Research Articles

Poor impregnation of sapwood from Cryptomeria japonica kiln-dried logs is a problem for preservative treatment in Japan. The permeability of copper azole (CuAz) into sapwood was reported to decrease with an increase in the drying temperature of logs, due in part to the presence of bordered pits. However, damaged and aspirated bordered pits appeared abundantly at 100 °C and 120 °C, although the difference in permeability was very little. To investigate this phenomenon, two types of smaller split log pieces, one containing both heartwood and sapwood, and the other containing sapwood without heartwood, were dried at 20 °C to 120 °C to test higher drying conditions. Results were similar to those of the dried logs. However, the impregnation and penetration at 80 °C were the lowest, and those at 100 °C and 120 °C were greater than the dried logs. Additionally, the number of damaged bordered pits on dried, split samples was generally higher than that of dried logs, as observed with scanning electron microscopy.

This study regards the effect of technological aspects on mat compression during the manufacturing of low-density particleboards made of two low density species – i.e. poplar and pine. Using these materials, three-layer low-density particleboards (500 kg/m3) were prepared. Three series were manufactured: (1) neat pine, (2) poplar-pine (face layer and core layer, respectively) and (3) neat poplar boards. Measurements of real-time variations in mat core temperature, pressure, and mat thickness allowed for the analysis of the mat compaction. Selected mechanical properties (modulus of rupture, modulus of elasticity, and internal bonding) of the manufactured particleboards were determined. Raw material of lower density used for particleboard manufacturing required either prolonged pressing time or more intense heat transfer into the mat core. The highest strength values were obtained for the poplar-pine particleboards.

Copper coating was deposited on poplar veneer using different relative concentrations of plating solution. The coating structure, thickness, crystal structure, surface resistivity, contact angle, surface free energy, and electromagnetic shielding effectiveness were investigated. The surface morphology and thickness were observed using scanning electron microscopy, and the crystal structure was analyzed using X-ray diffraction. Increasing the relative concentration of plating solution resulted in a uniform and dense coating structure, and the thickness notably increased. In addition, the lateral direction resistivity was two times greater than the longitudinal direction resistivity, and the surface wettability changed from hydrophilic to hydrophobic, which led to a decline in surface free energy. Electromagnetic shielding effectiveness reached 62 dB in the frequency range of 10 kHz to 1.5 GHz. The electroless plating copper veneer was optimal when the solution contained 80 g/L of CuSO4·5H2O, 20 g/L of C4O6H4KNa, 40 g/L of EDTA-2Na, and 40 mL/L of HCHO 40 mL/L.

Lignocresol was isolated from softwood with p-cresol using sulfuric acid and phase separation. An alkaline treatment of the lignocresol, followed by acidification, selectively yielded a guaiacyl coumaran, G1, in the acid-soluble fraction. With further alkaline treatment of G1 in 0.5 M of NaOH solution at 170 °C for 60 min, it was strongly suggested that a guaiacyl benzofuran derivative, G2, was obtained by the elimination of formaldehyde, based on analytical data of the reaction mixture. The process is very unique and well-designed based on the reactivity of Cα-ethers, or Cα-OH, Cβ-aryl-ethers, and Cγ-OH of lignin, although condensation reactions via formaldehyde occurred in parallel to give condensed products with a diarylmethane structure. Because these phenolic dimers, G1 and G2, were recovered from the guaiacyl unit linked with the neighboring guaiacyl units via two b-aryl-ether bonds, they are promising lignin-derived chemicals that are obtainable in a high yield.

This study investigated the effect of expanded vermiculite (EV) on the flammability properties of medium-density fiberboard (MDF), which was evaluated by limiting oxygen index (LOI) and simultaneous thermal analysis (TG-DSC). In addition, the modulus of rupture (MOR) and the modulus of elasticity (MOE) of the samples were studied. The results indicated that the addition of EV increased the LOI of MDF, while it decreased the MOR and MOE of MDF quite rapidly. The TG data showed that the fiber-charring rate of the fire retardant MDF increased sharply, more than 10 times that of untreated MDF. Moreover, with increasing of the ratio of the EV and fiber (V/F), it increased the fiber-charring rate of the MDF sharply, decreased the temperature of the maximum mass loss, and decreased the maximum mass loss rate of MDF. The DSC test results indicated that the total temperature range of the exothermic stage had extended and that the first peak in the exothermic stage decreased rapidly with increasing of V/F ratio.

