NC State
BioResources
  • Researchpp 2660-2672Pesenti, H., Torres, M., Oliveira, P., Gacitua, W., and Leoni, M. (2017). "Exploring Ulex europaeus to produce nontoxic binderless fiberboard," BioRes. 12(2), 2660-2672.AbstractArticlePDF
    Ulex europaeus is one of the most abundant and aggressively invasive plants on the world. Its fibres, which can be isolated using an alkaline pulping process, have been successfully thermo-pressed into high-density fibreboards without any type of binder. The influence of the bioorganic and crystalline components on the product was investigated using crystallographic, thermo-analytical, and mechanical techniques. Cellulose was predominantly an Iβ polymorph, more common in hardwood, but the composition of the material was typical of softwood. Both the crystallinity in the fibres and the average domain size of cellulose increased during thermo-pressing. Notwithstanding that the residual lignin was present in a small amount, this promoted the cohesion of fibres by improving hydrolysis and adhesion properties. The best overall properties were observed in the pressed products of 1030 ± 38 kg/m3, showing an elastic modulus of 4.31 ± 0.26 GPa, with a modulus of rupture of 26.5 ± 1.3 MPa. These results serve as the basis to transform the invasive species into a fully non-toxic added-value resource.
  • Researchpp 2673-2689Zaharia, S. M., Morariu, C. O., Nedelcu, A., and Pop, M. A. (2017). "Experimental study of static and fatigue behavior of CFRP-balsa sandwiches under three-point flexural loading," BioRes. 12(2), 2673-2689.AbstractArticlePDF
    Balsa wood is a natural cellular material with an excellent resistance-to-weight ratio that is ideal for manufacturing the core of sandwich structures. In this study, sandwich specimens with a carbon-fiber-reinforced polymer (CFRP) skin and a balsa wood core were tested with static and dynamic loading. Three-point flexural tests in static regime determined the mechanical characteristics of the CFRP-balsa specimens that were needed for subsequent fatigue strength tests. Also, experimental research was performed on the Charpy impact response of the CFRP-balsa sandwich specimens. This study implemented an accelerated fatigue testing method to identify and predict the mean fatigue life of the CFRP-balsa sandwich specimens subjected to cyclic fatigue via three-point flexural tests. Using the accelerated fatigue and the three-point flexural testing methodology on the CFRP-balsa sandwich specimens, the testing period was reduced by 11.9 times, and thus the material costs necessary for the tests were also reduced. Also, the breaking surfaces were analysed to reveal the failure modes of CFRP-balsa specimens subjected to static and fatigue tests at three-point flexural and at impact tests.
  • Researchpp 2690-2698Mertoglu-Elmas , G. (2017). "The effect of colorants on the content of heavy metals in recycled corrugated board papers," BioRes. 12(2), 2690-2698.AbstractArticlePDF

    Recycled paper is an important raw material to provide sustainability of natural resources and reduce the environmental impact of the use of paper from recycled pulp in the packaging industry. Hence, recycled paper production is higher in terms of volume and utilization. Recycled paper products are used in the packaging industry partially or fully. Such usage leads to the presence of heavy metals due to recycled and chemical additive sources. The present study aims at determining the amounts and also identifying the sources of heavy metals such as Pb, Cd, Zn, Ni, and Cu contained in recycled testliner (TL) and fluting (FLT), which are main products used in production of corrugated cardboard. The metals in the structure of the paper used in packages directly or indirectly in contact with foods are heavy metals. Mean values of 2.6 mg kg-1 Pb (lead), 2.8 mg kg-1 Zn (zinc), 0.094 mg kg-1 Cd (cadmium), 1.8 mg kg-1 Ni (nickel), and 25.4 mg kg-1 Cu (copper) were detected in test liner and fluting papers using inductively coupled plasma optical emission spectrometry (ICP-OES). The main sources of heavy metals are colorants, mainly consisting of conventional paint and pigments as well as spot and Pantone Matching System (PMS) colorants.

