NC State
BioResources
  • Researchpp 4187-4201Mansour, M. M. A., Nasser, R. A., Salem, M. Z. M., Ali, H. M., and Hatamleh, A. A. (2017). "Study of mold invasion on the surface of wood/polypropylene composites produced from aqueous pretreated wood particles, Part 2: Juniperus procera wood branch," BioRes. 12(2), 4187-4201.AbstractArticlePDF

    Mold invasion by Trichoderma harzianum T6776 over the surface of wood-plastic composites (WPCs) made from Juniperus procera wood-branch and polypropylene with a melt-blending technique was examined using scanning electron microscopy (SEM) and electron dispersive X-ray spectroscopy (EDX). Before the addition of coupling agent, the WPC samples were made from untreated and pretreated wood-branch particles of J. procera with either cold or hot water and then mixed with polypropylene to produce panels. The surfaces of WPC samples were inoculated by a mold suspension of T. harzianum. SEM-EDX measurements of WPCs made from J. procera particles showed little or no growth of T. harzianum, irrespective of treatment with cold or hot water. The results suggest that WPCs made from the particles of J. procera wood-branch pretreated with either cold or hot water could be useable in wet conditions. In addition, using of J. procera as durable wood for manufacturing of WPCs had good effects on the prevention of the mold infestation over the surfaces of the produced panels.

  • Researchpp 4202-4213Podlena, M., Böhm, M., Múčka, M., and Bomba, J. (2017). "Determination of the bending moment of a dowel and tenon joint on window profile IV 92 of a wooden window," BioRes. 12(2), 4202-4213.AbstractArticlePDF

    This study deals with calculating and comparing the bending moments of two types of corner joints for commercially produced wooden sashes. The triple tenon and mortise joint was compared to a dowel joint on the sash of a window profile IV 92, made of spruce glued laminated timber. On the testing machine, the maximum force in the angular plane of a window sash under compression or tension mode was applied, and the measured values were converted to the bending moments. A significant difference between the bending moments for the mortise and tenon joint, and dowel joint were determined. The dowel joints achieved 167 Nm in a tensile test and 168 Nm in a compression test, while the mortise and tenon joint achieved 344 Nm in a tensile test and 325 Nm in a compression test. However, a significant difference was not revealed between the compression and tension tests for both types of joints. The differences for both types of joints were explained via the different sizes of the bonded surfaces, which was higher for the tested triple tenon and mortise joint by 29%.

  • Researchpp 4214-4228Zeng, L., Zeng, B., Chen, J., Zhang, L., Zhan, P., Hu, B., and Zhang, Y. (2017). "Synergistic fermentation of camphor leaves by cellulolytic fungus and optimization of reducing sugar production," BioRes. 12(2), 4214-4228.AbstractArticlePDF

    The degradation of lignocellulosic materials requires the synergy of multiple enzymes. Synergistic fermentation would be an alternative to a complete enzyme system and consequentially enhance enzymatic production. The present study used cellulolytic fungus of Penicillium decumbens, Aspergillus niger C112, and Trichoderma reesei RutC-30 as the starting strains, to screen for the best combination and proportion of synergistic fermentation. The experiments of different combinations and inoculum ratios for synergistic fermentation were performed, and Box-Behnken designs were adopted to optimize the fermentation conditions. The best combination of strains was confirmed as T. reesei RutC-30 and P. decumbens with an 8:2 inoculum ratio. The maximum sugar concentration was 1.48 g/L with CMCase (17.53 U/mL) and FPase (4.78 U/mL) in this situation. Response surface methodology revealed the optimized parameters as a substrate concentration of 5.93% at 32.12 °C, and a fermentation time of 5.85 d with a predicted sugar concentration of 2.91 g/L. Under these conditions, a maximum sugar production of 2.96 g/L was achieved in verification experiments.