The many uses of wood are greatly affected by its surface properties, which are significantly altered by heat treatment. Investigated here are the wettability and surface brittleness when treating poplar wood with heat at 160, 180, 200, and 220 °C for 2 h. Contact angles were measured by the sessile drop method, and surface free energy was calculated. Surface brittleness was expressed by hardness (HD value), roughness (Ra, Rq, Ry, and Rz values), and abrasive resistance (K value). Next, non-destructive Fourier transform near-infrared spectroscopic (FT-NIR) and X-ray photoelectron spectroscopic (XPS) measurements were employed to analyze the surface chemical changes. Scanning electron microscopy (SEM) revealed the post-heating microscopic structure. The results demonstrated that heat treatment reduces the surface wettability while increasing the surface brittleness, which becomes more apparent with increased temperature. Significant differences were determined (p < 0.05) between the surface parameters at four different temperatures. The degradation of cell wall components and the deterioration of microstructures was further expounded by FT-NIR, XPS, and SEM analyses. Furthermore, the abrasive resistance and hardness values decreased in line with the rate of weight loss (WL, %) and temperature. This indicates a strong correlation between the surface characteristics and the WL or temperature. The intensity of heat treatment appears to be predictable and easy to regulate.

The goal of this work was to evaluate the technical feasibility of walnut shell flour (WSF) as substitute for wood in walnut shell flour/thermoplastic starch (WSF/TPS) composites. The effects of walnut shell flour (WSF), thermoplastic starch (TPS), and nanoclay on the physical and mechanical properties of WSF/TPS composites were investigated. The composite samples were formed in a Colin extruder with four-chamber heat with temperatures. Then, test samples were made using injection molding. The addition of up to 40% WSF greatly improved the tensile strength, flexural strength, and elasticity modulus of the composite. Also, the composites made with higher WSF contents had increased thickness swelling and water absorption. The incorporation of nanoclay (0% to 5%), greatly improved the tensile properties. Soil burial degradation experiments showed that biodegradation was accelerated by the increase of starch in the composite mixtures. The study showed that WSF can be successfully utilized for the manufacture of composites with useful physical and mechanical properties.

In an attempt to find a more efficient technique for biodegradation of the recalcitrant Reactive Black 5 (RB-5) dye, a composite xylan-polyvinyl alcohol (xylan-PVOH) hydrogel was used to immobilize laccase from the white-rot fungusTrametes versicolor. Xylan was prepared from the black liquor of pulp and paper effluent, and it was esterified with citric acid prior to cross-linking with polyvinyl alcohol (PVOH). The optimum composition for the immobilized laccase bead formation consisted of 4% (w/v) modified xylan, 10% (w/v) PVOH, and 15 U.mL-1 crude laccase. The maximum decolorization of RB-5 (98.45 ± 1.96 %) was obtained within the first cycle (6 h) at 40 °C. In the eighth cycle, the reused beads were able to decolorize 55.35 ± 2.46 % of the RB-5. Moreover, the xylan-PVOH beads extended the optimum pH range of laccase activity from 6 to 10 and tolerated a temperature up to 10 °C higher than that of the free enzyme. These results suggest that the xylan-PVOH bead has great potential as the polymer matrix for enzyme immobilization, which has applications in wastewater treatment.

Wood plastic composites (WPCs) have recently gained increased market share as a result of their beneficial properties and use of sustainable material sources. Currently, however, WPC products are limited to extruded profiles. More complex product shapes and geometries will increase market potential, but they demand additional post-processing after extrusion. Post-processing machinery coupled online with an extruder necessitates material handling, which is commonly achieved using belt conveyors. This paper considers transport of WPC material through a post-extrusion process using a belt conveyor system. Special emphasis is placed on studying the friction and surface energy properties of the belt conveyor. Friction at the interface of the raw material and belt cover was tested using a standard incline-plane method, and adhesion and stickiness were evaluated by determining the surface free energies of the belt cover and WPC material at 23 and 100 °C. On the basis of these measurements, this paper investigates key aspects of belt cover material selection and proposes a conveyor belt configuration for a prototype post-extrusion process line that can be utilized in commercial mass production of WPC products.

The characterization of fibers extracted from leaflet, the empty fruit bunches, leaf sheath, and spath of palm tree was performed. The fibers were extracted using three different procedures through chemical and /or enzymatic methods. The raw fibers studied have xylose contents between 13-22% and glucose content between 30% and 45%. The microfibrillar angle (MFA) values are in the order: bunch > spath > leaf sheath >> leaflet. Spath and leaf sheath, which naturally occur in a woven form present poor mechanical strength but could be readily used to produce cheap composites. Leaflet fibers extracted from date palm tree exhibiting a low MFA (16°), a high cellulose content, and cellulose crystallinity present the highest ultimate tensile strengths (≈ 1250 N.mm-2).