  • Researchpp 2699-2710Liu, H., Luo, B., Shen, S., and Li, L. (2017). "Design and mechanical tests of FRP pipe with bamboo and veneer layer," BioRes. 12(2), 2699-2710.AbstractArticlePDF

    Pipes that are light in weight are necessary for convenience and to reduce the cost of transportation and installation. A new design of glass fiber reinforced plastic (FRP) pipe with a bamboo and veneer layer is presented in this paper. The core layer of the sandwich structure of the pipe wall is made of bamboo and veneer, and the inner and outer layers are FRP. Range analysis and variance analysis of orthogonal experiments were conducted to investigate the effect of fiber stress, winding angle, and core material on the mechanical performance of the pipes subjected to shearing and parallel-plate loading tests. The results indicated that the new design of FRP pipe with a bamboo and veneer layer was feasible, and the pipe had better mechanical performance with a fiber stress of 300 N, a winding angle of 30°, and a core material of bamboo. Core material was the most influential factor in mechanical performance. The average density of pipes was 0.94 g/cm3, approximately half that of the glass fiber reinforced plastic mortar (GRPM) pipes. The FRP pipe offered advantages in terms of weight savings and improved mechanical performance, and it showed a great application potential for the future.

  • Researchpp 2711-2720Liao, C., Zhang, H., Song, X., Chen, T., and Huang, S. (2017). "The screening method of the internal defects in wood members of the ancient architectures by hammering sound," BioRes. 12(2), 2711-2720.AbstractArticlePDF

    Defects have a serious impact on the load carrying capacity and the safety of ancient architectural wood members. Common screening methods to identify defects cause damage to this wood. To protect ancient architecture, it is necessary to develop a method that can screen for internal defects and estimate their size quickly and efficiently without destruction. This paper studied the detection mechanism of the sound hammering method for screening internal defects in wood. Wood members generated different kinds of vibration through hammering experiments, and the vibration produced by hammering wood with internal-hole defects was divided into three kinds: local surface vibration, the whole structure vibration, and defective-part vibration. The parameters and their variation of these three kinds of vibration were investigated by a mechanical vibration simplified model, and the method for screening the internal defects based on sound hammering was proposed. The feasibility of the method was verified by experiments.

  • Researchpp 2721-2730Büyüksarı, U. (2017). "Effect of loading rate on mechanical properties of micro-size Scots pine wood," BioRes. 12(2), 2721-2730.AbstractArticlePDF

    The use of micro-size samples is becoming more important to determine the mechanical properties of wood. The aim of this study was to investigate the effect of the loading rate on the micro-mechanical properties of Scots pine (Pinus sylvestris L.) wood. The bending strength, modulus of elasticity in bending, compression strength parallel to the grain, and tensile strength parallel to the grain were determined using micro-size test samples. Three different loading rates were used for each test. The first loading rates were determined according to related ISO standards, and the second and third loading rates were determined as half- and quarter- of the standard loading rates. The results showed that the loading rate had significantly affected the modulus of elasticity and compression strength of Scots pine wood. However, the loading rate had no significant effect on the bending and tensile strength of the Scots pine wood. When the loading rate decreased, the mechanical properties of micro-size Scots pine wood were decreased.