  • Researchpp 4229-4238Kang, H. Y., Lee, W. H., Jang, S. S., and Kang, C. W. (2017). "Polyethylene glycol treatment of Han-ok round wood components to prevent surface checking," BioRes. 12(2), 4229-4238.AbstractArticlePDF

    The effect of polyethylene glycol (PEG) treatment was investigated relative to surface checks of red and Korean pine round wood for building Korean-style homes. The logs used for this study were impregnated with a solution of PEG-1000 for three weeks, and then they were dried to a moisture content of about 15% at the temperature of 120 °C within the drying time of 49 h. During the middle stage of drying, slight surface checks were found on red pine PEG-treated logs compared with severe surface checks on red pine control logs. Due to PEG treatment and high drying temperature, at the end of drying, apparent surface check was not found on red pine PEG-treated logs compared with serious surface checks on the corresponding control log. No surface checks were discovered on Korean pine logs during and after drying due to the PEG effect. Thus, PEG treatment was effective in preventing surface checks on red and Korean pine logs during drying at high temperature.

  • Researchpp 4239-4258Hatam, A., Dehghani Firouzabadi, M., and Resalati, H. (2017). "Surface chemistry of gravure printed décor paper and adhesion of melamine formaldehyde resin coatings," BioRes. 12(2), 4239-4258.AbstractArticlePDF

    The surface chemistry of gravure printed décor paper and its effect on the adhesion of melamine formaldehyde (MF) coatings were studied. Two industrially printed decor papers with different designs were used for the study. A combination of the attenuated total reflectance Fourier transform Infrared (ATR FT-IR) and FT-IR spectroscopy techniques were employed to determine the effect of the gravure printing ink on the printed paper surface chemistry. Then, the influence of the surface chemistry on the adhesion of MF coatings was characterized according to the abrasion resistance test. The ATR IR results suggested that the printing ink components had a noticeable effect on the surface characteristics of the printed décor paper. In addition, it was indicated that the use of an organosilane adhesion promoter in the gravure ink formulation could significantly affect the adhesion strength of the MF coatings through the formation of ring siloxane structures. It seemed that siloxane bridges formed between the molecules of ink binder and UF resin could enhance the adhesion strength of subsequent MF coatings and could reveal better Taber abrasion resistance performance.

  • Researchpp 4259-4269Luo, Y. Y., Xiao, S. L., and Li, S. L. (2017). "Effect of initial water content on foaming quality and mechanical properties of plant fiber porous cushioning materials," BioRes. 12(2), 4259-4269.AbstractArticlePDF

    A porous, wood-fiber-based cushioning material for packaging was prepared in this study using poplar fiber and wood powder raw materials as an environmentally friendly resource. Water, the foaming agent azodicarbonamide and sodium bicarbonate, starch, and nucleating agent French chalk were used as additives, and the ingredients were subjected to hot-press molding. The effects of the initial water content on the foaming quality and mechanical properties of the plant fiber porous cushioning materials were explored. The results showed that the initial water content had a substantial influence on the foaming quality and mechanical properties of plant fiber porous buffer materials. When the initial water content was 69.3%, the initial embryo viscosity was the most suitable for bubble growth, and the porosity, pore size, and distribution of the samples were optimal. Furthermore, the mechanical properties of the samples were the strongest. The foaming mechanism of the plant fiber porous cushioning material was similar to the foaming mechanism of a polymer foaming material. Thus, the embryo viscosity had the greatest influence on the bubble growth process.

