitative anatomical characteristics were determined. Qualitatively, characters such as distinct growth rings, diffuse-porous wood, deposits in vessel elements, simple perforation plates, alternate intervessel pits, heterogeneous ray type, and septate fibres, were common to all species. The quantitative evaluation showed that there were differences between species. Entandrophragma species differ in some wood characteristics such as the tangential diameter of the vessel, ray height, ray width, and fibre lumen diameter. E. utile had higher values of the mean tangential vessel diameter (180 μm) and fiber lumen diameter (18.4 μm) than the other two species. It is possible to say that the anatomical features of E. cylindricum differ from that of other species and that it will be easier to diagnose among other species. E. cylindricum had the lowest values of the mean tangential vessel diameter (147 μm) and ray height (361 μm).  Distinctive characters for E. utile and E. angolense are tangential vessel diameter, vessel length, ray height, ray width, and all fibre dimensions.

A surface response design was employed to develop a sodium hydroxide (NaOH) pretreatment method for Quercus variabilis Blume using low NaOH concentration at low temperature. Nevertheless, the persistent issues associated with alkaline pretreatment of lignocellulose, namely high-water consumption and wastewater generation, remain prevalent in this pretreatment process. To address these challenges, this study aimed to conduct enzymatic hydrolysis of NaOH-treated Q. variabilis Blume without the intermediary washing steps. The results revealed that, following pretreatment and solid-liquid separation, NaOH-treated Q. variabilis Blume could be directly subjected to cellulase-mediated hydrolysis with pH adjustment, eliminating the need for washing steps. The maximum enzymatic hydrolysis efficiency reached 95.9% under specific conditions (1.2% NaOH, 8.9 °C, 32.1 h). This approach offers a promising avenue to enhance the enzyme hydrolysis rate of NaOH-treated lignocellulose. Notably, the low-temperature and low-concentration NaOH treatment effectively removed a substantial portion of lignin and hemicelluloses, resulting in a higher crystallinity index of the cellulose-rich residue compared to substrates treated solely with steam explosion. The integration of direct pretreatment and alkaline treatment emerges as an environmentally friendly and economically viable method for producing glucose and high-purity lignin. The obtained lignin can be further transformed into high-value products within the biorefinery framework.