  • Researchpp 2731-2747Zhang, B., Leng, E., Wang, Y., Gong, X., Zhang, Y., and Xu, M. (2017). "Characterization of water-soluble intermediates and solid residues from fast pyrolysis of cellulose in a wire-mesh reactor," BioRes. 12(2), 2731-2747.AbstractArticlePDF
    The fast pyrolysis characteristics of cellulose were investigated in a wire-mesh reactor, which minimized the secondary reactions between the solid residues and the evolved volatiles during pyrolysis and facilitated the collection of the primary intermediates and volatiles. The main component of the water-soluble intermediates was anhydro-oligosaccharides with various degrees of polymerization (DP). The yields of cellotriosan and cellotetraosan in the intermediates were much higher than those of levoglucosan and cellobiosan in the early pyrolysis stage, indicating that the depolymerization of the cellulose chain occurred during a random cleavage process. Anhydro-oligosaccharides with DP up to 3, and partially decomposed sugar-ring-containing oligomers, were identified in the primary volatiles. Among the sugar-ring-containing oligomers, the compound with a relative molecular weight of 222 was considered to be the product of a reverse aldolization reaction. An analysis of the solid residues confirmed the occurrence of intramolecular dehydration during the cellulose pyrolysis.
  • Researchpp 2748-2767Yao, X., Xu, K., and Liang, Y. (2017). "Assessing the effects of different process parameters on the pyrolysis behaviors and thermal dynamics of corncob fractions," BioRes. 12(2), 2748-2767.AbstractArticlePDF
    The influence of heating rate, gas flow, and biomass particle size on the pyrolysis and thermal dynamics of corncobs (CC) was investigated experimentally using the quantitative method of thermogravimetric analysis (TGA) coupled with mass spectrometry (MS), and the obtained results were compared in depth. For the examined heating rates of 5, 10, and 20 °C/min, the CC pyrolysis at higher heating rates resulted in a more complete decomposition. The initial pyrolysis temperature decreased when gas flow was increased from 30 to 90 mL/min, whereas the weight loss increased. Particle sizes (d ≤ 74 μm, 74 μm < d ≤ 154 μm, 154 μm < d ≤ 280 μm, and 280 μm < d ≤ 450 μm) had pronounced effects on the thermal decomposition and bio-syngas compounds (CO, CO2, CH4, and H2) distribution. The emission intensities of most the gaseous products increased at the elevated heating rate, while they decreased with increasing gas flow. In sum, the pyrolysis of CC particles of 154 μm < d ≤ 280 μm under 20 °C/min and in a gas flow of 30 to 60 mL/min was the most appropriate for bio-syngas production in industrial applications.
  • Researchpp 2768-2779Li, S., Yang, Q., and Ye, Y. (2017). "Preparation of activated carbon from herbal residues and kinetics of cephalosporin antibiotic adsorption in wastewater," BioRes. 12(2), 2768-2779.AbstractArticlePDF

    In order to utilize the leftover materials from traditional Chinese medicine production and to remove antibiotics from wastewater, extracted herbal residues were used as raw materials to produce activated carbon. To keep a constant quality and adsorption ability across cephalosporin antibiotic samples, all samples were divided into rhizomes, fruits, and leaves to make activated carbon by step-wise carbonization and overheated steam activation. The three kinds of carbon were mixed in the optimal ratio of 5:4:2, which had homogeneity in quality with a high adsorption capacity. Maximum adsorption of the mixture to cefalexin and cefradine were 7.1 mg/g, and the mixture removed 84% of the antibiotics from treated wastewater. Approximately 90% of the antibiotics was desorbed after ultrasonic treatment of the distilled water-carbon mixture for 10 min, and a re-adsorption capacity of 80% was maintained for next use. The adsorption process is dominated by a pseudo-second order kinetic reaction, with two active sites binding to one antibiotic molecule. The rate-limiting step is an intra-particle diffusion process. The isothermal adsorption process conforms to Langmuir and Tempkin isotherm models, showing multilayer and physical adsorption. The activated carbon from herbal residues can adsorb a low concentration of antibiotics in wastewater and be recycled after ultrasonic treatment.

  • Researchpp 2780-2791Hacibektasoglu, M., Campean, M., Ispas, M., and Gurau, L. (2017). "Influence of heat treatment duration on the machinability of beech wood (Fagus sylvatica L.) by planing," BioRes. 12(2), 2780-2791.AbstractArticlePDF
    The comparative behavior of heat-treated and untreated beech wood (Fagus sylvatica L.) were studied in response to planing. Beech wood samples were heat-treated in an electric oven without air circulation, at atmospheric pressure, at 200 °C for 1, 2, 3, 4, 5, or 6 h. After conditioning, both the heat-treated samples and the untreated controls were planed at a rotation speed (n) of 4567 rpm and a feed speed (u) of 10 m/min via a “silent power” cylindrical cutter. The cutting power was measured during machining by a Vellemann DAQ board. After processing, the surface quality was measured along and across the cutting direction with a stylus MarSurf XT20 instrument, and the processing roughness was assessed by the roughness parameter Rk. The influence of the heat-treating duration upon the cutting power and the processing roughness were analyzed and correlated to the mass loss after the heat treatment. Linear regression functions were generated for both of the correlations.

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