  • Researchpp 4270-4282Oktaee, J., Lautenschläger, T., Günther, M., Neinhuis, C., Wagenführ, A., Lindner, M., and Winkler, A. (2017). "Characterization of willow bast fibers (Salix spp.) from short-rotation plantation as potential reinforcement for polymer composites," BioRes. 12(2), 4270-4282.AbstractArticlePDF
    Short-rotation coppices have potential to be the future source of raw materials for many applications in the wood and paper industries. It is important to establish methods and products to handle their waste biomass. In this paper, the properties of bast fibers extracted from the bark of willow trees (Salix spp.) were evaluated for potential future use in the production of natural fiber-polymer composites. The anatomy of the fibers was investigated through optical and electron microscopy. The thermogravimetric analysis of these fibers showed that the major mass loss occurs at 257 °C. The density of the fibers was measured with a gas pycnometer (1.19 ± 0.2 g/cm3). The chemical analysis showed that willow bark fibers have a composition similar to willow wood. As an indicator of mechanical properties, single willow bast fibers were characterized by tensile tests. The results revealed values for tensile strength (307.6 ± 130.1 MPa) and Young’s modulus (16.9 ± 8.4 GPa) that are comparable to some commonly used natural fibers. The overall results showed that willow bast fibers have the required mechanical properties as well as thermal stability for application in reinforcement of polymers.
  • Researchpp 4283-4301Gurau, L., Irle, M., Campean, M., Ispas, M., and Buchner, J. (2017). "Surface quality of planed beech wood (Fagus sylvatica L. ) thermally treated for different durations of time," BioRes. 12(2), 4283-4301.AbstractArticlePDF
    Thermally treating wood improves its dimensional stability and durability. The chemical changes brought about by a heat treatment also affect the mechanical properties of wood. Consequently, a heat treatment also influences how a wood surface responds to machining. This study examined the impact of heat treatments at 200 C between 1 h and 6 h on the subsequent surface quality of planed beech wood (Fagus sylvatica L.). The new approach was that surface quality was assessed by following a tested method from previous research regarding the measuring and evaluation recommendations meant to reduce the biasing effect of wood anatomy, Also, a large number of roughness parameters were used for interpretation of the combined effect of processing and wood anatomy after filtering the data with a robust filter. Among those, Rk is the parameter that is least biased by wood anatomy and that best expresses the effect of processing alone. Electron micrographs were taken to visually assess the resultant surfaces. The results showed a gradual increase in processing roughness, as distinctively measured by Rk, which increased with longer durations of the treatment. Vessel cavities were deeper than those caused by processing and that influenced, among other parameters, Ra, which is most commonly used in literature to assess surface quality. The ray tissue, especially, exhibited both greater pull-out of fibers and a sort of plasticization with increased treatment time. The length of the thermal treatment reduced surface waviness. The results also showed that it was necessary to calculate the roughness parameters to differentiate between two similar surfaces rather than relying on visual and tactile assessments alone.
  • Researchpp 4302-4313Ma, Q., Han, L., Li, Q., Ma, S., and Huang, G. (2017). "Applicability of two separation methods for elemental analysis of typical agricultural biomass in China," BioRes. 12(2), 4302-4313.AbstractArticlePDF
    China still lacks standardized methods for element compositional analysis of agricultural biomass, in particular crop straw and livestock manure, which severely restricts the efficiency of the comprehensive utilization of agricultural biomass. Two separation methods, namely adsorbed–desorbed separation (AS) and chromatographic separation (CS), were applied to simultaneously analyze the carbon, hydrogen, nitrogen, and sulfur elements in major agricultural biomass. The optimal sizes of 1.00 mm for crop straws and 0.50 mm for livestock manure were obtained through optimization experiments. Afterwards, the sample mass was considered on two different elemental analysis instruments. From the metrological characteristics and variance analysis, a sample mass of 40 mg of the AS method was applicable for all the agricultural biomass, even with a content of 0.5%. On the other hand, 5 mg of the CS method was suitable for agricultural biomass with contents greater than 1.5%. It is recommended that samples should be kept free of impurities and completely homogeneous, especially for livestock manure. The results provide significant data for establishing a national standard system in the near future.
  • Researchpp 4314-4326Birkett, G. C., Sicoli, S., Horvath, L., Foster, J., Kim, Y. T., Renneckar, S., and Goodell, B. (2017). "Investigation of nanofibrillated cellulose for hydrophobic packaging material: Examining alternatives to solvent exchange and lyophilization," BioRes. 12(2), 4314-4326.AbstractArticlePDF
    A bio-based polyurethane and a thermosetting acrylic were tested in conjunction with nano-fibrillated cellulose and conventional kraft fiber to evaluate their use as a bio-derived, biodegradable packaging foam. Foams were evaluated for their density, water uptake, and compressive creep behavior. Bio-based urethane had a mean density of 68 kg/m3, mean water uptake of 4% in 24 h, and exceeded the 10% limit on compressive strain when tested at 71 °C and 22 °C, but remained below the limit when tested at -54 °C. The thermosetting acrylic had a mean density of 128 kg/m3, mean water uptake of 337% in 24 h, and showed less than 10% compressive creep at all three temperature conditions. The bio-derived urethane was able to incorporate 4% cellulose by mass, and the thermosetting acrylic was able to incorporate 48% cellulose by mass. In a 12-week test of biodegradation under fungal attack by Gloeophyllum trabeum and Rhodonia placenta, the urethane foam had < 3% mass loss and the acrylic foam had < 1% mass loss. The acrylic foams showed potential for durable packaging, particularly if they could be combined with a surface sealant that could be ruptured at the end of service life to promote degradation of the foam.

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